dibutylphenyl phosphate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: dibutylphenyl phosphate
• 英文别名: Tris(2,3-dibutylphenyl) phosphate
• 化学式: C₄₂H₆₃O₄P
• 分子量: 662.934
• InChiKey: ISHJJMOYOTZDNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.2
• 重原子数：
  47
• 可旋转键数：
  24
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Halogen-free flame retardant polyester
  申请人：Wit De Gerrit

  公开号：US20060074155A1

  公开（公告）日：2006-04-06

  Novel polyester composition comprising a polyester, wherein said polyester comprises structural units derived from substituted or unsubstituted diacid or diester, a substituted or unsubstituted diol; a phosphorus containing compound and at least one selected from a stabilizer and an organic compound comprising at least one functional group is been disclosed. In addition methods for the preparation of the polyester composition and articles derived from said composition is disclosed.

  本发明涉及一种新型聚酯组合物，包括聚酯和以下组分：由取代或未取代的二酸或二酯衍生的结构单元，取代或未取代的二元醇，含磷化合物以及至少选择自稳定剂和含有至少一个官能团的有机化合物之一。此外，本发明还涉及制备该聚酯组合物的方法以及从该组合物衍生的物品。
• Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid
  申请人：Moody Leslie Shane

  公开号：US20070232779A1

  公开（公告）日：2007-10-04

  Described as one aspect of the invention are polyester compositions A polyester composition comprising at least one polyester which comprises: (A) a dicarboxylic acid component comprising: i) 70 to 100 mole % of cyclohexanedicarboxylic acid residues or an ester thereof comprising: (a) 80 to 99 mole % trans-cyclohexanedicarboxylic acid residues or an ester thereof; and (b) 1 to 20 mole % cis-cyclohexanedicarboxylic acid residues or an ester thereof; ii) 0 to 30 mole % of aliphatic dicarboxylic acid residues, other than cyclohexanedicarboxylic acid residues, having up to 16 carbon atoms or esters thereof, other than cyclohexanedicarboxylic acid residues; and iii) 0 to 10 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (B) a glycol component comprising: i) 5 to 35 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) 65 to 95 mole % of 1,4-cyclohexanedimethanol residues, 1,3-cyclohexanedimethanol residues, 1,2-cyclohexanedimethanol residues or esters thereof or mixtures thereof, wherein the total mole % of said dicarboxylic acid component is equal to 100 mole %; the total mole % of said glycol component is equal to 100 mole %; wherein the inherent viscosity of said polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; and wherein said polyester has a Tg of from 66 to 120° C. The polyesters may be manufactured into articles.

  本发明的一方面是聚酯组合物，其中包括至少一种聚酯，该聚酯包括：(A) 二羧酸组分，包括：i) 70至100摩尔％的环己二甲酸残基或其酯，包括：(a) 80至99摩尔％的反式环己二甲酸残基或其酯；和(b) 1至20摩尔％的顺式环己二甲酸残基或其酯；ii) 0至30摩尔％的具有高达16个碳原子的脂肪族二羧酸残基（环己二甲酸残基除外）或其酯；以及iii) 0至10摩尔％的具有高达20个碳原子的芳香族二羧酸残基；和(B) 二元醇组分，包括：i) 5至35摩尔％的2,2,4,4-四甲基-1,3-环丁二醇残基；和ii) 65至95摩尔％的1,4-环己二甲醇残基，1,3-环己二甲醇残基，1,2-环己二甲醇残基或其酯或其混合物，其中所述二羧酸组分的总摩尔％等于100摩尔％；所述二元醇组分的总摩尔％等于100摩尔％；其中所述聚酯的固有粘度在60/40（重量/重量）苯酚/四氯乙烷中以0.5 g / 100 ml浓度在25°C下测定为0.35至1.2 dL / g；且所述聚酯的Tg在66至120°C之间。这些聚酯可以制成物品。
• Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid
  申请人：Moody Leslie Shane

  公开号：US20070232778A1

  公开（公告）日：2007-10-04

  Described as one aspect of the invention are polyester compositions comprising at least one polyester which comprises: (A) a dicarboxylic acid component comprising: i) 70 to 100 mole % of cyclohexanedicarboxylic acid residues or an ester thereof comprising: (a) 70 to 98 mole % trans-cyclohexanedicarboxylic acid residues or an ester thereof; and (b) 2 to 30 mole % cis-cyclohexanedicarboxylic acid residues or an ester thereof; ii) 0 to 30 mole % of aliphatic dicarboxylic acid residues, other than cyclohexanedicarboxylic acid residues, having up to 16 carbon atoms or esters thereof, other than cyclohexanedicarboxylic acid residues,; and iii) 0 to 10 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (B) a glycol component comprising: i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) 1 to 99 mole % of 1,4-cyclohexanedimethanol residues, 1,3-cyclohexanedimethanol residues, 1,2-cyclohexanedimethanol residues or esters thereof or mixtures thereof, wherein the total mole % of said dicarboxylic acid component is equal to 100 mole %; the total mole % of said glycol component is equal to 100 mole %; wherein the inherent viscosity of said polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; and wherein said polyester has a Tg of from 60 to 155° C. The polyesters may be manufactured into articles.

  本发明的一方面是聚酯组合物，包括至少一种聚酯，其包括：（A）二羧酸成分，包括：i）70至100摩尔％的环己烷二羧酸残基或其酯，包括：（a）70至98摩尔％的反式环己烷二羧酸残基或其酯；和（b）2至30摩尔％的顺式环己烷二羧酸残基或其酯；ii）0至30摩尔％的脂肪族二羧酸残基，除了具有高达16个碳原子的环己烷二羧酸残基或其酯之外；和iii）0至10摩尔％的具有高达20个碳原子的芳香族二羧酸残基；以及（B）乙二醇成分，包括：i）2,2,4,4-四甲基-1,3-环丁二醇残基的1至99摩尔％；和ii）1,4-环己二甲醇残基、1,3-环己二甲醇残基、1,2-环己二甲醇残基或其酯或其混合物的1至99摩尔％；其中，所述二羧酸成分的总摩尔％等于100摩尔％；所述乙二醇成分的总摩尔％等于100摩尔％；其中，所述聚酯的固有粘度为0.35至1.2 dL/g，在60/40（重量/重量）苯酚/四氯乙烷中，在25°C下浓度为0.5 g/100 ml时确定；所述聚酯具有从60°C到155°C的Tg。这些聚酯可以制成物品。
• Stain and Color Change Resistant Poly(Phenylene Ether) Composition
  申请人：SABIC INNOVATIVE PLASTICS IP B.V.

  公开号：US20130253105A1

  公开（公告）日：2013-09-26

  Disclosed are polymer compositions, comprising: (a) a poly(phenylene ether); (b) a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene; (c) a polybutene; (d) a flame retardant; (e) an anti-UV agent wherein the agent comprises a trisaryl-1,3,5-triazine; (f) a copolymer of ethylene and a C 3 -C 12 alpha-olefin; and (g) a polyolefin homopolymer; wherein the polymer composition does not contain a benzotriazole-type UV absorber; all weight percents are based on the total weight of the composition; and wherein an article made from the composition: (i) is substantially stainless; (ii) exhibits a CIELAB color shift, (ΔE) of 3 or less after 168 hours of heat exposure at 75° C.; and (iii) exhibits a CIELAB color shift, (ΔE) of 12 or less after 300 hours of xenon arc exposure according to ASTM D 4459. Also disclosed are processes for making the compositions as well as articles derived therefrom.

  本发明涉及聚合物组合物，包括：(a)聚苯醚；(b)烯丙基芳香化合物和共轭二烯的氢化嵌段共聚物；(c)聚丁烯；(d)阻燃剂；(e)抗紫外线剂，其中该剂包括三芳基-1,3,5-三嗪；(f)乙烯和C3-C12α-烯烃的共聚物；和(g)聚烯烃均聚物；其中聚合物组合物不含苯并三唑类紫外线吸收剂；所有重量百分比均基于组合物的总重量；以及由该组合物制成的物品：(i)基本上不锈；(ii)在75°C的热暴露168小时后，显示CIELAB颜色偏移(ΔE)小于3；和(iii)根据ASTM D 4459，在300小时氙弧曝光后，显示CIELAB颜色偏移(ΔE)小于12。还公开了制备该组合物以及由此得到的物品的工艺。
• FLEXIBLE, WRINKLE RESISTANT POLY (PHENYLENE ETHER) CABLE JACKETING COMPOSITION
  申请人：SABIC GLOBAL TECHNOLOGIES B.V.

  公开号：US20150252214A1

  公开（公告）日：2015-09-10

  Disclosed is a flexible, wrinkle-resistant cable jacketing composition, comprising: cable jacketing compositions, comprising specific amounts of a poly(phenylene ether), a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, an olefin homopolymer, a polybutene, and a flame retardant. Also disclosed are processes for making such compositions, as well as articles derived therefrom.

  本发明涉及一种柔性、抗皱缩的电缆护套组合物，包括：电缆护套组合物，包括特定量的聚苯乙烯醚、烯丙基芳香化合物和共轭二烯的氢化嵌段共聚物、烯烃均聚物、聚丁烯和阻燃剂。同时还公开了制备此类组合物的方法，以及由此得到的制品。