tris(thiourea)zinc(II) sulfate

• 分子结构分类: 有机化合物 - 有机盐 - 有机硫酸盐
• 英文名称: tris(thiourea)zinc(II) sulfate
• 英文别名: zinc tris thiourea sulfate；[Zn(thiourea)₃(SO₄)]；[Zn(tu)₃(SO₄)]；zinc tris(thiourea)sulfate；sulfatotris(thiourea)zinc；zinc;thiourea;sulfate
• 化学式: C₃H₁₂N₆O₄S₄Zn
• 分子量: 389.82
• InChiKey: GLVOVYXPKVSFFY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -3.77
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  341
• 氢给体数：
  6
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  tris(thiourea)zinc(II) sulfate 、 硫脲 以 水 为溶剂， 生成
  参考文献：
  名称：

  Ugai, Ya. A.; Semenov, V. N., Journal of general chemistry of the USSR, 1989, vol. 59, p. 1952 - 1959

  摘要：

  DOI：
• 作为产物：
  描述：

  硫脲 、 zinc(II) sulfate 以 水 为溶剂， 生成 tris(thiourea)zinc(II) sulfate
  参考文献：
  名称：

  EPR and optical absorption studies of VO(II)-doped zinc Tris thiourea sulfate

  摘要：

  Electron paramagnetic resonance (EPR) of vanadyl ion as an impurity in polycrystalline zinc tris thiourea sulfate (ZTS), a prominent nonlinear optical host, has been studied at X-band frequencies at room temperature. Spin-Hamiltonian parameters and molecular orbital coefficients have been calculated. The optical absorption spectra. have also been studied to deduce the crystal field parameters. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(01)00535-2

文献信息

• Reinvestigation of growth of thiourea urea zinc sulfate crystal
  作者：Bikshandarkoil R. Srinivasan、Teja A. Naik、Zbigniew Tylczyński、K.R. Priolkar

  DOI：10.1016/j.saa.2013.08.083

  日期：2014.1

  Reinvestigation of the growth of thiourea urea zinc sulfate crystal is reported. Aqueous reaction of thiourea, urea and zinc sulfate in 1:1:1 mol ratio results in the formation of the well known [Zn(tu)3(SO4)] (1) (tu=thiourea) crystal and not the 'so called' novel semiorganic nonlinear optical thiourea urea zinc sulfate (2) crystal, as claimed by Redrothu Hanumantha Rao, S. Kalainathan, Spectroscopic

  据报道对硫脲脲锌硫酸盐晶体的生长进行了重新研究。硫脲，尿素和硫酸锌以1：1：1摩尔比进行的水反应导致形成众所周知的[Zn（tu）3（SO4）]（1）（tu = thiourea）晶体，而不是所谓的如Redrothu Hanumantha Rao，S.Kalainathan所述，新型半有机非​​线性光学硫脲脲硫酸锌（2）晶体，新型半有机非​​线性光学晶体-硫脲脲的光谱研究，成核，生长，光学，热和二次谐波研究硫酸锌，Spectrochim。Acta A97（2012）456-463。在这项工作中，我们证明了元素分析数据，红外光谱和NMR光谱以及X射线粉末模式对于准确表征产品的有用性。
• EPR and optical absorption studies of VO(II)-doped zinc Tris thiourea sulfate
  作者：K Vasantha、P.A Angeli Mary、S Dhanuskodi

  DOI：10.1016/s1386-1425(01)00535-2

  日期：2002.1

  Electron paramagnetic resonance (EPR) of vanadyl ion as an impurity in polycrystalline zinc tris thiourea sulfate (ZTS), a prominent nonlinear optical host, has been studied at X-band frequencies at room temperature. Spin-Hamiltonian parameters and molecular orbital coefficients have been calculated. The optical absorption spectra. have also been studied to deduce the crystal field parameters. (C) 2002 Elsevier Science B.V. All rights reserved.
• Ugai, Ya. A.; Semenov, V. N., Journal of general chemistry of the USSR, 1989, vol. 59, p. 1952 - 1959
  作者：Ugai, Ya. A.、Semenov, V. N.

  DOI：——

  日期：——