Krypton bis[pentafluoro-oxotellurate(<scp>VI</scp>)], Kr(OTeF<sub>5</sub>)<sub>2</sub>, the first example of a Kr–O bond
作者:Jeremy C. P. Sanders、Gary J. Schrobilgen
DOI:10.1039/c39890001576
日期:——
Kryptonbis[pentafluoro-oxotellurate(VI)] provides the firstexample of a species containing a krypton–oxygen bond and has been prepared by the reaction of KrF2 with natural abundance and 17O-enriched B(OTeF5)3 at –90 to –112 °C in SO2CIF solvent; characterization of the thermally unstable Kr(OTeF5)2 and its decomposition products has been achieved using 19F and 17O n.m.r. spectroscopy.