Physical properties of aqueous polydiorganosiloxane dispersions such as freeze/thaw stability and physical properties of the elastomeric films derived therefrom, such as high temperature heat stability and clarity, are improved by selecting an appropriate surfactant with specific characteristics. Herein, the polydiorganosiloxane dispersion is made through a direct emulsification process. The high temperature stability and clarity of the elastomer formed from our dispersion avoid surfactants which form siloxane redistribution catalysts at temperatures above 100°C. and surfactants which do not produce a matched refractive index of the phases.
通过选择具有特定特性的适当表面活性剂,可改善
水性聚二有机
硅氧烷分散体的物理性质(如冻/融稳定性)以及由此产生的弹性薄膜的物理性质(如高温热稳定性和透明度)。在这里,聚二有机
硅氧烷分散体是通过直接乳化工艺制成的。由我们的分散体形成的弹性体具有高温稳定性和透明度,避免了在温度超过 100°C 时形成
硅氧烷再分布催化剂的表面活性剂,也避免了不能产生相匹配折射率的表面活性剂。