iminodisulfuryl chloride | 15588-41-7

• 英文名称: iminodisulfuryl chloride
• 英文别名: chloro imido disulfurylfluoride；N-chloro-N-fluorosulfonylsulfamoyl fluoride
• CAS: 15588-41-7
• 化学式: ClF₂NO₄S₂
• 分子量: 215.586
• InChiKey: DZYZSTILZCEGKN-UHFFFAOYSA-N

物化性质

• 熔点：
  -52 °C
• 密度：
  2.152±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  88.3
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  iminodisulfuryl chloride 、 偏氟乙烯 生成 N-(2-chloro-1,1-difluoroethyl)-N-fluorosulfonylsulfamoyl fluoride
  参考文献：
  名称：

  COLBURN C. B.; HILL W. E.; VERMA R. D., J. FLUOR. CHEM., 1981, 17, NO 1, 75-84

  摘要：

  DOI：
• 作为产物：
  描述：

  mercury(II) bis(bis(fluorosulphuryl)imide) 、 氯 以 neat (no solvent) 为溶剂， 以89%的产率得到iminodisulfuryl chloride
  参考文献：
  名称：

  Synthesis of Poly- and the First Perfluoroalkyl-N(SO₂F)₂ Derivatives:  Improved Methods for the Preparation of XN(SO₂F)₂ (X = H, Cl) and Single-Crystal Diffraction Studies of HN(SO₂Cl)₂, HN(SO₂F)₂, and CF₃CH₂N(SO₂F)₂

  摘要：

  The preparation of HN(SO2F)(2) was achieved conveniently by fluorination of HN(SO2Cl)(2) with SbF3. Reactions of Hg[N(SO2F)(2)](2) with fluoroalkyl iodides RI (R = i-C3F7CH2CH2 and CF3CH2) gave i-C3F7CH2CH2N(SO2F)(2) (1) and CF3CH2N(SO2F)(2) (2). The chlorination of Hg[N(SO2F)(2)](2) provided a high-yield method of synthesizing the well-known ClN(SO2F)(2). N-alkylation of ClN(SO2F)(2) with fluorinated ethenes CF2=CHal(2) (CHal(2) = CF2, CFCl, and CCl2) resulted in the formation of CF2ClCF2N(SO2F)(2) (3), CF2ClCFClN(SO2F)(2) (4a, major), CFCl2-CF2N(SO2F)(2) (4b, minor), and CCl3CF2N(SO2F)(2) (5). The synthesis of the first perfluoroalkyl-N(SO2F)(2) derivatives CF3N(SO2F)(2) (6), C2F5N(SO2F)(2) (7), n-C3F7N(SO2F)(2) (8), and n-C4F9N(SO2F)(2) (9) was accomplished with moderate-to-good yields by reacting ClN(SO2F)(2) with iodoperfluoroalkanes RFI (R-F = CF3, C2F5. n-C3F7, and n-C4F9). Similarly, Cln(SO2F)(2) reacted with CF3CH2I to give 2. Photolysis of ClN(SO2F)(2) with iodoperfluoroalkanes RFI (RF n-C3F7, and n-C4F9) gave 8 and 9 in low yields. HN(SO2F)(2) belongs to a monoclinic crystal system P2(1) (No. 4): a = 5.1619(5) Angstrom, b = 7.8153(8) Angstrom, c = 6.8028(7) Angstrom, beta = 100.411(2)degrees, V = 269.92(5) Angstrom(3), Z = 2. HN(SO2Cl)(2) is monoclinic P2(1)/c (No. 14): a = 7.7331(3) Angstrom, b = 10.0542(2) Angstrom, c = 9.3197(3) Angstrom, beta = 109.495(1)degrees, V = 683.07(4) Angstrom(3), Z = 3. CF3CH2N(SO2F)(2) is orthorhombic P2(1)2(1)2(1) (No. 19): a = 11.1245(1) Angstrom, b = 28.8003(4) Angstrom, c = 7.7120 Angstrom, V = 2470.90(4) Angstrom(3), Z = 12.

  DOI：

  10.1021/ic9800031
• 作为试剂：
  描述：

  bis(trifluoromethyl)diazomethane 在 iminodisulfuryl chloride 作用下， 生成 (1-chloro-2,2,2-trifluoro-1-trifluoromethylethyl)imido bis(sulfonyl fluoride)
  参考文献：
  名称：

  Varwig,J. et al., Chemische Berichte, 1974, vol. 107, p. 2468 - 2472

  摘要：

  DOI：

文献信息

• Preparation of the first iminodisulfurylazide: A nitrogen bound covalent azide containing an N4 unit
  作者：Hagen Holfter、Thomas M. Klapötke、Axel Schulz

  DOI：10.1016/0277-5387(95)00412-2

  日期：1996.5

  Iminodisulfurylchloride, (FSO2)2NCl, reacted with activated sodium azide giving iminodisulfurylazide, (FSO2)2NN3, which was identified and characterized by vibrational (IR and Raman) and NMR spectroscopy (14N and 19F), mass spectrometry and ab initio computations.

  Iminodisulfurylchloride，（FSO 2）2 NCl，用活化的叠氮化钠给予iminodisulfurylazide反应，（FSO 2）2 NN 3，将其鉴定和表征通过振动（IR和Raman）和NMR光谱（14 N和19 ˚F ），质谱和从头算。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.9, 5, page 1 - 38
  作者：

  DOI：——

  日期：——
• Varwig, J.; Mews, R.; Glemser, O., Chemische Berichte, 1974, vol. 107, p. 2468 - 2472
  作者：Varwig, J.、Mews, R.、Glemser, O.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: C: MVol.D3, 6.2.5.6.7.12, page 239 - 239
  作者：

  DOI：——

  日期：——
• The Preparation and Chemistry of N-Chlorimidodisulfuryl Fluoride
  作者：John K. Ruff

  DOI：10.1021/ic50039a008

  日期：1966.5