作者:Trygve E. Eriksen、Johan Lind、Gábor Merényi
DOI:10.1039/f19817702115
日期:——
been determined by pulse and steady-state radiolyses. The yield was found to be dependent on ClO–2 concentration but independent of pH. The solvated electron was found to react with ClO–2 with a rate constant (2.5 ± 0.5)× 109 S–1 mol–1 dm3 to yield ClO–. In its reaction with ClO–2 the OH. radical was found to produce two species; ClO.2 and an OH. adduct. At sufficiently high ClO–2 concentrations the
ClO的收率。2在次氯酸钠的照射水溶液2已经由脉冲和稳态radiolyses确定。发现产量取决于ClO – 2的浓度,但不受pH的影响。发现溶剂化电子以速率常数(2.5±0.5)×10 9 S –1 mol –1 dm 3与ClO – 2反应生成ClO –。在与ClO - 2的反应中是OH 。发现自由基产生两种物质;ClO 。2和一个OH 。加合物。在足够高的ClO – 2浓度下,加合物与ClO – 2反应生成更多的ClO 。2。