1-Hexacosanol, dihydrogen phosphate | 64131-15-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: 1-Hexacosanol, dihydrogen phosphate
• 英文别名: hexacosyl dihydrogen phosphate
• CAS: 64131-15-3
• 化学式: C₂₆H₅₅O₄P
• 分子量: 462.7
• InChiKey: JFVBBNIZHDGXAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.6
• 重原子数：
  31
• 可旋转键数：
  26
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  66.8
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• Crystalline polyolefin composition
  申请人：Chisso Corporation

  公开号：EP0416321A1

  公开（公告）日：1991-03-13

  A crystalline polyolefin composition which provides molded articles having improved stiffness characteristics is disclosed, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I): wherein R represents an alkylidene group having from 1 to 4 carbon atoms or a sulfur atom; Ar1 and Ar2, which may be the same or different, each represents an alkylarylene group or a cycloalkylarylene group; and n represents 0 or 1, and (B) from 0.001 to 1 part by weight of at least one compound selected from the group consisting of (1) an aliphatic monocarboxylic acid salt with lithium or sodium, (2) a dithiocarbamic acid salt with lithium, sodium or potassium, (3) a 2-mercaptobenzothiazole salt with lithium, sodium or potassium, (4) a 2-mercaptobenzimidazole salt with lithium, sodium or potassium and (5) a benzotriazole salt with lithium, sodium or potassium. A crystalline polyolefin composition which provides molded articles having improved stiffness charateristics is also disclosed, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I) shown above, (B ) from 0.001 to 1 part by weight of at least one compound selected from the group consisting of (1) an aliphatic monocarboxylic acid salt with potassium, strontium or barium, (2) a hydroxy-higher fatty acid salt with potassium, strontium or barium, (3) an aliphatic polycarboxylic acid salt with lithium, sodium, potassium, strontium or barium, (4) a salt of an aliphatic hydroxy acid having form 2 to 6 carbon atoms with lithium, sodium, potassium, magnesium, strontium or barium, (5) an aromatic carboxylic acid salt with lithium, sodium, strontium, barium or aluminum, (6) a glutamic acid salt with lithium, sodium, potassium, strontium or barium, (7) an aliphatic phosphoric acid salt with sodium, potassium, calcium, strontium or barium, (8) a lithium, sodium, potassium or barium salt of a cyclic phosphorus compound represented by formula (II): wherein Ar3 and Ar4, which may be the same or different, each represents an arylene group, an alkylarylene group, a cycloalkylarylene group, an arylarylene group or an aralkylarylene group; M represents lithium, sodium, potassium or barium; and m represents an atomic valence of M, (9) magnesium or aluminum hydroxide, (10) magnesium oxide, (11) magnesium or calcium carbonate and (12) hydrotalcite, and (C) from 0.01 to 1 part by weight of an aliphatic amine.

  本发明公开了一种结晶聚烯烃组合物，该组合物可提供具有改进的刚度特性的模塑制品，该组合物包括按重量计100份的结晶聚烯烃、(A)按重量计0.001至1份的由式(I)代表的亚磷酸氟化合物： 其中 R 代表具有 1 至 4 个碳原子的亚烷基或硫原子；Ar1 和 Ar2 可以相同或不同，各自代表烷基芳基或环烷基芳基；n 代表 0 或 1，以及 (B) 0.(1) 锂或钠的脂肪族一羧酸盐，(2) 锂、钠或钾的二硫代氨基甲酸盐、(3) 锂、钠或钾的 2-巯基苯并噻唑盐， (4) 锂、钠或钾的 2-巯基苯并咪唑盐， (5) 锂、钠或钾的苯并三唑盐。 本发明还公开了一种结晶聚烯烃组合物，该组合物可提供具有改进的刚度特性的模塑制品，其成分包括 100 份（重量）结晶聚烯烃、(A) 0.001 至 1 份（重量）由上文式(I)代表的亚磷酸氟化合物、(B ) 0.(1)钾、锶或钡的脂肪族一羧酸盐；(2)钾、锶或钡的羟基高级脂肪酸盐；(3)锂、钠、钾、锶或钡的脂肪族多羧酸盐；(4)锂、钠、钾、镁、锶或钡的具有 2 至 6 个碳原子的脂肪族羟基酸盐、(5) 锂、钠、锶、钡或铝的芳香族羧酸盐； (6) 锂、钠、钾、锶或钡的谷氨酸盐、(7) 含有钠、钾、钙、锶或钡的脂肪族磷酸盐， (8) 由式（II）代表的环磷化合物的锂、钠、钾或钡盐： 其中 Ar3 和 Ar4 可以相同或不同，各自代表芳基、烷芳基、环烷芳基、芳基芳基或芳基芳基；M 代表锂、钠、钾或钡；m 代表 M 的原子价，(9) 氢氧化镁或铝，(10) 氧化镁，(11) 碳酸镁或碳酸钙和 (12) 水滑石，以及 (C) 0.01至1份重量的脂肪族胺。
• PROPYLENE-ETHYLENE COPOLYMER COMPOSITIONS AND PROCESS FOR THE PRODUCTION THEREOF
  申请人：CHISSO CORPORATION

  公开号：EP0790262A1

  公开（公告）日：1997-08-20

  A propylene-ethylene copolymer composition is obtained which has a good moldability and is excellent in the balance of rigidity, toughness, and impact-strength. A propylene-ethylene copolymer composition having a melt flow rate of 10 to 300 g/10 minutes and obtained by producing 60 to 95 % by weight, based on the weight of whole polymer, of a propylene polymer having a melt flow rate (ASTM D-1238) in the range of 100 to 1,000 g/10 minutes and having a ratio (Cf) of integrated values of the propylene polymer dissolved in o-dichlorobenzene at a temperature of lower than 112°C, and a temperature of 112°C or higher, respectively, which is an index of the stereoregurality in molecules and molecular weight distribution, when the amounts of the propylene polymer dissolved therein at each of the temperatures were determined by raising the temperature of the o-dichlorobenzene continuously or stepwise, of 0.5 or less, by carrying out polymerization of propylene in the presence of a highly stereoregular catalyst and hydrogen in a polymerization step (I), and then producing 5 to 40 % by weight, based on the weight of whole polymer, of an ethylene-propylene copolymer by feeding ethylene and propylene to the propylene polymer produced in the polymerization step (I) to react so that the content of ethylene becomes 30 to 80 % by weight, in a polymerization step (II); and a propylene-ethylene copolymer composition comprising the composition mentioned above and a α-crystal and/or β-crystal nucleator added therewith.

  一种丙烯-乙烯共聚物组合物具有良好的成型性，并且在刚性、韧性和冲击强度的平衡方面表现优异。 一种熔体流动速率为 10 至 300 克/10 分钟的丙烯-乙烯共聚物组合物，通过以下方法获得 以整个聚合物的重量为基准，生产 60% 至 95% 重量百分比的丙烯聚合物，其熔体流动速率（ASTM D-1238）在 100 至 1,000 克/10 分钟范围内，在温度低于 112°C、和 112°C 或更高温度下溶解在邻二氯苯中的丙烯聚合物的综合值之比 (Cf)，这分别是分子立体性和分子量分布的指标，当通过连续或逐步提高邻二氯苯的温度 0.5 或更低，在聚合步骤 (I) 中，在高度立体配位催化剂和氢的存在下进行丙烯聚合，然后 在聚合步骤(II)中，通过向聚合步骤(I)中生成的丙烯聚合物中加入乙烯和丙烯进行反应，使乙烯的含量达到 30% 至 80%（以整个聚合物的重量计），生成 5% 至 40%（以重量计）的乙烯-丙烯共聚物；以及丙烯-乙烯共聚物组合物，该组合物包括上述组合物和加入其中的 α 结晶和/或 β 结晶成核剂。
• MODIFIED OLEFIN (CO)POLYMER COMPOSITION, PROCESS FOR PREPARING THE SAME, AND MODIFIED OLEFIN (CO)POLYMER COMPOSITION MOLDING
  申请人：CHISSO CORPORATION

  公开号：EP0972800A1

  公开（公告）日：2000-01-19

  A high molecular weight polyethylene prepared by preliminary polymerization is added at the time of main polymerization of an olefin, for example, propylene, to prepare an olefin (co)polymer composition comprising the above high molecular weight polyethylene finely dispersed as fine particles in the polyolefin, such as polypropylene, and a cross-linked structure is formed in the olefin (co)polymer composition. This process can provide a modified olefin (co)polymer composition improved in the strength in a molten state in terms of melt tension or the like and in crystallization temperature and excellent in moldability such as high-speed producibility and a molded modified olefin (co)polymer composition excellent in properties such as heat resistance and rigidity.

  在对烯烃（例如丙烯）进行主聚合时，加入通过预聚合制备的高分子量聚乙烯，以制备烯烃（共）聚合物组合物，该组合物由上述高分子量聚乙烯以细颗粒形式分散在聚烯烃（例如聚丙烯）中组成，并在烯烃（共）聚合物组合物中形成交联结构。这种工艺可以提供一种改性烯烃（共）聚合物组合物，它在熔融状态下的强度（如熔体张力等）和结晶温度方面都有所提高，并具有优异的成型性（如高速生产性），而且成型的改性烯烃（共）聚合物组合物具有优异的性能（如耐热性和刚性）。
• AQUEOUS-LIQUID-ABSORBABLE RESIN, AQUEOUS-LIQUID-ABSORBABLE COMPOSITION, AND ABSORBER MATERIAL AND ABSORBABLE OBJECT EACH PRODUCED USING SAME
  申请人：Sanyo Chemical Industries, Ltd.

  公开号：EP2690133A1

  公开（公告）日：2014-01-29

  An absorbable resin, for which a large amount of a plant-derived raw material can be used, and which has an excellent capability of absorbing an aqueous liquid, and has a good gel modulus and therefore can exhibit an excellent absorbing capability under pressurized conditions; and an absorbable composition. An absorbable resin produced by binding an oxidized polysaccharide (A1) having a carboxyl group which may be neutralized with a neutralizing agent and/or a crosslinked product thereof (A2) to a poly(meth)acrylic acid (B1) in which at least one carboxyl group may be neutralized with a neutralizing agent and/or a crosslinked product thereof (B2); or an absorbable composition produced by mixing the component (A1) and/or the component (A2) with the component (B1) and/or the component (B2). The component (A1) has a weight average molecular weight of 2,000-10,000,000. The component (A1) has an acid value of 65-850 mgKOH/g. When the component (A1) has a carboxyl group which is neutralized with a neutralizing agent, the acid value of the component (A1) before the neutralization is 65-850 mgKOH/g.

  一种可吸收树脂，可使用大量植物提取原料，具有极佳的吸收水性液体的能力，并具有良好的凝胶模量，因此可在加压条件下表现出极佳的吸收能力；以及一种可吸收组合物。将具有可被中和剂和/或其交联产物（A2）中和的羧基的氧化多糖（A1）与至少一个羧基可被中和剂和/或其交联产物（B2）中和的聚（甲基）丙烯酸（B1）结合而制得的可吸收树脂；或将组分（A1）和/或组分（A2）与组分（B1）和/或组分（B2）混合而制得的可吸收组合物。组分（A1）的重量平均分子量为 2,000-10,000,000 。组分（A1）的酸值为 65-850 mgKOH/g。当组分（A1）具有用中和剂中和的羧基时，中和前组分（A1）的酸值为 65-850 mgKOH/g。
• AQUEOUS LIQUID ABSORBING RESIN, AQUEOUS LIQUID ABSORBING COMPOSITION, AND ABSORBENT BODY AND ABSORBENT ARTICLE USING SAME
  申请人：Sanyo Chemical Industries, Ltd.

  公开号：EP2899224A1

  公开（公告）日：2015-07-29

  An absorbent resin and an absorbent composition that use a large amount of material derived from plants, have excellent aqueous liquid absorbing capability, and have excellent absorbing capability in a compressed state due to having a favorable gel elastic modulus. An absorbent resin made by bonding (A1) an oxidized polysaccharide having a carboxyl group that may be neutralized by a neutralizing agent, and/or (A2) a crosslinked compound thereof with (B1) a poly(meth)acrylic acid where at least one of the carboxyl groups may be neutralized by a neutralizing agent, and/or (B2) a crosslinked compound thereof; or an absorbent composition made by blending (A1) and/or (A2) and (B1) and/or the (B2) ; wherein the weight average molecular weight of (A1) is 2, 000 to 10, 000, 000, the acid value of (A1) is 65 to 524 mgKOH/g, and if (A1) has a carboxyl group that has been neutralized by a neutralizing agent, the acid value prior to neutralizing is 65 to 524 mgKOH/g.

  一种吸水树脂和一种吸水剂组合物，它们使用了大量从植物中提取的材料，具有极佳的水性液体吸收能力，并且由于具有良好的凝胶弹性模量而在压缩状态下具有极佳的吸收能力。一种吸水树脂，通过将（A1）具有可被中和剂中和的羧基的氧化多糖和/或（A2）其交联化合物与（B1）聚（甲基）丙烯酸（其中至少一个羧基可被中和剂中和）和/或（B2）其交联化合物粘合而成；或将(A1)和/或(A2)与(B1)和/或(B2)混合制成的吸水剂组合物；其中(A1)的重量平均分子量为2,000至10,000,000，(A1)的酸值为65至524 mgKOH/g，如果(A1)具有已被中和剂中和的羧基，则中和前的酸值为65至524 mgKOH/g。