Hexafluor-p-dioxen | 56625-38-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶英
• 英文名称: Hexafluor-p-dioxen
• 英文别名: 2,2,3,3,5,6-Hexafluoro-2,3-dihydro-1,4-dioxine；2,2,3,3,5,6-hexafluoro-1,4-dioxine
• CAS: 56625-38-8
• 化学式: C₄F₆O₂
• 分子量: 194.033
• InChiKey: GBSIBPSSTJHPSJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  Hexafluor-p-dioxen 在 二(2,2,3,3,3-五氟-1-氧代丙基)过氧化物 作用下， 反应 168.0h， 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Perhalodioxins and perhalodihydrodioxins

  摘要：

  Two perhalo-1,4-dioxins, representatives of a previously unknown class of compounds, have been synthesized and shown to exhibit unusual reactivity. In particular, reaction with oxygen is spontaneous and exothermic, and radical-catalyzed homopolymerization will proceed through a fluorinated double bond. Representatives of the perhalo-2,3-dihydro-1,4-dioxin class have also been prepared and found to have reactivity in general intermediate to that of the perhalodioxoles and acyclic trifluorovinyl ethers. Computational studies of the two systems established that introduction of the first double bond raises the energy substantially, while the second double bond results in a near-planar ring with dramatically increased energy content.

  DOI：

  10.1021/jo00012a026
• 作为产物：
  描述：

  2,3-dichloro-2,3,5,5,6,6-hexafluoro-1,4-dioxane 在 1,2-二溴乙烷 、 锌 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以45%的产率得到Hexafluor-p-dioxen
  参考文献：
  名称：

  Perhalodioxins and perhalodihydrodioxins

  摘要：

  Two perhalo-1,4-dioxins, representatives of a previously unknown class of compounds, have been synthesized and shown to exhibit unusual reactivity. In particular, reaction with oxygen is spontaneous and exothermic, and radical-catalyzed homopolymerization will proceed through a fluorinated double bond. Representatives of the perhalo-2,3-dihydro-1,4-dioxin class have also been prepared and found to have reactivity in general intermediate to that of the perhalodioxoles and acyclic trifluorovinyl ethers. Computational studies of the two systems established that introduction of the first double bond raises the energy substantially, while the second double bond results in a near-planar ring with dramatically increased energy content.

  DOI：

  10.1021/jo00012a026

文献信息

• Polyhalodihydrodioxins and polyhalodioxoles
  申请人：E. I. Du Pont de Nemours and Company

  公开号：US05026801A1

  公开（公告）日：1991-06-25

  This invention is directed to halodihydrodioxins, their preparation and their polymers, which provide amorphous homopolymers that are resistant to ring opening side reactions. The resulting polymers can be used for films and thermally stable molded objects, coatings for substrates such as wood, glass, paper and metal and for protective packaging. This invention also concerns the preparation of polyhalogenated dioxoles.

  本发明涉及卤代二氢二氧杂环烷、它们的制备和聚合物，其提供无定形的同聚物，对于环开放副反应具有抵抗性。所得到的聚合物可用于薄膜和热稳定成型物体，涂层用于基材如木材、玻璃、纸张和金属以及用于保护包装。本发明还涉及多卤代二氧杂环丙烷的制备。
• KRESPAN, CARL G.;DIXON, DAVID A., J. ORG. CHEM., 56,(1991) N2, C. 3915-3923
  作者：KRESPAN, CARL G.、DIXON, DAVID A.

  DOI：——

  日期：——
• Perhalodioxins and perhalodihydrodioxins
  作者：Carl G. Krespan、David A. Dixon

  DOI：10.1021/jo00012a026

  日期：1991.6

  Two perhalo-1,4-dioxins, representatives of a previously unknown class of compounds, have been synthesized and shown to exhibit unusual reactivity. In particular, reaction with oxygen is spontaneous and exothermic, and radical-catalyzed homopolymerization will proceed through a fluorinated double bond. Representatives of the perhalo-2,3-dihydro-1,4-dioxin class have also been prepared and found to have reactivity in general intermediate to that of the perhalodioxoles and acyclic trifluorovinyl ethers. Computational studies of the two systems established that introduction of the first double bond raises the energy substantially, while the second double bond results in a near-planar ring with dramatically increased energy content.