Aluminum;neon

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: Aluminum;neon
• 英文别名: aluminum;neon
• 化学式: AlNe
• 分子量: 47.1605
• InChiKey: FMTOVDHACKZQRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.38
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  氖气 、 三甲基铝 以 gaseous matrix 为溶剂， 生成 Aluminum;neon
  参考文献：
  名称：

  Experimental and theoretical study of the AlNe complex

  摘要：

  The laser fluorescence excitation spectrum of the AlNe complex, in the vicinity of the Al atomic 3d←3p and 5s←3p atomic transitions, is reported. Transitions out of the v=0 vibrational levels of both lower-state spin-orbit levels, X1 2Π1/2 and X2 2Π3/2, to vibrational levels of the C 2Δ, D 2Π, and H 2Σ+ AlNe electronic states were observed. From observations of the onset of excitation to the Al(3d)+Ne dissociation continuum, dissociation energies for the various AlNe electronic states were determined. Ab initio calculations of AlNe electronic states correlating with the ground Al(3p)+Ne atomic asymptote were also carried out. The X1 2Π1/2 and X2 2Π3/2 binding energies computed using the calculated AlNe(X 2Π, A 2Σ+) potential energy curves were in reasonable agreement with the experimental determinations. The experimentally determined dissociation energy for the X2 2Π3/2 level is significantly larger than that of the ground X1 2Π1/2 level (D0=32.3±0.3 and 14.1±0.3 cm−1, respectively).

  DOI：

  10.1063/1.475749

文献信息

• Experimental and theoretical study of the AlNe complex
  作者：Xin Yang、Paul J. Dagdigian、Millard H. Alexander

  DOI：10.1063/1.475749

  日期：1998.3

  The laser fluorescence excitation spectrum of the AlNe complex, in the vicinity of the Al atomic 3d←3p and 5s←3p atomic transitions, is reported. Transitions out of the v=0 vibrational levels of both lower-state spin-orbit levels, X1 2Π1/2 and X2 2Π3/2, to vibrational levels of the C 2Δ, D 2Π, and H 2Σ+ AlNe electronic states were observed. From observations of the onset of excitation to the Al(3d)+Ne dissociation continuum, dissociation energies for the various AlNe electronic states were determined. Ab initio calculations of AlNe electronic states correlating with the ground Al(3p)+Ne atomic asymptote were also carried out. The X1 2Π1/2 and X2 2Π3/2 binding energies computed using the calculated AlNe(X 2Π, A 2Σ+) potential energy curves were in reasonable agreement with the experimental determinations. The experimentally determined dissociation energy for the X2 2Π3/2 level is significantly larger than that of the ground X1 2Π1/2 level (D0=32.3±0.3 and 14.1±0.3 cm−1, respectively).