Dysprosium--lambda~2~-stannane (1/3) | 12790-49-7

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: Dysprosium--lambda~2~-stannane (1/3)
• 英文别名: dysprosium;λ2-stannane
• CAS: 12790-49-7
• 化学式: DySn₃
• 分子量: 518.63
• InChiKey: UQHSKPSHSGHWQS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.75
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Dysprosium--lambda~2~-stannane (1/3) 以 水 为溶剂， 生成 氢化镝(DyH3) 、 tin
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: MVol.D, 19.11.4, page 320 - 320

  摘要：

  DOI：
• 作为产物：
  描述：

  tin 、 氢化镝(DyH3) 以 neat (no solvent) 为溶剂， 生成 Dysprosium--lambda~2~-stannane (1/3)
  参考文献：
  名称：

  Koretskaya, O. E.; Komarovskaya, L. P.; Skolozdra, R. V., Inorganic Materials, 1988, vol. 24, p. 1112 - 1114

  摘要：

  DOI：

文献信息

• Miller, K., Dissertation Abstracts International, B: The Sciences and Engineering, Diss. Univ. of Provo, Utah, 1971, S. 1/103, 1971, vol. 32, p. 268
  作者：Miller, K.

  DOI：——

  日期：——
• Interaction of the components in the Dy–Ag–Sn ternary system at 870 K
  作者：V.V. Romaka、A. Tkachuk、V. Davydov

  DOI：10.1016/j.jallcom.2006.08.244

  日期：2007.7

  The phase diagram of the Dy-Ag-Sn ternary system was constructed at 870 K using data of X-ray and partially metallographic analyses. Presence of the DyAgSn starmide in the system was confirmed (ST CaIn2, SG P6(3)/mmc, a = 0.46813(2), c = 0.73433(5) nm) and two new compounds were found: Dy3Ag4Sn4 (ST Gd3Cu4Ge4, SG Immm, a = 0.45316(1), b = 0.72887(2), c = 1.51225(5) nm) and DyAgSn2 (ST Cu3Au, SG Pm-3m, a = 0.453 10(l) nm). The DyAgSn2 is a Curie-Weiss paramagnet in the temperature range 80-470 K (mu(eff) = 10.64 mu(B), theta p = -14 K). A formation of substitutional solid solutions DyAg1-xSnx and DyAg2-xSn, was established. (c) 2006 Elsevier B.V. All rights reserved.
• An investigation of the structures of the compounds in the tin-rich part of the Dy–Sn system: Crystal structure of Dy5Sn11 and Dy5Sn13
  作者：G. Venturini、A. Mesbah

  DOI：10.1016/j.jallcom.2007.03.141

  日期：2008.6

  The structural properties of the compounds in the tin-rich part of the dysprosium-tin system have been studied by X-ray powder diffraction. The crystal structures of six compounds DySn2+x (0 < x < 1) have been characterized. There are four compounds with known structural types: DySn2 with the ZrSi2 structure, Dy3Sn7 with the Gd3Sn7 structure, Dy2Sn5 with the Er2Ge5 structure, DySn3 with the DyGe3 structure and two compounds characterized by new body-centred orthorhombic types (Immm): Dy5Sn11 (a = 4.411 angstrom, b= 42.50 angstrom and c = 4.328 angstrom) and Dy5Sn13 (a = 4.341 angstrom, b = 48.05 angstrom and c = 4.405 angstrom) which result from various insertions of AuCu3 and alpha Po slabs into the ZrSi2 structure. The relationships and structural evolution are discussed. (c) 2007 Elsevier B.V. All rights reserved.