Bis(p-nonylphenyl) hydrogen phosphate | 34332-97-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: Bis(p-nonylphenyl) hydrogen phosphate
• 英文别名: bis(4-nonylphenyl) hydrogen phosphate
• CAS: 34332-97-3
• 化学式: C₃₀H₄₇O₄P
• 分子量: 502.7
• InChiKey: TUBPQDOOWCNEEE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.8
• 重原子数：
  35
• 可旋转键数：
  20
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

文献信息

• CHROMIUM-BASED CATALYST COMPOSITION FOR PRODUCING CONJUGATED DIENE POLYMERS
  申请人：Bridgestone Corp.

  公开号：US20020115558A1

  公开（公告）日：2002-08-22

  A catalyst composition that is the combination of or the reaction product of ingredients comprising (a) a chromium-containing compound; (b) an organomagnesium compound; and (c) a silyl phosphonate. also, a process for forming conjugated diene polymers by using the catalyst composition.

  这是一个催化剂组合物的描述，由以下成分组成或反应生成：(a)含铬化合物；(b)有机镁化合物；和(c)硅基膦酸酯。同时，还提供了使用该催化剂组合物制备共轭二烯聚合物的方法。
• METHOD FOR PRODUCING MODIFIED CONJUGATED DIENE POLYMER/COPOLYMER, MODIFIED CONJUGATED DIENE POLYMER/COPOLYMER, AND RUBBER COMPOSITION AND TIER USING THE SAME
  申请人：Tanaka Ken

  公开号：US20110146877A1

  公开（公告）日：2011-06-23

  The invention provides a method for producing a modified conjugated diene (co)polymer, the method including comprising: a modification reaction step including causing an organic silane compound to react with a conjugated diene (co)polymer having an active site at the active site, the organic silane compound having a characteristic group for forming a silanol group through hydrolysis and, in the vicinity of the characteristic group, (i) a functional group which binds the organic silane compound to the conjugated diene (co)polymer via addition to or substitution at the active site and which promotes reaction between the silanol group and a reinforcing filler after the addition or substitution reaction, or (ii) a functional group which promotes reaction between the silanol group and a reinforcing filler, and a hydrolyzation step performed after the modification reaction step; a modified conjugated diene (co)polymer having, at a molecular end of the conjugated diene (co)polymer, a silanol group, and a functional group in the vicinity of the silanol group, the functional group accelerating reaction between the silanol group and the reinforcing filler; a rubber composition containing the (co)polymer and carbon black having specific characteristics; and a tire formed from the rubber composition.

  本发明提供了一种生产改性共轭二烯（共）聚合物的方法，该方法包括：修改反应步骤，包括使有机硅化合物与具有活性位点的共轭二烯（共）聚合物在活性位点处反应，所述有机硅化合物具有通过水解形成硅醇基团的特征基团，在特征基团附近，（i）通过加成或置换作用于活性位点，将有机硅化合物与共轭二烯（共）聚合物结合的功能基团，并促进加成或置换反应后硅醇基团和增强填料之间的反应，或（ii）促进硅醇基团和增强填料之间反应的功能基团；修改反应步骤后进行水解步骤；在共轭二烯（共）聚合物的分子末端具有硅醇基团和硅醇基团附近的功能基团的改性共轭二烯（共）聚合物；包含具有特定特性的碳黑的橡胶组合物；以及由该橡胶组合物形成的轮胎。
• Agricultural and horticultural guanidine-type fungicide and process for production thereof
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0155509A1

  公开（公告）日：1985-09-25

  @ An agricultural and horticultural fungicide of low phytotoxicity comprising as an active ingredient an addition salt between a fungicidal guanidine compound and an acid having an oleophilic group with at least 9 carbon atoms in total. The acid addition salt is produced by reacting a fungicidal guanidine compound or its acid addition salt with an acid having an oleophilic group with at least 9 carbon atoms in total or its salt.

  一种植物毒性低的农用和园艺杀菌剂，其有效成分包括杀菌胍化合物与具有总共至少 9 个碳原子的亲油基团的酸之间的加成盐。 酸加成盐是由杀菌胍化合物或其酸加成盐与具有总共至少 9 个碳原子的亲油基团的酸或其盐反应生成的。
• Crystaline block copolymer and process for producing the same
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0234512A2

  公开（公告）日：1987-09-02

  crystalline block copolymer containing at least a triblock chain represented by the formula A-B-C or containing at least a radial structure represented by the formula (D-EX in the polymer chain is provided. These triblock chains or radial structures comprise blocks of a homopolymer of a vinyl aromatic compound or a copolymer of a vinylaromatic compound with another vinylaromatic compound or a conjugated diene compound having a glass transition temperature of not lower that 50°C and a weight average molecular weight in the range of from 2,000 to 100,000 and blocks of a homopolymer of a conjugated diene compound or a copolymer of a conjugated diene compound with another conjugated diene compound or a copolymer of a conjugated diene compound having less that 20 wt.% of a vinyl aromatic compound having a glass transition temperature of not higher than 10°C and a crystallinity at 25°C and a 1,4-trans-linkage ratio in the conjugated diene portion of 80 % or higher. These crystalline block copolymers are produced by polymerization of the respective monomers in the presence of a composite catalyst comprising the catalyst components (a), (b) and (c), or (a), (b), (c) and (d), wherein (a) is an organic compound of barium or strontium; (b) is an organic compound of lithium; (c) is an organomagnesium compound; and (d) is an organoaluminum or organozinc compound. Further provided are shaped bodies obtainable by injection, extrusion or compression molding comprising such crystalline block copolymer.

  本发明提供了一种结晶嵌段共聚物，其聚合物链中至少含有一个由式 A-B-C 表示的三嵌段链或至少含有一个由式（D-EX）表示的径向结构。这些三嵌段链或径向结构包括乙烯基芳香族化合物均聚物嵌段，或乙烯基芳香族化合物与另一种乙烯基芳香族化合物或共轭二烯化合物的共聚物嵌段，其玻璃化转变温度不低于 50℃，重量平均分子量在 2,000 至 100,000 之间；以及共轭二烯化合物均聚物嵌段，或共轭二烯化合物与另一种共轭二烯化合物的共聚物嵌段，或共轭二烯化合物与乙烯基芳香族化合物或共轭二烯化合物的共聚物嵌段，其玻璃化转变温度不低于 50℃，重量平均分子量在 2,000 至 100,000 之间。乙烯基芳香族化合物的共聚物，其玻璃化转变温度不高于 10°C，结晶度为 25°C，共轭二烯部分的 1,4-反式连接比例为 80% 或更高。 这些结晶嵌段共聚物是在由催化剂组分(a)、(b)和(c)或(a)、(b)、(c)和(d)组成的复合催化剂存在下，通过聚合各单体而制得的，其中 (a) 是钡或锶的有机化合物； (b) 是锂的有机化合物 (c) 是一种有机镁化合物；和 (d) 有机铝或有机锌化合物。 此外，还提供了可通过注塑、挤压或压缩成型获得的由此类结晶嵌段共聚物组成的成型体。
• A prepolymerization process for producing a conjugated diene compound prepolymer solution
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0304088A1

  公开（公告）日：1989-02-22

  A conjugated diene compound prepolymer solution useful for the production of a vinyl aromatic compound high impact polymer material is produced by a process in which a prepolymerization mixture is prepared from 1 to 70 parts by weight of a conjugated diene compound and 30 to 99 parts by weight of a vinyl aromatic compound, and is prepolymerized at 0°C to 150°C in the presence of a prepolymerization catalyst which can cause the conjugated diene compound to be selectively polymerized but is substantially not effective for the polymerization of the vinyl aromatic compound to an extent such that the conjugated diene compound and the vinyl aromatic compound are prepolymerized at degrees of conversion of the conjugated diene compound at least 50% and 10% or less, respectively, and the resultant prepolymer solution is further polymerized by a radical or anionic polymerization method so that the vinyl aromatic compound is polymerized with the conjugated diene compound prepolymer.

  一种可用于生产乙烯基芳香族化合物高抗冲聚合物材料的共轭二烯化合物预聚物溶液是通过以下工艺生产的：用 1 至 70 份（重量）共轭二烯化合物和 30 至 99 份（重量）乙烯基芳香族化合物制备预聚混合物、并在 0°C 至 150°C 温度下，在一种预聚催化剂存在下进行预聚，该催化剂能使共轭二 烯化合物选择性聚合，但对乙烯基芳香化合物的聚合基本无效，使共轭二烯化合物 和乙烯基芳香化合物分别在共轭二烯化合物转化率至少为 50%和 10%或更低的条件下预 聚、然后用自由基聚合法或阴离子聚合法进一步聚合得到的预聚物溶液，使乙烯基芳香族化合物与共轭二烯化合物预聚物聚合。