三(间羟基苯基)磷酸酯 | 94135-13-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 三(间羟基苯基)磷酸酯
• 中文别名: 哌嗪,2,6-二氯-
• 英文名称: phosphoric acid tris-(3-hydroxy-phenyl ester)
• 英文别名: Phosphorsaeure-tris-(3-hydroxy-phenylester)；Tris-(3-oxy-phenyl)-phosphat；tris(m-hydroxyphenyl) phosphate；tris(3-hydroxyphenyl) phosphate
• CAS: 94135-13-4
• 化学式: C₁₈H₁₅O₇P
• 分子量: 374.287
• InChiKey: GGYSSENSJNGXLU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  105
• 氢给体数：
  3
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  间苯二酚 在 五氯化磷 作用下， 生成 三(间羟基苯基)磷酸酯
  参考文献：
  名称：

  Secretant, Bulletin de la Societe Chimique de France, 1896, vol. <3> 15, p. 363

  摘要：

  DOI：

文献信息

• PROCESS FOR PRODUCING POLYPHENYLENE ETHER RESIN COMPOSITION
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP1676886A1

  公开（公告）日：2006-07-05

  The invention relates to: a process for producing a poly(phenylene ether) resin composition which comprises (A) a poly(phenylene ether) and (B) a styrene resin and in which the styrene resin (B) is a styrene resin comprising a rubber-modified polystyrene containing a polybutadiene having 90% or higher cis-1,4 bonds, the process comprising a first step in which the poly(phenylene ether) (A) is melt-kneaded together with (B1) part or all of the styrene resin which does not include any rubber-modified polystyrene containing an unhydrogenated polybutadiene and a subsequent second step in which the remaining styrene resin including (B2) a rubber-modified polystyrene containing a polybutadiene having 90% or higher cis-1,4 bonds is melt-kneaded; and a poly(phenylene ether) resin composition obtained by the process. According to the invention, a modified PPE can be stably supplied which is free from various appearance failures such as black foreign particles, unmelted matter, and color unevenness and is excellent in practical properties such as stability to high-temperature residence, heat exposure resistance, and low-temperature impact resistance, in particular, heat deterioration resistance.

  本发明涉及一种生产聚亚苯基醚树脂组合物的工艺，它包括(A)聚亚苯基醚和(B)苯乙烯树脂，其中苯乙烯树脂(B)是由橡胶改性聚苯乙烯组成的苯乙烯树脂，含有顺式-1,4键含量为90%或更高的聚丁二烯、该工艺包括：第一步，将聚苯醚（A）与（B1）部分或全部苯乙烯树脂熔融捏合，其中不包括任何含有未氢化聚丁二烯的橡胶改性聚苯乙烯；第二步，将剩余的苯乙烯树脂熔融捏合，其中包括（B2）含有顺式-1,4 键含量为 90% 或更高的聚丁二烯的橡胶改性聚苯乙烯；以及通过该工艺获得的聚苯醚树脂组合物。根据本发明，可以稳定地提供一种改性聚苯乙烯，这种聚苯乙烯没有各种外观故障，如黑色异物颗粒、未熔化物和颜色不均匀，并且具有优异的实用性能，如对高温停留的稳定性、耐热暴露性和耐低温冲击性，特别是耐热劣化性。
• FLAME-RETARDANT RESIN COMPOSITION
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP2048198A1

  公开（公告）日：2009-04-15

  An object of the present invention is to provide a flame-retardant resin composition that supports a high productivity, that resists bleed out by a flame retardant present in the composition, that resists the migration of its components into ABS resin, that exhibits a high flame retardancy, and that exhibits a high flexibility. More specifically, disclosed is a resin composition comprising, based on the total content of components (A), (B), (C), and (D), the component (A), which a is polyphenylene ether, in a content of 10 % by weight or more but less than 45 % by weight, a component (B), which is a hydrogenated copolymer principally comprising an aromatic vinyl monomer unit and a conjugated diene monomer unit, in a content of of 20 % by weight or more, a component (C), which is a styrene resin and/or olefin resin, in a content of 0 % by weight or more, and a component (D), which is a metal phosphinate, in a content () of 2 % by weight or more.

  本发明的目的是提供一种阻燃树脂组合物，该组合物可支持高生产率，可防止组合物中的阻燃剂渗出，可防止其组分迁移到 ABS 树脂中，具有高阻燃性和高柔韧性。更具体地说，本发明公开了一种树脂组合物，以组分（A）、（B）、（C）和（D）的总 含量为基准，包括组分（A），其中 A 为聚苯醚，含量为 10%（重量）或以上，但低于 45%（重量）；组分（B）、成分(B)是主要由芳香乙烯基单体单元和共轭二烯单体单元组成的氢化共聚物，含量为 20% 或以上（按重量计）；成分(C)是苯乙烯树脂和/或烯烃树脂，含量为 0% 或以上（按重量计）；成分(D)是金属膦酸盐，含量为 2% 或以上（按重量计）。
• TRANSESTERIFICATION PROCESS
  申请人：FMC Corporation (UK) Limited

  公开号：EP0775147A1

  公开（公告）日：1997-05-28
• IMAGE RECORDING PAPER MEDIUM AND IMAGE RECORDING METHOD
  申请人：FUJIFILM Corporation

  公开号：US20160250866A1

  公开（公告）日：2016-09-01

  The image recording paper medium contains at least one kind of organic phosphorus compound selected from an organic phosphonic acid represented by the following Formula (1), a salt thereof, an organic phosphoric acid represented by the following Formula (2), and a salt thereof. In the formulae, each of R 1 and R 2 independently represents an unsubstituted alkyl group, an unsubstituted cycloalkyl group, an unsubstituted alkenyl group, or an aryl group.
• US8865804B2
  申请人：——

  公开号：US8865804B2

  公开（公告）日：2014-10-21