Me2C(η5-C5H4)2VCl2 | 875008-41-6

• 英文名称: Me2C(η5-C5H4)2VCl2
• CAS: 875008-41-6
• 化学式: C₁₃H₁₄Cl₂V
• 分子量: 292.102
• InChiKey: OSJYJRNYLNYECY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Me2C(η5-C5H4)2VCl2 、 sodium carbonate 以 水 为溶剂， 生成
  参考文献：
  名称：

  Ansa-vanadocene complexes with short interannular bridges

  摘要：

  The new ansa-vanadocene complexes with short interannular bridges (CH3)(2)C(C5H4)(2)VX2 (X = Cl, Br) were prepared, characterized by spectroscopic methods and X-ray structural analysis. It was shown, that connection of cyclopentadienyl rings by dimethylmethane bridge affects the structural parameters. The behavior ansa-vanadocene dichloride in aqueous solution in presence of bio-ligands was studied by EPR spectroscopy. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.08.024
• 作为产物：
  描述：

  (acetylacetonate)2VCl*THF 、 2,2-dicyclopentadienylpropane 、 三氯化磷 在 n-BuMgCl 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 以5.6%的产率得到Me2C(η5-C5H4)2VCl2
  参考文献：
  名称：

  Ansa-vanadocene complexes with short interannular bridges

  摘要：

  The new ansa-vanadocene complexes with short interannular bridges (CH3)(2)C(C5H4)(2)VX2 (X = Cl, Br) were prepared, characterized by spectroscopic methods and X-ray structural analysis. It was shown, that connection of cyclopentadienyl rings by dimethylmethane bridge affects the structural parameters. The behavior ansa-vanadocene dichloride in aqueous solution in presence of bio-ligands was studied by EPR spectroscopy. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.08.024