neodymium(III) nitrate hexahydrate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 镧系含氧阴离子化合物
• 英文名称: neodymium(III) nitrate hexahydrate
• 英文别名: neodymium nitrate hexahydrate；Nd(NO₃)₃*6H₂O；neodimium nitrate hexahydrate；Nd(NO₃)₃·6H₂O；Neodymium(3+);nitrate;hydrate
• 化学式: 6H₂O*3NO₃*Nd
• 分子量: 438.346
• InChiKey: AOZVKWNBJDECIL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.06
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  neodymium(III) nitrate hexahydrate 以 neat (no solvent) 为溶剂， 生成 neodymium(III) nitrate
  参考文献：
  名称：

  稀土和其他金属硝酸盐的热解

  摘要：

  摘要 镧、铈(III)硝酸盐的热解曲线。测定了镨、钕、钐、钇、钪、钍、铀（VI）和锆。氧化物水平是在 450-830° 的温度范围内获得的。

  DOI：

  10.1016/0003-2670(56)80082-2
• 作为产物：
  描述：

  硝酸 以 水 为溶剂， 生成 neodymium(III) nitrate hexahydrate
  参考文献：
  名称：

  Vinarov, I. V.; Kornelli, M. E., 1962, # 2, p. 32 - 35

  摘要：

  DOI：
• 作为试剂：
  描述：

  copper(II) choride dihydrate 、 水 、 hexaammonium heptamolybdate tetrahydrate 、 1,2-丙二胺 、 2-吡啶甲酸 、 germanium dioxide 在 盐酸 、 neodymium(III) nitrate hexahydrate 作用下， 反应 2.5h， 以25%的产率得到
  参考文献：
  名称：

  Syntheses, structures and properties of two copper-2-picolinic-acid germanomolybdate hybrids with mixed organic components

  摘要：

  Two inorganic-organic hybrids based on saturated alpha-Keggin-type germanomolybdates with mixed organic components [H(2)DAP](2)[Cu(PA)(2)][alpha-GeMo12O40]center dot 8H(2)O (1) and [NH4](2)[H8L] [Cu(PA)(2)]alpha-GeMo12O40]center dot 8H(2)O (2) (DAP = 1.2-diaminopropane, HPA = 2-picolinic acid, H6L = 1,3-bis[tris(hydroxymethyl)methylamino] propane) have been obtained via the conventional aqueous solution method and structurally characterized by elemental analysis, IR spectra, thermogravimetric (TG) analysis and single-crystal X-ray diffraction. 1 stands for an one-dimensional linear organic-inorganic hybrid germanomolybdate chain constructed from classical Keggin [alpha-GeMo12O40](4-) units supported by [Cu(PA)(2)] linkers, whereas 2 represents the first hybrid germanomolybdate containing the H6L component and consists of a saturated alpha-Keggin polyanion [alpha-GeMo12O40](4-), a diprotonated [H8L](2+) cation, a copper coordination complex [Cu(PA)(2)], two ammonium cations [NH4](+) and eight lattice Water molecules. Furthermore, the electrochemical and electrocatalytic properties of 1 and 2 have also been investigated in detail. (C) 2016 Published by Elsevier B.V.

  DOI：

  10.1016/j.inoche.2016.07.014

文献信息

• Effect of ligand substitution on the SMM properties of three isostructural families of double-cubane Mn₄Ln₂ coordination clusters
  作者：Muhammad Nadeem Akhtar、Yanhua Lan、Murad A. AlDamen、Yan-Zhen Zheng、Christopher E. Anson、Annie K. Powell

  DOI：10.1039/c7dt04304j

  日期：——

  Three isostructural lanthanide series with a core of MnIII2MnII2Ln2 are reported. These three families have the formulae of [MnIII2MnII2Ln2(μ4-O)2(H2edte)2(piv)6(NO3)2] no crystallization solvent, Ln = La, Ce, Pr, Nd, Eu (1–4, 6); solv = 3MeCN, Ln = Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Y (5, 7–13)}, where H2edte = N,N,N′,N‘-tetrakis(2-hydroxyethyl)ethylenediamine and piv = pivalate; [MnIII2MnII2Ln2(μ4

  报道了三个具有锰III 2锰II 2 Ln 2核心的同构镧系元素。这三个家族具有[Mn的式III 2锰II 2 LN 2（μ 4 -O）2（H 2 edte）2（PIV）6（NO 3）2 ] 无结晶化溶剂，Ln为镧，铈，镨，钕，铕（1-4，6）; SOLV = 3MeCN，Ln为钐，钆，铽，镝，钬，铒，铥，镱，Y（5，7-13）}，其中H 2 edte = Ñ，N，N ′，N′-四（2-羟乙基）乙二胺，piv ＝新戊酸酯；[锰III 2锰II 2 LN 2（μ 4 -O）2（H 2 edte）2（苯并）6（NO 3）2 ]，其中苯并=苯甲酸盐，或[锰III 2锰II 2 LN 2（μ 4 -O）2（edteH 2）2（苯）6（NO 3）2]·2MeCN Ln = Gd，Tb，Dy（14-16）; 和[锰III 2锰II 2 LN 2（μ 4 -O）2（edteH 2）2（PIV）8 ]
• Lanthanide complexes with mono- and bicyclic macromolecules. Synthesis and spectroscopic studies
  作者：A. Seminara、A. Musumeci

  DOI：10.1016/s0020-1693(00)93627-2

  日期：1980.1

  Abstract Complexes of lanthanide(III) chlorides, thiocyanates, nitrates and perchlorates with three cyclic polyethers containing five or six oxygen atoms in the cycle and two bicyclic macromolecules containing five or six oxygen and two nitrogen atoms in the cycles have been prepared and characterized. Possible arrangements around the cation are proposed on the ground of conductivity measurements,

  摘要制备并表征了镧系元素氯化物（Ⅲ），硫氰酸盐，硝酸盐和高氯酸盐与循环中含五个或六个氧原子的三个环状聚醚和两个含五个或六个氧和两个氮原子的双环大分子的配合物。基于电导率测量，振动和电子光谱，提出了围绕阳离子的可能布置。
• Tetranuclear NIR luminescent Schiff-base Zn–Nd complexes
  作者：Xingqiang Lü、Weiyu Bi、Wenli Chai、Jirong Song、Jianxin Meng、Wai-Yeung Wong、Wai-Kwok Wong、Richard A. Jones

  DOI：10.1039/b710204f

  日期：——

  With the simple dinuclear Zn–Nd complex [ZnNdL(H2O)(NO3)3] (1) (H2L = N,N′-bis(3-methoxysalicylidene)ethylene-1,2-diamine) as the precursor, tetranuclear [Zn2Nd2L2(4,4′-bpy)(NO3)6]·Et2O (2) and [Zn2Nd2L2(4,4′-bpe)]·2H2O (3) (4,4′-bpy = 4,4′-bipyridine, 4,4′-bpe = trans-bis(4-pyridyl)ethylene) complexes are formed: suitable choice of bidentate linkers could construct multinuclear heterometallic 3d–4f Schiff-base complexes with improved luminescent properties, and the controlling of linker character shows a potentially effective way to the fine-tuning properties of NIR luminescence from Nd ions.

  以简单的双核Zn–Nd配合物[ZnNdL(H2O)(NO3)3] (1) (H2L = N,N′-双(3-甲氧基水杨醛)亚乙基-1,2-二胺)为前驱体，合成了四核的[Zn2Nd2L2(4,4′-联吡啶)(NO3)6]·Et2O (2)和[Zn2Nd2L2(4,4′-BPE)]·2H2O (3) (4,4′-联吡啶 = 4,4′-联吡啶，4,4′-BPE = 反式双(4-吡啶基)亚乙基)配合物：适宜的双齿配体的选择可以构建具有增强发光性能的多核异金属3d–4f席夫碱配合物，并且配体性质的调控显示出对来自Nd离子的近红外发光精细调谐的有效途径。
• Lanthanide nitrate complexes of octamethylpyrophosphoramide
  作者：Joseph A. Sylvanovich、Stanley K. Madan

  DOI：10.1016/0022-1902(72)80205-7

  日期：1972.8

  The syntheses and physical properties of the crystalline compounds [Ln(OMPA)2(NO3)3] (Ln = Gd, Er, Yb) are reported. For most of the complexes, the i.r. and Raman spectra, molar conductivities, mol. wt., and X-ray powder patterns are reported. I.R. spectra of these complexes indicate that in the solid state, the complexes contain coordinated nitrate, and in all cases, coordination through the oxygen

  报道了结晶化合物[Ln（OMPA）2（NO 3）3 ]（Ln ＝ Gd，Er，Yb）的合成和物理性质。对于大多数配合物，红外光谱和拉曼光谱，摩尔电导率，摩尔。报道了X射线粉末的重量和重量。这些络合物的红外光谱表明，在固态下，该络合物含有配位的硝酸盐，并且在所有情况下均观察到通过OMPA的氧原子进行配位。这些化合物的组成和X射线数据均清楚地表明存在两个同构的OMPA配合物系列。
• Synthesis, characterization and luminescent properties of lanthanide complexes with a novel multipodal ligand
  作者：Zhen-Zhong Yan、Na Hou、Cong-Min Wang

  DOI：10.1016/j.saa.2014.09.035

  日期：2015.2

  Solid complexes of lanthanide nitrates with an novel multipodal ligand, 1,2,4,5-tetramethyl-3,6-bisN,N-bis[((2'-furfurylaminoformyl)phenoxyl)ethyl]-aminomethyl}-benzene (L) have been synthesized and characterized by elemental analysis, infrared spectra and molar conductivity measurements. At the same time, the luminescent properties of the Sm(III), Eu(III), Tb(III) and Dy(III) nitrate complexes in solid

  硝酸镧与新型多足配体1,2,4,5-四甲基-3,6-双N，N-双[（（（2'-糠基氨基甲酰基）苯氧基）乙基]-氨基甲基}-苯的固体配合物（ L）已经合成并通过元素分析，红外光谱和摩尔电导率测量来表征。同时，研究了固态Sm（III），Eu（III），Tb（III）和Dy（III）硝酸盐配合物的发光性能。在紫外线的激发下，这些配合物表现出中心金属离子的特征发射。配体的最低三重态能级表明，配体的三重态能级（T1）比其他镧系离子更好地匹配了Tb（III）的共振能级。