Tris(2-bromo-4-methylphenyl) phosphate | 35656-01-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: Tris(2-bromo-4-methylphenyl) phosphate
• CAS: 35656-01-0
• 化学式: C₂₁H₁₈Br₃O₄P
• 分子量: 605.0
• InChiKey: XVHSMXGREZXJKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• FIRE RETARDANT ORGANIC HIGH MOLECULAR COMPOSITION
  申请人：ACOME, SOCIETE COOPERATIVE DE TRAVAILLEURS

  公开号：EP0042440A1

  公开（公告）日：1981-12-30

  An organic high molecular composition having improved fire retardance, which is prepared by compounding a fire retardant composition comprising (a) organic high molecular material, (b) organic fire retardant, and (c) incombustible, polar, inorganic powder, with (d) a multi-functional compound and (e) an organic compound represented by the following formula [wherein Z represents an oxygen atom or a sulfur atom, A represents a divalent hydrocarbyl group containing 2 to 20 carbon atoms, optionally having a substituent, and forming a ring together with the adjacent two carbon atoms and B, and B represents an oxygen atom or an imino group represented by -NY- (wherein Y represents a hydrogen atom, a halogen atom or an organic group containing 30 or less carbon atoms)] or the hydrolyzate thereof.

  一种具有更佳阻燃性的有机高分子组合物，其制备方法是将包含(a)有机高分子材料、(b)有机阻燃剂和(c)不可燃极性无机粉末的阻燃组合物与(d)多功能化合物和(e)由下式表示的有机化合物复合在一起 [其中 Z 代表氧原子或硫原子，A 代表含有 2 至 20 个碳原子的二价烃基，可选择具有一 个取代基，并与相邻的两个碳原子和 B 一起形成一个环，B 代表氧原子或由 -NY- 代表的亚氨基（其中 Y 代表氢原子、卤素原子或含有 30 个或更少碳原子的有机基团））]或其水解物。
• Method for producing modified polyisocyanurate foams
  申请人：NISSHINBO INDUSTRIES, INC.

  公开号：EP0585636A1

  公开（公告）日：1994-03-09

  A method for producing a modified polyisocyanurate foam by reacting an organic polyisocyanate, polyol and water in the presence of a trimerizing catalyst composed of a certain hydroxyalkyl quaternary ammonium compound, and a carbodiimidizing catalyst composed of a certain phosphorene oxide. The method enables production of low density modified polyisocyanurate foams with ease and rapidly without using volatile blowing agents such as CFC, HCFC, HFC and methylene chloride.

  一种生产改性聚异氰脲酸酯泡沫塑料的方法，在由某种羟烷基季铵化合物组成的三聚催化剂和由某种氧化膦组成的碳二亚胺催化剂存在下，使有机聚异氰脲酸酯、多元醇和水发生反应。该方法可以在不使用氟氯化碳、氟氯烃、氢氟碳化合物和二氯甲烷等挥发性发泡剂的情况下，轻松快速地生产出低密度改性聚异氰脲酸酯泡沫塑料。
• Process for producing polyisocyanurate foams
  申请人：NISSHINBO INDUSTRIES, INC.

  公开号：EP0635527A1

  公开（公告）日：1995-01-25

  A process for producing polyisocyanurate foam which comprises reacting an organic polyisocyanate with a polyol and water in the presence of a halogen-free aliphatic phosphoric ester having a molecular weight of 140 to 270 and a trimerization catalyst. Polyisocyanurate foams having good adhesion to membrane such as paper, iron, aluminium, plywood and the like can be obtained without use of an volatile blowing agent such as CFCs, HCFCs and HFCs and even at low density according to the present process.

  一种生产聚异氰脲酸酯泡沫塑料的工艺，包括在分子量为 140 至 270 的无卤脂肪族磷酸酯和三聚催化剂存在下，使有机聚异氰脲酸酯与多元醇和水发生反应。根据本发明的工艺，可以在不使用挥发性发泡剂（如氯氟化碳、氟氯烃和氢氟碳化合物）的情况下，甚至在低密度的情况下，获得与膜（如纸、铁、铝、胶合板等）具有良好粘附性的聚异氰脲酸酯泡沫。
• Process for producing modified polyisocyanurate foams
  申请人：NISSHINBO INDUSTRIES, INC.

  公开号：EP0656382A1

  公开（公告）日：1995-06-07

  A modified polyisocyanurate foam is produced by reacting an organic polyisocyanate, a polyol and water in the presence of three catalyst, i.e. two particular trimerization catalysts and a carbodiimidation catalyst. There can be produced, without using any evaporating type blowing agent, a modified polyisocyanurate foam which is suitably used for continuous production of laminate boards, siding boards, insulation boards, etc.

  改性聚异氰酸酯泡沫塑料是通过有机聚异氰酸酯、多元醇和水在三种催化剂（即两 种特定的三聚催化剂和一种碳二亚胺化催化剂）存在下发生反应而产生的。在不使用任何蒸发型发泡剂的情况下，可以生产出改性聚异氰脲酸酯泡沫塑料，这种泡沫塑料适用于连续生产层压板、护墙板、绝缘板等。
• Process of the preparation of modified polyisocyanurate foams for heat insulation materials
  申请人：Daido Steel Sheet Corporation

  公开号：EP0716106A2

  公开（公告）日：1996-06-12

  A process of the preparation of the modified polyisocyanurate foams provided by a reaction of a polyisocyanate with a polyol composition mixture comprising a polyol, water, a trimerization catalyst, a carbodiimide catalyst, and an aromatic compound used as a chain extender. An amount of the aromatic compound used in the preparation is 0.5 to 10.0 % by weight with respect to a total weight of the polyisocyanate and the polyol mixture.

  一种改性聚异氰酸酯泡沫塑料的制备工艺，由多异氰酸酯与多元醇组合物混合物反应提供，多元醇组合物混合物包括多元醇、水、三聚催化剂、碳化二亚胺催化剂和用作扩链剂的芳香族化合物。在制备过程中，芳香族化合物的用量为多异氰酸酯和多元醇混合物总重量的 0.5%至 10.0%（按重量计）。