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5,6,7,12-Tetramethyl-2,2,3,3,9,9,10,10-octakis-trifluoromethyl-1,4,8,11-tetraoxa-6,12-diaza-5λ⁵,7λ⁵-diphospha-dispiro[4.1.4.1]dodecane | 92344-04-2

分子结构分类

有机化合物 - 有机杂环化合物 - 二氧磷杂环戊烷

中文名称

——

中文别名

——

英文名称

5,6,7,12-Tetramethyl-2,2,3,3,9,9,10,10-octakis-trifluoromethyl-1,4,8,11-tetraoxa-6,12-diaza-5λ⁵,7λ⁵-diphospha-dispiro[4.1.4.1]dodecane

英文别名

5,6,7,12-Tetramethyl-2,2,3,3,9,9,10,10-octakis(trifluoromethyl)-1,4,8,11-tetraoxa-6,12-diaza-5lambda5,7lambda5-diphosphadispiro[4.1.47.15]dodecane；5,6,7,12-tetramethyl-2,2,3,3,9,9,10,10-octakis(trifluoromethyl)-1,4,8,11-tetraoxa-6,12-diaza-5λ5,7λ5-diphosphadispiro[4.1.47.15]dodecane

5,6,7,12-Tetramethyl-2,2,3,3,9,9,10,10-octakis-trifluoromethyl-1,4,8,11-tetraoxa-6,12-diaza-5λ<sup>5</sup>,7λ<sup>5</sup>-diphospha-dispiro[4.1.4.1]dodecane化学式

CAS

92344-04-2

化学式

C₁₆H₁₂F₂₄N₂O₄P₂

mdl

——

分子量

814.191

InChiKey

BTSPVCOZXJGTNU-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

8.5
重原子数：

48
可旋转键数：

0
环数：

3.0
sp3杂化的碳原子比例：

1.0
拓扑面积：

43.4
氢给体数：

0
氢受体数：

30

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	2-azido-2,2-dimethyl-4,4,5,5-tetrakis-trifluoromethyl-2λ⁵-[1,3,2]dioxaphospholane	66436-22-4	C₈H₆F₁₂N₃O₂P	435.109

反应信息

作为产物：

描述：

2-azido-2,2-dimethyl-4,4,5,5-tetrakis-trifluoromethyl-2λ⁵-[1,3,2]dioxaphospholane 以乙腈为溶剂，生成 5,6,7,12-Tetramethyl-2,2,3,3,9,9,10,10-octakis-trifluoromethyl-1,4,8,11-tetraoxa-6,12-diaza-5λ⁵,7λ⁵-diphospha-dispiro[4.1.4.1]dodecane

参考文献：

名称：

Majoral, Jean-Pierre; Bertrand, Guy; Ocando-Mavarez, Edgar, Bulletin des Societes Chimiques Belges, 1986, vol. 95, # 11, p. 945 - 958

摘要：

DOI：

点击查看最新优质反应信息

文献信息

First evidence for a Curtius-type rearrangement involving a pentacoordinated atom

作者：Antoine Baceiredo、Guy Bertrand、Jean Pierre Majoral、Ulrich Wermuth、Reinhard Schmutzler

DOI：10.1021/ja00335a032

日期：1984.11

同类化合物

尿苷5'-二磷酸酯溴乙酰醇 N,N-二乙基-4-甲基-1,3,2-二氧杂磷杂环戊烷-2-胺 4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷-2-醇 2-氯-4-甲基-1,3,2-二氧杂磷杂环戊烷 2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷 2-氯-1,3,2-二氧磷杂环戊烷 (3,5-二甲基苯基)[羟基(吡啶-4-基甲基)-lambda~5~-氮烷基]甲酮 2-Dipropylamino-<1,3,2 λ³>dioxaphospholan 2-ethoxy-[1,3,2]oxazaphospholidine Ethylen-2.2.2-trifluorethylphosphit-ozonid 2-dimethylamino-(3ar,9ac,3'ar',9'ac')-hexadecahydro-2λ5-[2,2']spirobi(cycloocta[1,3,2]dioxaphosphole) 2,7-dimethyl-1,4,6,9-tetraoxa-5(λ⁵)-phosphaspiro<4.4>nonane Aethylenselenit 4,5-bis-trifluoromethyl-2λ⁵-spiro[[1,3,2]dioxaphosphole-2,1'-(2,8,9-trioxa-1-phospha-adamantane)] 5,5-Difluoro-1,4,6,9-tetraoxa-5λ⁶-tellura-spiro[4.4]nonane N-methyl-1-(1,4,6,9-tetraoxa-5λ5-phosphaspiro[4.4]nonan-5-yl)-N-(1,4,6,9-tetraoxa-5λ5-phosphaspiro[4.4]nonan-5-ylmethyl)methanamine 2-methyl-5-(2,2,2-trichloroethoxy)-1,4,6,9-tetraoxa-5λ5-phosphaspiro[4.4]nonan-3-one Butan-2,3-diylselenit (4r,5t-dimethyl-[1,3,2]dioxaphospholan-2-yl)-dimethyl-amine 3,3-dibromo-2-fluoro-4-propyl-1,2λ⁵-oxaphosphetane 2-Fluor-2,2-dibrom-4,4,5,5-tetrakis-(trifluormethyl)-(1,3,2λ⁵-dioxaphospholan [1,3,2]dioxaphospholan-2-yl-ethyl-amine 2-tert-butylamino-2,2-difluoro-4,4,5,5-tetrakis-trifluoromethyl-2λ⁵-[1,3,2]dioxaphospholane 3,3-dichloro-2-fluoro-4-propyl-1,2λ⁵-oxaphosphetane 1,1-Dibromo-3,5,8-tris-(1,1,2,2-tetrafluoro-ethyl)-2,6,7-trioxa-1λ⁵,4-diphospha-bicyclo[2.2.2]octane 2-Brom-4,4,5,5-tetrakis-(trifluormethyl)-(1,3,2λ⁵-dioxaphospholan dibutyl-(4-methyl-[1,3,2]dioxaphospholan-2-yl)-amine 2-(tert-butylimino)-1,3,2,4-oxaazaphosphaboretidine 1,1,3,3,5,5,7,7-Tetrakis--tetraphosphazatetraen 2-Chlor-2,2-dibrom-4,4,5,5-tetrakis-(trifluormethyl)-(1,3,2λ⁵-dioxaphospholan 2-Propoxy-[1,3,2]dioxaphospholan-4-one 2-Fluor-2,2-dichlor-4,4,5,5-tetrakis-(trifluormethyl)-(1,3,2λ⁵-dioxaphospholan 2-fluoro-3-methyl-[1,3,2]oxazaphospholidine 2,2,2,4-tetrachloro-3-isopropyl-4-triflyoromethyl-1,3,2-λ⁵-oxazaphosphetane 1,1-Dichloro-3,5,8-tris-(1,1,2,2-tetrafluoro-ethyl)-2,6,7-trioxa-1λ⁵,4-diphospha-bicyclo[2.2.2]octane 2-ethoxy-2-fluoro-2λ⁵-[1,3,2]dioxaphospholan-2-yl phosphoric acid-(2-ethyl-2-butyl-propanediyl ester)-(2-bromo-propyl ester) (4,4-dimethyl-1,3,2-dioxaphospholan-2-yl) 2,2,2-trifluoroacetate 2-Dimethylamino-4,4,5,5-tetrakis(trifluormethyl)-1,3,2λ³-dioxaphospholan 2,3,3-Trichloro-2,2-diethyl-4-trichloromethyl-2λ⁵-[1,2]oxaphosphetane (5-tert-butyl-[1,3,2]dioxaphosphinan-2-yl)-dimethyl-amine 2-cyclohexyl-[1,3,2]dioxaphospholane (4-tert-Butyl-[1,3,2]dioxaphospholan-2-yl)-diethyl-amine N-Methyl-N-[1-methyl-2-(4,4,5,5-tetramethyl-[1,3,2]dioxaphospholan-2-yloxy)-propyl]-acetamide 2,2-Dichlor-2-dimethylamino-4,4,5,5-tetrakis(trifluormethyl)-1,3,2λ⁵-dioxaphospholan methyl-2-trioxaphosphocanne-1,3,6,2 5-dimethylamino-2,4-diisopropylidene-1,3,6,9-tetraoxa-5λ5-phospha-spiro[4.4]nonane

5,6,7,12-Tetramethyl-2,2,3,3,9,9,10,10-octakis-trifluoromethyl-1,4,8,11-tetraoxa-6,12-diaza-5λ⁵,7λ⁵-diphospha-dispiro[4.1.4.1]dodecane | 92344-04-2

分子结构分类

计算性质

上下游信息

反应信息

文献信息

同类化合物

相关结构分类

热门分子

5,6,7,12-Tetramethyl-2,2,3,3,9,9,10,10-octakis-trifluoromethyl-1,4,8,11-tetraoxa-6,12-diaza-5λ5,7λ5-diphospha-dispiro[4.1.4.1]dodecane | 92344-04-2

分子结构分类

计算性质

上下游信息

反应信息

文献信息

同类化合物

相关结构分类

热门分子

5,6,7,12-Tetramethyl-2,2,3,3,9,9,10,10-octakis-trifluoromethyl-1,4,8,11-tetraoxa-6,12-diaza-5λ⁵,7λ⁵-diphospha-dispiro[4.1.4.1]dodecane | 92344-04-2