phosphorofluoridic acid diisobutyl ester | 563-22-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: phosphorofluoridic acid diisobutyl ester
• 英文别名: fluorophosphoric acid diisobutyl ester；Fluorophosphorsaeure-diisobutylester；Diisobutyl-fluorophosphat；Phosphorofluoridic acid, bis(2-methylporpyl) ester；1-[fluoro(2-methylpropoxy)phosphoryl]oxy-2-methylpropane
• CAS: 563-22-4
• 化学式: C₈H₁₈FO₃P
• 分子量: 212.201
• InChiKey: WUSAGAYGKIFWTG-UHFFFAOYSA-N

物化性质

• 沸点：
  100-102 °C(Press: 3 Torr)
• 密度：
  1.039 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  diisobutyl phosphite 在 potassium fluoride 、 三氯乙腈 作用下， 反应 0.5h， 以95%的产率得到phosphorofluoridic acid diisobutyl ester
  参考文献：
  名称：

  Single step fluorination of dialkylphosphites: trichloroacetonitrile–KF as an efficient reagent for the synthesis of dialkyl fluorophosphates

  摘要：

  The use of trichloroacetonitrite and KF mixture is described as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkyl fluorophosphates via in situ formation of dialkyl chlorophosphates in one-pot. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.02.051

文献信息

• Dichlorodimethylhydantoin–KF as an efficient reagent for one pot synthesis of dialkylfluorophosphates from dialkylphosphites
  作者：A.K. Gupta、J. Acharya、D.K. Dubey、M.P. Kaushik

  DOI：10.1016/j.jfluchem.2007.11.008

  日期：2008.3

  Organic-inorganic hybrid reagent dichlorodimethylhydantoin - KF (DCDMH - KF) mixture was explored as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkylfluorophosphates at room temperature and in shorter reaction times through a facile electrophilic - nucleophilic metathesis. (c) 2007 Elsevier B.V. All rights reserved.
• Trichloroisocyanuric Acid–KF as an Efficient Reagent for One-Pot Synthesis of Dialkylfluorophosphates from Dialkylphosphites
  作者：J. Acharya、A. K. Gupta、Deepak Pardasani、D. K. Dubey、M. P. Kaushik

  DOI：10.1080/00397910802215880

  日期：2008.10.22

  Trichloroisocyanuric acid-KF afforded dialkylfluorophosphates from dialkylphosphites at room temperature through a facile electrophilic-nucleophilic metathesis.
• Bany, Bulletin International de l'Academie Polonaise des Sciences et des Lettres, Classe des Sciences Mathematiques et Naturelles, Serie A: Sciences Mathematiques, 1951, p. 1,10,19
  作者：Bany

  DOI：——

  日期：——
• Single step fluorination of dialkylphosphites: trichloroacetonitrile–KF as an efficient reagent for the synthesis of dialkyl fluorophosphates
  作者：A.K. Gupta、J. Acharya、D. Pardasani、D.K. Dubey

  DOI：10.1016/j.tetlet.2008.02.051

  日期：2008.3

  The use of trichloroacetonitrite and KF mixture is described as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkyl fluorophosphates via in situ formation of dialkyl chlorophosphates in one-pot. (C) 2008 Elsevier Ltd. All rights reserved.