2,2'-((2-(((5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy)methyl)-2-ethylpropane-1,3-diyl)bis(oxy))bis(5,5-dimethyl-1,3,2-dioxaphosphinane) | 1159791-88-4

• 英文名称: 2,2'-((2-(((5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy)methyl)-2-ethylpropane-1,3-diyl)bis(oxy))bis(5,5-dimethyl-1,3,2-dioxaphosphinane)
• CAS: 1159791-88-4
• 化学式: C₂₁H₄₁O₉P₃
• 分子量: 530.472
• InChiKey: UVFHGGVBYOYNKG-UHFFFAOYSA-N

物化性质

• 沸点：
  491.2±35.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.33
• 重原子数：
  33.0
• 可旋转键数：
  10.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  83.07
• 氢给体数：
  0.0
• 氢受体数：
  9.0

反应信息

• 作为反应物：
  描述：

  2,2'-((2-(((5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy)methyl)-2-ethylpropane-1,3-diyl)bis(oxy))bis(5,5-dimethyl-1,3,2-dioxaphosphinane) 在 过氧化脲素 作用下， 以 四氯化碳 为溶剂， 反应 4.0h， 以75%的产率得到2-[2,2-Bis[(5,5-dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-ium-2-yl)oxymethyl]butoxy]-5,5-dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-ium
  参考文献：
  名称：

  Tris-phosphorylated esters of symmetrical and unsymmetrical triols

  摘要：

  By reaction of a series of triols and monosaccharides with 5,5-dimethyl-2-chloro-1,3,2-dioxaphosphorinane their tris-phosphorylated derivatives were synthesized, and the simplest chemical transformations of the latter were studied. Structures of the obtained P(V) derivatives were confirmed by (1)H, (13)C and (31)P NMR spectroscopy and by the MALDI TOF mass spectrometry and X-ray structural analysis.

  DOI：

  10.1134/s1070363208050083
• 作为产物：
  描述：

  三羟甲基丙烷 、 2-氯-5,5-二甲基-1,3,2-二氧磷杂环己烷 在 三乙胺 作用下， 反应 1.5h， 以0.98 g的产率得到2,2'-((2-(((5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)oxy)methyl)-2-ethylpropane-1,3-diyl)bis(oxy))bis(5,5-dimethyl-1,3,2-dioxaphosphinane)
  参考文献：
  名称：

  Tris-phosphorylated esters of symmetrical and unsymmetrical triols

  摘要：

  By reaction of a series of triols and monosaccharides with 5,5-dimethyl-2-chloro-1,3,2-dioxaphosphorinane their tris-phosphorylated derivatives were synthesized, and the simplest chemical transformations of the latter were studied. Structures of the obtained P(V) derivatives were confirmed by (1)H, (13)C and (31)P NMR spectroscopy and by the MALDI TOF mass spectrometry and X-ray structural analysis.

  DOI：

  10.1134/s1070363208050083