mercury(II) bis(bis(fluorosulphuryl)imide) | 104693-53-0

• 英文名称: mercury(II) bis(bis(fluorosulphuryl)imide)
• 英文别名: mercury bis(fluorosulphuryl)imide
• CAS: 104693-53-0
• 化学式: 2F₂NO₄S₂*Hg
• 分子量: 560.856
• InChiKey: IAMKEXHGVKOELR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.21
• 重原子数：
  10.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  82.38
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  mercury(II) bis(bis(fluorosulphuryl)imide) 、 氯 以 neat (no solvent) 为溶剂， 以89%的产率得到iminodisulfuryl chloride
  参考文献：
  名称：

  Synthesis of Poly- and the First Perfluoroalkyl-N(SO₂F)₂ Derivatives:  Improved Methods for the Preparation of XN(SO₂F)₂ (X = H, Cl) and Single-Crystal Diffraction Studies of HN(SO₂Cl)₂, HN(SO₂F)₂, and CF₃CH₂N(SO₂F)₂

  摘要：

  The preparation of HN(SO2F)(2) was achieved conveniently by fluorination of HN(SO2Cl)(2) with SbF3. Reactions of Hg[N(SO2F)(2)](2) with fluoroalkyl iodides RI (R = i-C3F7CH2CH2 and CF3CH2) gave i-C3F7CH2CH2N(SO2F)(2) (1) and CF3CH2N(SO2F)(2) (2). The chlorination of Hg[N(SO2F)(2)](2) provided a high-yield method of synthesizing the well-known ClN(SO2F)(2). N-alkylation of ClN(SO2F)(2) with fluorinated ethenes CF2=CHal(2) (CHal(2) = CF2, CFCl, and CCl2) resulted in the formation of CF2ClCF2N(SO2F)(2) (3), CF2ClCFClN(SO2F)(2) (4a, major), CFCl2-CF2N(SO2F)(2) (4b, minor), and CCl3CF2N(SO2F)(2) (5). The synthesis of the first perfluoroalkyl-N(SO2F)(2) derivatives CF3N(SO2F)(2) (6), C2F5N(SO2F)(2) (7), n-C3F7N(SO2F)(2) (8), and n-C4F9N(SO2F)(2) (9) was accomplished with moderate-to-good yields by reacting ClN(SO2F)(2) with iodoperfluoroalkanes RFI (R-F = CF3, C2F5. n-C3F7, and n-C4F9). Similarly, Cln(SO2F)(2) reacted with CF3CH2I to give 2. Photolysis of ClN(SO2F)(2) with iodoperfluoroalkanes RFI (RF n-C3F7, and n-C4F9) gave 8 and 9 in low yields. HN(SO2F)(2) belongs to a monoclinic crystal system P2(1) (No. 4): a = 5.1619(5) Angstrom, b = 7.8153(8) Angstrom, c = 6.8028(7) Angstrom, beta = 100.411(2)degrees, V = 269.92(5) Angstrom(3), Z = 2. HN(SO2Cl)(2) is monoclinic P2(1)/c (No. 14): a = 7.7331(3) Angstrom, b = 10.0542(2) Angstrom, c = 9.3197(3) Angstrom, beta = 109.495(1)degrees, V = 683.07(4) Angstrom(3), Z = 3. CF3CH2N(SO2F)(2) is orthorhombic P2(1)2(1)2(1) (No. 19): a = 11.1245(1) Angstrom, b = 28.8003(4) Angstrom, c = 7.7120 Angstrom, V = 2470.90(4) Angstrom(3), Z = 12.

  DOI：

  10.1021/ic9800031
• 作为产物：
  描述：

  mercury(II) trifluoroacetate 、 亚氨基二硫酰氟 以 三氟乙酸 为溶剂， 生成 mercury(II) bis(bis(fluorosulphuryl)imide)
  参考文献：
  名称：

  Singh, Sukhjinder; Desmarteau, Darryl D., Inorganic Chemistry, 1986, vol. 25, # 25, p. 4596 - 4597

  摘要：

  DOI：
• 作为试剂：
  描述：

  乙烷 在 mercury(II) bis(bis(fluorosulphuryl)imide) 、 亚氨基二硫酰氟 作用下， 180.0 ℃ 、3.55 MPa 条件下， 反应 3.0h， 以60%Spectr.的产率得到N-ethyl-bis(fluorosulfonyl)imide
  参考文献：
  名称：

  [EN] DIRECT OXIDATIVE AMINATION OF HYDROCARBONS
  [FR] AMINATION OXYDATIVE DIRECTE D'HYDROCARBURES

  摘要：

  提供了一种将至少含有一个C-H键的碳氢化合物转化为氮功能化产物的过程。该过程包括将碳氢化合物与（i）包括（a）氧化形式的主族元素或过渡金属和（b）至少一个含氮配体的氧化亲电试剂，或者（ii）氧化剂和氧化亲电试剂的还原形式（a）主族元素或过渡金属和（b）至少一个含氮配体接触在溶剂中，以提供氮功能化产物和一个亲电试剂还原产物。还提供了一种氧化组合物，其中包括至少一个含氮配体的氧化亲电试剂和一种不可氧化的液体。

  公开号：

  WO2019109045A1

文献信息

• Singh, Sukhjinder; Vij, Ashwani; Lal, Mohan, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1989, vol. 28, # 10, p. 890 - 892
  作者：Singh, Sukhjinder、Vij, Ashwani、Lal, Mohan、Verma, R. D.

  DOI：——

  日期：——