sodium;1,9-ditert-butyl-3,7-dimethyl-11-oxido-5H-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: sodium;1,9-ditert-butyl-3,7-dimethyl-11-oxido-5H-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide
• 化学式: C23H30NaO4P
• 分子量: 424.4
• InChiKey: FIAYJSUZUBQZOW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.73
• 重原子数：
  29
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  58.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Olefin block copolymers processes for producing the same and uses thereof
  申请人：——

  公开号：US20030055179A1

  公开（公告）日：2003-03-20

  The present invention provides polymers having any one of properties including affinity for metals or polar resins, impact resistance, mar resistance, heat resistance, rigidity, oil resistance, transparency, anti-fogging properties, electric insulating properties, high breakdown voltage, coating properties, low-temperature flexibility, moldability, environmental degradation, fluidity and dispersibility, and provides a process for preparation thereof. The olefin block copolymers (A-1) of the invention are represented by the formula (I) PO 1 —g 1 —B 1 (I) (wherein PO 1 is a segment composed of repeating units derived from an olefin having 2 to 20 carbon atoms, g 1 is an ester, ether, amide, imide, urethane, urea, silylether or carbonyl linkage, and B 1 is a segment containing an unsaturated hydrocarbon or a hetero atom). The olefin block copolymers are suitable for uses in adhesives; various molded articles such as construction and civil engineering materials, automobile interior and exterior materials, gasoline tanks, electric and electronic parts, medical care and sanitation materials, materials of miscellaneous goods, resin materials having environmental degradation properties, films and sheets; modifiers and dispersions.

  本发明提供了具有以下任一性质的聚合物，包括对金属或极性树脂的亲和性，抗冲击性，抗刮伤性，耐热性，刚度，耐油性，透明性，防雾性能，电绝缘性能，高击穿电压，涂料性能，低温柔性，可塑性，环境降解性，流动性和分散性，并提供其制备方法。本发明的烯烃嵌段共聚物（A-1）由公式（I）表示：PO1-g1-B1（I）（其中PO1是由具有2至20个碳原子的烯烃衍生的重复单元组成的片段，g1是酯，醚，酰胺，亚胺，脲，硅醚或羰基连接，B1是含有不饱和碳氢化合物或杂原子的片段）。烯烃嵌段共聚物适用于粘合剂；各种成型品，如建筑和土木工程材料，汽车内外饰料，汽油箱，电子和电气零件，医疗保健和卫生材料，杂货物料，具有环境降解性能的树脂材料，薄膜和片材；改性剂和分散剂。
• PROPYLENE-ETHYLENE COPOLYMER COMPOSITIONS AND PROCESS FOR THE PRODUCTION THEREOF
  申请人：CHISSO CORPORATION

  公开号：EP0790262A1

  公开（公告）日：1997-08-20

  A propylene-ethylene copolymer composition is obtained which has a good moldability and is excellent in the balance of rigidity, toughness, and impact-strength. A propylene-ethylene copolymer composition having a melt flow rate of 10 to 300 g/10 minutes and obtained by producing 60 to 95 % by weight, based on the weight of whole polymer, of a propylene polymer having a melt flow rate (ASTM D-1238) in the range of 100 to 1,000 g/10 minutes and having a ratio (Cf) of integrated values of the propylene polymer dissolved in o-dichlorobenzene at a temperature of lower than 112°C, and a temperature of 112°C or higher, respectively, which is an index of the stereoregurality in molecules and molecular weight distribution, when the amounts of the propylene polymer dissolved therein at each of the temperatures were determined by raising the temperature of the o-dichlorobenzene continuously or stepwise, of 0.5 or less, by carrying out polymerization of propylene in the presence of a highly stereoregular catalyst and hydrogen in a polymerization step (I), and then producing 5 to 40 % by weight, based on the weight of whole polymer, of an ethylene-propylene copolymer by feeding ethylene and propylene to the propylene polymer produced in the polymerization step (I) to react so that the content of ethylene becomes 30 to 80 % by weight, in a polymerization step (II); and a propylene-ethylene copolymer composition comprising the composition mentioned above and a α-crystal and/or β-crystal nucleator added therewith.

  一种丙烯-乙烯共聚物组合物具有良好的成型性，并且在刚性、韧性和冲击强度的平衡方面表现优异。 一种熔体流动速率为 10 至 300 克/10 分钟的丙烯-乙烯共聚物组合物，通过以下方法获得 以整个聚合物的重量为基准，生产 60% 至 95% 重量百分比的丙烯聚合物，其熔体流动速率（ASTM D-1238）在 100 至 1,000 克/10 分钟范围内，在温度低于 112°C、和 112°C 或更高温度下溶解在邻二氯苯中的丙烯聚合物的综合值之比 (Cf)，这分别是分子立体性和分子量分布的指标，当通过连续或逐步提高邻二氯苯的温度 0.5 或更低，在聚合步骤 (I) 中，在高度立体配位催化剂和氢的存在下进行丙烯聚合，然后 在聚合步骤(II)中，通过向聚合步骤(I)中生成的丙烯聚合物中加入乙烯和丙烯进行反应，使乙烯的含量达到 30% 至 80%（以整个聚合物的重量计），生成 5% 至 40%（以重量计）的乙烯-丙烯共聚物；以及丙烯-乙烯共聚物组合物，该组合物包括上述组合物和加入其中的 α 结晶和/或 β 结晶成核剂。
• HIGHLY CRYSTALLINE POLYPROPYLENE
  申请人：Japan Polyolefins Co., Ltd.

  公开号：EP0854155A1

  公开（公告）日：1998-07-22

  A highly crystalline polypropylene having a degree of crystallinity of at least 50.5% calculated from the heat of melting; and a relationship between a proportion f(R)of R-lamella with respect to spherulites and a weight-average molecular weight Mw which satisfies the following Formula (II). The above-mentioned proportion f(R) of R-lamella spherulites is calculated using the following Formula (I) from the birefringence Δn of crystallized spherulites obtained by melting said highly crystalline polypropylene at 230°C for 5 minutes, cooling to a temperature of 132°C at a cooling rate of 20°C/minute, and then maintaining said temperature for 90 minutes. Molded articles obtained using the above-mentioned highly crystalline polypropylene or a resin composition containing the above-mentioned highly crystalline polypropylene resin are superior in rigidity, heat resistance, scratch resistance, dimensional stability, and low production of odor during molding, and can be widely used in various applications.Formula (I)f(R) = ( - Δn + 0.0351) X 100/0.0528Formula (II).f(R) > - 2.5 X (logMw} -4)2 + 88.9

  一种高结晶聚丙烯，其结晶度根据熔化热计算至少为 50.5%；以及 R-拉美球粒比例 f(R)与重量平均分子量 Mw 之间的关系满足下式 (II)。上述 R-拉美拉球状物比例 f(R)是通过下式(I)从结晶球状物的双折射 Δn 计算得出的，结晶球状物是通过在 230°C 下熔化所述高结晶聚丙烯 5 分钟，以 20°C / 分钟的冷却速度冷却到 132°C 的温度，然后保持所述温度 90 分钟而得到的。使用上述高结晶性聚丙烯或含有上述高结晶性聚丙烯树脂的树脂组合物获得的模塑制品在刚性、耐热性、抗划伤性、尺寸稳定性和模塑过程中产生的气味低等方面均具有优越性，可广泛应用于各种领域。
• ALPHA-OLEFIN/AROMATIC VINYL COPOLYMER COMPOSITION AND MOLDINGS THEREOF
  申请人：Mitsui Chemicals, Inc.

  公开号：EP0870801A1

  公开（公告）日：1998-10-14

  The present invention provides a composition containing an α-olefin/aromatic vinyl compound copolymer, which has no chlorine content and can bring about formed products, such as films, sheets, pipes and tubes, exhibiting a moderate extensible elasticity and ability for adhering onto various surfaces together with superior properties in the transparency, fogging resistance, durablility of the fogging resistance and ability for restoring from strain. The composition comprises 99.5 - 90 weight % of a copolymer (A) of an α-olefin and an aromatic vinyl compound, the copolymer (A) being composed of 99.95 - 70 mole % of the structural unit derived from the α-olefin and 0.05 - 30 mole % of the structural unit derived from the aromatic vinyl compound and 0.5 - 10 weight % of an anti-fogging agent (B).

  本发明提供了一种含有α-烯烃/芳香族乙烯基化合物共聚物的组合物，该组合物不含氯，可制成薄膜、片材、管材和管材等成型产品，具有适度的延伸弹性和附着于各种表面的能力，同时在透明度、防雾性、防雾耐久性和应变恢复能力方面具有优异的性能。该组合物包括 99.5 - 90 重量百分比的 α-olefin 和芳香族乙烯基化合物的共聚物 (A)，共聚物 (A) 由 99.95 - 70 摩尔百分比的 α-olefin 结构单元和 0.05 - 30 摩尔百分比的芳香族乙烯基化合物结构单元组成，以及 0.5 - 10 重量百分比的防雾剂 (B)。
• ETHYLENE COPOLYMER COMPOSITION AND MOLDINGS
  申请人：Mitsui Chemicals, Inc.

  公开号：EP0869146A1

  公开（公告）日：1998-10-07

  The present invention provides a copolymer composition based on ethylene which exhibits an adequate extensible flexibility and an ability for adhering onto various surfaces and which is superior in the transparency, strength, restorability from strain, blocking resistance and processibility and has no content of chlorine, as well as formed products made thereof, such as films, sheets, pipes and tubes, wherein said copolymer composition comprises (A) 10 - 90 % by weight of a copolymer of ethylene with an aromatic vinyl compound and/or an α - olefin, which has a degree of crystallinity of at least 10 % but less than 90 % and an intrinsic viscosity [η A] of 1 - 10 dl/g and (B) 10 - 90 % by weight of a homopolymer of ethylene or a copolymer of ethylene with an aromatic vinyl compound and/or an α -olefin, which has a degree of crystallinity higher than 10 % but not higher than 90 % and an intrinsic viscosity [η B] of 0.1 - 2 dl/g wherein at least one of the above ethylenic copolymer (A) and the ethylenic polymer (B) has the copolymerized aromatic vinyl compound and wherein the ratio of [degree of crystallinity of (A)/degreee of crystallinity of (B)] is less than 1 and the ratio of [η A]/[η B] is greater than 1.

  本发明提供了一种以乙烯为基础的共聚物组合物，该组合物具有足够的延伸柔韧性和粘附在各种表面的能力，在透明度、强度、应变恢复性、抗阻塞性和可加工性方面都很出色，并且不含氯；本发明还提供了由该组合物制成的成型产品，如薄膜、片材、管材和管材，其中所述共聚物组合物包括 (A) 10-90%（重量百分比）的乙烯与芳香族乙烯基化合物和/或 α-烯烃的共聚物，其结晶度至少为 10%，但低于 90%，固有粘度[η A]为 1-10dl/g，以及 (B) 10-90%（重量百分比）的乙烯均聚物或乙烯与芳香族乙烯基化合物和/或 α-烯烃的共聚物，其结晶度高于 10%但不高于 90%，固有粘度[η B]为 0.1-2 dl/g 上述乙烯基共聚物（A）和乙烯基聚合物（B）中至少有一种具有共聚芳香族乙烯基化合物，且[(A)的结晶度/(B)的结晶度]之比小于 1，[η A]/[η B]之比大于 1。