Oxoniumylidenemanganese | 72125-83-8

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: Oxoniumylidenemanganese
• CAS: 72125-83-8
• 化学式: HMnO
• 分子量: 71.9453
• InChiKey: IPPVBHWPMXOGAB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.18
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Oxoniumylidenemanganese 、 DL-谷氨酸 以 正己烷 为溶剂， 反应 3.0h， 生成 manganese glutamate
  参考文献：
  名称：

  Method for preparation of metal organic acid chelates

  摘要：

  揭示了一种方法，可以通过在非水环境中将有机酸配体与金属化合物反应来制备有机酸螯合物。然后通过过滤或蒸发来回收螯合物。

  公开号：

  US06670494B1
• 作为产物：
  描述：

  manganese(II) sulfate 、 氢氧化钾 以 水 为溶剂， 生成 Oxoniumylidenemanganese
  参考文献：
  名称：

  Method for preparation of metal organic acid chelates

  摘要：

  揭示了一种方法，可以通过在非水环境中将有机酸配体与金属化合物反应来制备有机酸螯合物。然后通过过滤或蒸发来回收螯合物。

  公开号：

  US06670494B1
• 作为试剂：
  描述：

  2-羟基辛酸 在 Oxoniumylidenemanganese 作用下， 生成 庚醛
  参考文献：
  名称：

  Boeeseken; Verkade, Chemisches Zentralblatt, 1917, vol. 88, # I, p. 851

  摘要：

  DOI：

文献信息

• Method for preparation of organic chelate
  申请人：Lee Ho Ke

  公开号：US20050283013A1

  公开（公告）日：2005-12-22

  A method for the preparation of organic chelates utilized as ingredients of animal feedstuffs. The organic chelates are passed to the intestines of livestock without decomposition in the stomach, and thereby have a high absorption rate. The present invention provides a preparation method of perfect chelate minerals having a high yield and containing copper, zinc, iron, manganese, or cobalt. The organic chelate mineral is prepared by precipitating metal sulfates or chlorides with sodium hydroxide or potassium hydroxide in a solution of two equivalents of an amino acid completely dissolved at above 70° C., collecting metal hydroxide by removing sodium sulfate, potassium sulfate, sodium chloride or potassium chloride through filtering, dissolving the metal hydroxide by adding the equivalent weights of hydrochloric acid, and then neutralizing the hydrochloric acid added for dissolving metal hydroxide.

  一种制备有机螯合物的方法，用作动物饲料的成分。有机螯合物在畜禽的胃中不会分解，因此具有高吸收率。本发明提供了一种制备完美螯合矿物质的方法，其产率高，含有铜、锌、铁、锰或钴。有机螯合矿物质是通过在完全溶解的两当量氨基酸溶液中，用氢氧化钠或氢氧化钾沉淀金属硫酸盐或氯化物，通过过滤去除硫酸钠、硫酸钾、氯化钠或氯化钾收集金属氢氧化物，通过加入等当重量的盐酸溶解金属氢氧化物，然后中和溶解金属氢氧化物所加的盐酸来制备的。
• The heterotopic divergent ligand N-oxide-4,4′-bipyridine (bipyMO) as directing-agent in the synthesis of oligo- or polynuclear heterometallic complexes
  作者：Daniela Belli Dell'Amico、Samuele Ciattini、Lorenzo Fioravanti、Luca Labella、Fabio Marchetti、Carlo Andrea Mattei、Simona Samaritani

  DOI：10.1016/j.poly.2017.10.009

  日期：2018.1

  The simple but rarely used heterotopic divergent ligand N-oxide-4,4'-bipyridine (bipyMO) has been exploited, for the first time, for the preparation of heterometallic derivatives, showing the ability to selectively use its two potential coordination sites in dependence of the metal ion nature. By reacting in refluxing acetonitrile (1)(infinity)[Cu(hfac)(2)(bipyMO)] with (1)(infinity)[Mn(hfac)(2)(bipyMO)] (herein completely characterized), the heterometallic self-assembled monodimensional coordination polymer containing the two regularly alternated moieties Cu(hfac)(2)[N](2) and Mn(hfac)(2)[O](2) was obtained in high yield and purity and structurally characterized. On the other hand, a molecular heterometallic compound was obtained using, as a ligand, the here prepared mononuclear complex trans-[PtCl2(bipyMO)(PPh3)], with the hypodentate bipyMO ligand coordinated to platinum through the nitrogen atom. Reaction with [Zn(hfac)(2)(DME)] afforded the heterometallic trinuclear complex trans[Zn(hfac)(2)trans-PtCl2(PPh3)(bipyMO)}(2)] that was structurally characterized. (C) 2017 Elsevier Ltd. All rights reserved.
• US2008/262114
  申请人：——

  公开号：——

  公开（公告）日：——