rubidium perchlorate | 13510-42-4

• 物质功能分类: 无机化工 - 无机盐 - 金属卤化物及卤酸盐
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱金属含氧阴离子化合物
• 英文名称: rubidium perchlorate
• 英文别名: rubidium(1+);perchlorate
• CAS: 13510-42-4
• 化学式: ClO₄*Rb
• 分子量: 184.918
• InChiKey: NQYGGOOZLKJKPS-UHFFFAOYSA-M

物化性质

• 熔点：
  281°C
• 沸点：
  decomposes at 606℃ [KIR79]
• 密度：
  2,8 g/cm3
• 稳定性/保质期：
  在常温常压下，该物质是稳定的。应避免与其接触的物料包括还原剂、易氧化材料、有机材料、金属粉末、硫磺、铝和铝合金以及镁。 在279℃时，会转变为立方晶体结构，并具有吸湿性。其溶解度随温度变化显著：在0℃时为1.1g/100gH2O，在25℃时升至1.8g/100gH2O，在100℃时达到221g/100gH2O；在甲醇中的溶解度为9×10-3g/100cm³（25℃），乙醇中为0.06g/100cm³（25℃）。 该物质的标准生成焓（ΔfH）为-437kJ/mol，标准生成吉布斯自由能（ΔfG）为-308kJ/mol，熵值（S）为164J/(K·mol)。熔点为281℃，而当温度达到606℃时会分解，密度为2.80g/cm³。 此外，在与有机物或有机金属化合物混合的情况下，可能发生爆炸。

计算性质

• 辛醇/水分配系数(LogP)：
  -7.75
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.3
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• TSCA：
  Yes
• 危险等级：
  5.1
• 危险品标志：
  O,Xn
• 安全说明：
  S17,S26,S36
• 危险类别码：
  R20/22,R8,R36/37/38
• WGK Germany：
  3
• 危险品运输编号：
  UN 1481 5.1/PG 2
• 包装等级：
  II
• 危险类别：
  5.1
• 储存条件：
  常温密闭保存，阴凉通风干燥。

SDS

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Section 1: Product Identification
Chemical Name: Rubidium perchlorate, anhydrous (99.9%-Rb)
CAS Registry Number: 13510-42-4
Formula: RbClO4
EINECS Number: 236-840-1
Chemical Family: metal perchlorate salt
Synonym: Perchloric acid, rubidium salt.

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Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 13510-42-4 100% no data no data

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Section 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract. May affect thyroid and kidney functions
Primary Routes of Exposure: Ingestion
Eye Contact: Causes moderate irritation of the eyes.
Skin Contact: Causes moderate irritation of the skin.
Inhalation: May cause difficulty in breathing and irritate mucous membranes and respiratory tract.
No specific information is available on the physiological effects of ingestion. May cause gastrointestinal
Ingestion:
irritation, nausea, and vomiting.
Acute Health Affects: Irritating to skin, eyes and respiratory tract.
Chronic Health Affects: Perchlorates reversibly inhibit thyroid iodine uptake. Kidney function may be affected.
NTP: No
IARC: No
OSHA: No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

---

SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: Water spray
Spray closed containers with water until fire is out. Avoid contact with combustible material. Fire fighters
Special Fire Fighting Procedures:
should be equipped with a NIOSH approved self-contained breathing apparatus.
Hazardous Combustion and If involved in a fire this material may emit corrosive hydrogen chloride fumes.
Decomposion Products:
Releases oxygen on heating. May decompose explosively under fire fighting conditions. Do not mix with
Unusual Fire or Explosion Hazards:
combustibles.

---

SECTION 6: Accidental Release Measures
Do not mix spilled powder with any combustible materials, such as sawdust. Sweep up the solid and dilute
Spill and Leak Procedures:
with water.

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SECTION 7: Handling and Storage
Store in a tightly sealed container in a cool dry place away from combustible and flammable materials. If the
Handling and Storage:
container is left open, salt may adsorb moisture from the atmosphere

---

SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: If possible, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form: white xtl.
Molecular Weight: 184.92
Melting Point: no data
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: 2.8
Odor: none
Solubility in Water: Soluble

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SECTION 10: Stability and Reactivity
Stability: Hygroscopic
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: Any contact with combustible matter.
Incompatibility: Reducing agents, organic matter, active metals, phosphorus, sulfur, hydrazine, hydroxylamine, strong acids
Decomposition Products: Oxygen, Rubidium oxide, hydrogen chloride,

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SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available

---

SECTION 12: Ecological Information
Ecological Information: No data available

---

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

---

SECTION 14: Transportation
Shipping Name (CFR): Perchlorates, Inorganic, N.O.S.
Hazard Class (CFR): 5.1
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN# 1481
Shipping Name (IATA): Perchlorates, Inorganic, N.O.S.
Hazard Class (IATA): 5.1
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN# 1481

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SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none

---

SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

水中溶解度(g/100ml)：不同温度(℃)时每100毫升水中的溶解克数为：

• 0℃: 1.09g
• 10℃: 1.19g
• 20℃: 1.55g
• 30℃: 2.2g
• 40℃: 3.26g
• 60℃: 6.27g
• 80℃: 11g
• 90℃: 15.5g
• 100℃: 22g

生产方法： 将等摩尔的HClO4和碳酸铷溶液混合，蒸发出过量的水，得到晶体。在水中重结晶纯化后，加热至150℃以上进行干燥。

反应信息

• 作为反应物：
  描述：

  rubidium perchlorate 以 neat (no solvent) 为溶剂， 以100%的产率得到rubidium chloride
  参考文献：
  名称：

  Braekken, H.; Harang, L., Zeitschrift fur Kristallographie und Mineralogie, 1930, vol. 75, p. 538 - 538

  摘要：

  DOI：
• 作为产物：
  描述：

  rubidium carbonate 在 aq. HClO₄ 作用下， 以 高氯酸 为溶剂， 生成 rubidium perchlorate
  参考文献：
  名称：

  Tarasov, V. P.; Meladze, M. A.; Kirakosyan, G. A., Koordinatsionnaya Khimiya, 1992, vol. 18, p. 707 - 717

  摘要：

  DOI：
• 作为试剂：
  描述：

  秋水仙碱 在 rubidium perchlorate 作用下， 以 甲醇 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  秋水仙碱与单价金属阳离子盐的复合物的抗真菌，抗癌和对接研究。

  摘要：

  已经获得了秋水仙碱与一价阳离子高氯酸盐和碘化物的配合物，并通过光谱法对其进行了表征。DFT和光谱研究表明，对秋水仙碱生物学作用机制（即与微管蛋白的结合）至关重要的二面角ω1-1a-12-12a取决于复合金属阳离子的直径。生物学测试表明秋水仙碱没有抗真菌特性（秋水仙碱仅对A.pullulans有活性），与其衍生物-（秋水仙碱）相反。秋水仙碱与金属阳离子的络合可显着提高抗真菌效力，甚至低于MIC <1μg/ ml。秋水仙碱复合物比秋水仙碱更有效，其中一些甚至比杀菌标准IPBC更有效。观察到秋水仙碱复合物对A.pululans的最高效力（MIC = 0.5μg/ ml）。与有关抗真菌效力的发现相反，抗癌研究表明秋水仙碱的复合物（〜IC50 = 2 nM）比秋水仙碱的复合物（〜IC50 = 6μM）更有活性。还测试了MDA-MB-231乳腺癌细胞系和人肺成纤维细胞CCD39Lu。

  DOI：

  10.1111/cbdd.13583

文献信息

• Ethynylpyrene Linked Benzocrown Ethers as Fluorescent Sensors for Metal Ions
  作者：Hajime Maeda、Kazuhiro Tanaka、Mona Aratani、Masahito Segi

  DOI：10.1111/php.13071

  日期：2019.5

  complexes with metal ions. Results of experiments employing repeated addition and removal of Mg(ClO4)2 demonstrate that the ON‐OFF fluorescence response can be repeated at least three times. Results of molecular orbital calculations show that complexation with metal ions lowers the energies of both the π and π* levels of the ethynylpyrene moiety and that in some cases the vacant orbital on the metal becomes

  合成了含有与一种或四种苯并冠醚相连的乙炔基芘的物质，并评估了它们对金属离子的吸收和荧光光谱响应。向这些物质的溶液中添加金属高氯酸盐会促进它们的吸收和荧光最大值的短波长偏移并增加它们的荧光强度。荧光强度增加的幅度取决于环的大小和冠醚的数量以及金属阳离子的性质。使用荧光强度与浓度数据计算复合物形成的结合常数。使用乔布斯图的分析表明，含有一个苯并冠醚部分的物质与金属离子形成 1:1 的络合物。重复添加和去除 Mg(ClO4)2 的实验结果表明，ON-OFF 荧光响应可以重复至少 3 次。分子轨道计算结果表明，与金属离子的络合降低了乙炔基芘部分的 π 和 π* 能级，在某些情况下，金属上的空轨道变成了配合物的 LUMO。从静电排斥和结构调节方面提出了对金属离子促进的光谱变化的解释。分子轨道计算结果表明，与金属离子的络合降低了乙炔基芘部分的 π 和 π* 能级，在某些情况下，金属上的空轨道变成了配合物的
• Crown Ether Palladacycles as Metalloligands: Suitable Precursors for Tetranuclear Mixed Transition/Non-Transition Metal Complexes
  作者：Samuel Castro-Juiz、Alberto Fernández、Margarita López-Torres、Digna Vázquez-García、Antonio J. Suárez、José M. Vila、Jesús J. Fernández

  DOI：10.1021/om900390a

  日期：2009.12.14

  Pb(SCN)2, RbClO4, and Ba(ClO4)2 gave the corresponding products in which the cation (Na+, K+, NH4+, Pb2+, Rb+, Ba2+) was coordinated to the crown ether moiety. The structures of compounds 1a and 6a (a complex with one Na+ cation coordinated to each crown ether group) have been determined by X-ray single-crystal diffraction analysis.

  Pd（OAc）2与席夫碱配体2,3,4-（MeO）3 C 6 H 2 C（H）═N-[9,10-（C 8 H 16 O 5）C 6 H 3的反应]（a）和2,3,4-（MeO）3 C 6 H 2 C（H）═N[9,10-（C 10 H 20 O 6）C 6 H 3 ]（b）导致环化金属化合物[Pd 2,3,4-（MeO）3 C 6 HC（H）═N-[9,10-（C 8 H 16 O 5）C 6 H ^ 3 ] - C6，N }（μ-O 2 CME）] 2（1A）和[钯2,3,4-（MEO）3 Ç 6 HC（H）= N [9,10- （C 10 H ^ 20 ö 6）C 6 H ^ 3 ] - C6，N }（μ-O 2 CME）] 2（图1b），分别通过C-H活化。1a与四丁基氯化铵水溶液的复分解反应得到相应的带有桥联氯化物配体2a的环钯二聚体。用NaClO 4处理二聚体化合物，KClO
• Unique structural topologies involving metal–metal and metal–sulfur interactions: salts of [Ni(C3S5)2]x− with cis-anti-cis-dicyclohexyl-18-crown-6 complexed counter ions
  作者：Leroy Cronin、Stewart J. Clark、Simon Parsons、Takayoshi Nakamura、Neil Robertson

  DOI：10.1039/b008299f

  日期：——

  Preparation by electrocrystallisation has been carried out for the salts [Rb(anti-dchyl-18c6)]2[Ni(dmit)2] 1, [Rb(anti-dchyl-18c6)][Ni(dmit)2] 2, [Cs(anti-dchyl-18c6)]2[Ni(dmit)2] 3 and [Cs(anti-dchyl-18c6)1.5][Ni(dmit)2]64 (anti-dchyl-18c6 = cis-anti-cis-dicyclohexyl-18-crown-6, dmit = C3S5). Salts 1 and 3 involve the planar dianionic nickel complex sandwiched by two metal–crown units. This leads to short Rb+ ⋯ Ni and Rb+ ⋯ S interactions in 1 and the shortest recorded Cs+ ⋯ Ni distance of 3.47 Å in 3, presumably stabilised by the four surrounding S atoms at 3.73–4.44 Å. DFT calculations on the dianionic salts 1 and 3 indicate an essentially electrostatic interaction between the [Ni(dmit)2]2− complex and the Rb+ or Cs+ ion and show frontier orbitals qualitatively similar to those previously derived from EHMO calculations on molecular conductors containing [Ni(dmit)2]. Salt 2 consists of non-stacked nickel complexes arranged in chains linked by S ⋯ Rb+ interactions through the terminal sulfurs with the Rb+ ion placed exactly within the plane of the crown oxygens. Magnetic susceptibility measurement indicated weak antiferromagnetic interactions. Salt 4 shows a 2-D sheet of nickel complexes stacked in a herringbone arrangement separated by layers of counter ions complexed by the crowns in a disordered manner with the anion ∶ cation ratio of 6 ∶ 1 uniquely high among [Ni(dmit)2]x− salts. Salt 4 displays semiconductor behaviour with σRT = 10−2 S cm−1.

  通过电结晶法制备了 [Rb(anti-dchyl-18c6)]2[Ni(dmit)2] 1、[Rb(anti-dchyl-18c6)][Ni(dmit)2] 2、[Cs(anti-dchyl-18c6)]2[Ni(dmit)2] 3 和 [Cs(anti-dchyl-18c6)1.5][Ni(dmit)2]64（anti-dchyl-18c6 = cis-anti-cis-dicyclohexyl-18-crown-6, dmit = C3S5）。盐 1 和盐 3 包含夹在两个金属冠单元中的平面二离子镍络合物。这导致 1 中的 Rb+ââ¯ââNi 和 Rb+ââ¯âS 相互作用较短，而 3 中记录的最短 Cs+ââ¯âNi 距离为 3.47 Ã，可能是由周围的四个 S 原子稳定在 3.73â4.44 Ã。对二离子盐 1 和 3 的 DFT 计算表明，[Ni(dmit)2]2â 复合物与 Rb+ 或 Cs+ 离子之间基本上存在静电作用，并显示出与之前通过对含有 [Ni(dmit)2] 的分子导体进行 EHMO 计算得出的前沿轨道性质相似的前沿轨道。盐 2 由非堆叠的镍络合物组成，这些镍络合物通过末端的硫以 Sââ¯âRb+ 相互作用连接成链，Rb+ 离子正好位于冠氧原子的平面内。磁感应强度测量结果表明，它们之间存在微弱的反铁磁相互作用。盐 4 显示了一个以人字形排列方式堆叠的二维片状镍络合物，它被由冠氧根络合的反离子层以无序的方式隔开，其阴离子§¶Â阳离子比率为 6§¶Â 1，在[Ni(dmit)2]xâ 盐中是独一无二的高比率。盐 4 具有ÏRT = 10â2 S cmâ1 的半导体特性。
• Supramolecular assemblies prepared from an iron(ii) tripodal imidazole complex. A molecular scaffolding for the self assembly of icosahedral complexes of K+, Rb+, Cs+ and NH4+ cations
  作者：Greg Brewer、Ray J. Butcher、Carol Viragh、Genevieve White

  DOI：10.1039/b704823h

  日期：——

  and 37% low spin, LS, at 295 K to pure LS in the double salts. Attempts to incorporate sodium or silver in the above salts failed due to their size and oxidizing strength, respectively. The analogous manganese complex, [MnH3L1](ClO4)2, failed to give these double salts under identical reaction conditions. The lack of reactivity of [MnH3L1](ClO4)2 does not appear to be due to its solubility or geometric

  三（2-氨基乙基）胺（叔戊）的1：3席夫碱缩合物与2-咪唑甲醛，H 3 L 1，[FeH 3 L 1 ]（ClO 4）2的铁（II）配合物与MClO 4（M ＝ K，Rb，Cs和NH 4）。产物为式[FeH 3 L 1 ]（ClO 4）2 }·MClO 4的复盐。通过元素分析，X射线晶体学，ESMS，IR和Mössbauer光谱对复合物进行了表征。所得的络合物均为三角形，在P中结晶并在扩展晶格中显示六聚体结构。阳离子位于c轴的原点（0，0，0）和c / 2（0，0，0.5）处。阳离子为十二个坐标，并表现出由六个二齿高氯酸根阴离子形成的扭曲的二十面体几何形状。高氯酸根阴离子与位于六边形顶点的铁络合物发生广泛的氢键结合。每个高氯酸根阴离子具有与三个铁配合物的五个氢键。铁络合物使用咪唑N H和亚胺N C H作为高氯酸盐氧原子的供体。咪唑N H是三叉供体，亚胺C H是分叉的捐助者。双盐的形成和伴
• An Aluminum-Based Metal–Organic Cage for Cesium Capture
  作者：Stefan Ilic、Ann M. May、Pavel M. Usov、Hannah D. Cornell、Bradley Gibbons、Paula Celis-Salazar、Daniel R. Cairnie、James Alatis、Carla Slebodnick、Amanda J. Morris

  DOI：10.1021/acs.inorgchem.2c00445

  日期：2022.5.2

  where at low concentrations, Cs+ binds to Al-pdc-AA in a 1:1 ratio. The binding site was identified from the crystal structure of CsH7[Al8(pdc)8(OAc)8O4] (Cs+⊂Al-pdc-AA), and a binding affinity of ∼106–107 M–1 was determined from NMR titration experiments. The Al-pdc-AA showed improved selectivity for cesium binding over alkali metal cations (Cs+ > Rb+ > K+ ≫ Na+ ∼ Li+). Collectively, the study reports

  金属-有机笼是一类超分子结构，通常需要仔细选择有机接头和金属节点。在这一类中，很少有金属有机笼的例子，其中节点由主族金属组成。在此，我们制备了铝基金属有机笼，H 8 [Al 8 (pdc) 8 (OAc) 8 O 4] (Al-pdc-AA)，使用廉价和市售的材料。在封端剂乙酸的存在下，通过溶剂化铝和吡啶-二羧酸接头的溶剂热自组装实现了笼的形成。获得的超分子结构通过单晶X射线衍射（SCXRD）、热重分析和核磁共振光谱进行了表征。基于晶体结构和计算分析，笼子有一个直径为 3.7 Å 的富电子空腔，适用于结合阳离子如铯（离子半径为 1.69 Å）。在 DMSO 中用1 H 和133 Cs NMR 光谱探测主客体相互作用，其中在低浓度下，Cs +以 1:1 的比例与 Al-pdc-AA 结合。结合位点由 CsH 7 [Al 8 (pdc) 8 (OAc) 8 O 4 ] (Cs + ⊂ Al-p