申请人:Kemira OY
公开号:US05603911A1
公开(公告)日:1997-02-18
The object of the invention is a process for preparing a crystalline, stable sodium percarbonate, in which polymers of gross formulas (I or II) are added in the preparation process to control the crystal form of the sodium percarbonate and to coat the crystals, the molecular weight of the polymers varying in the range from 500 to 1,000,000 g/mol, or salts of these polymers or mixtures of polymers of formulas (I and It) or of their salts are added. Formula (I) denotes (I) and formula (II) denotes (II): HO--(--CH.sub.2 --CH.sub.2 --O).sub.r --(CHCH.sub.3 --CH.sub.2 --O).sub.s --(--CH.sub.2 --CH.sub.2 --O).sub.t --H and X<100% and Y>0%, R.sub.1 is --H or --CH.sub.3, R.sub.2 is --COOM, in which M may be H.sup.+ or a cation, in particular Na.sup.+, K.sup.+ or NH.sup.+.sub.4, R.sub.7 and R.sub.8 may be identical or different, being --COOM, --CONR.sub.5 R.sub.6, H, --OH or --COO(--CH.sub.2 --CH.sub.2 --O).sub.r --(CHCH.sub.3 --CH.sub.2 --O).sub.s --(--CH.sub.2 --CH.sub.2 --O).sub.t --H and R.sub.5 and R.sub.6 are --H or an alkyl group, in particular C.sub.1 --C.sub.4 and may be mutually identical or different groups and r, t and s may vary respectively in the range from 0 to 100%, their sum being 100%.
本发明的目的是提供一种制备晶体稳定的过碳酸钠的方法,其中在制备过程中添加具有总式(I或II)的聚合物以控制过碳酸钠的晶体形态并包覆晶体,聚合物的分子量在500至1,000,000克/摩尔范围内变化,或添加这些聚合物的盐或公式(I和II)或它们的盐的混合物。公式(I)表示(I),公式(II)表示(II):HO-(-CH.sub.2-CH.sub.2-O).sub.r-(CHCH.sub.3-CH.sub.2-O).sub.s-(-CH.sub.2-CH.sub.2-O).sub.t-H,其中X<100%且Y> 0%,R.sub.1为-H或-CH.sub.3,R.sub.2为-COOM,其中M可以是H.sup.+或阳离子,特别是Na.sup.+,K.sup.+或NH.sub.4.sup.+,R.sub.7和R.sub.8可以相同也可以不同,分别为-COOM,-CONR.sub.5R.sub.6,H,-OH或-COO(-CH.sub.2-CH.sub.2-O).sub.r-(CHCH.sub.3-CH.sub.2-O).sub.s-(-CH.sub.2-CH.sub.2-O).sub.t-H,其中R.sub.5和R.sub.6是-H或烷基,特别是C.sub.1-C.sub.4,并且可以是相互相同或不同的基团,r,t和s可以分别在0至100%的范围内变化,它们的总和为100%。