3,6-dithiaoctahydroanthracene-1,8-dione | 381732-75-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异硫色满
• 英文名称: 3,6-dithiaoctahydroanthracene-1,8-dione
• 英文别名: 1,9-Dihydrothiopyrano[4,3-g]isothiochromene-4,6-dione
• CAS: 381732-75-8
• 化学式: C₁₂H₁₀O₂S₂
• 分子量: 250.342
• InChiKey: KXMICNCHRGZEIF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  84.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,6-dithiaoctahydroanthracene-1,8-dione 在 selenium(IV) oxide 、 氯化亚砜 、 sodium acetate 作用下， 以 甲醇 、 溶剂黄146 为溶剂， 生成 3,6-dithia-3,4,5,6-tetrahydroanthracene[1,2-d][1,2,3]selenadiazole[7,8-d][1,2,3]thiadiazole
  参考文献：
  名称：

  A NEW CLASS OF FUSEDBIS[1,2,3] SELENA AND/OR THIADIAZOLES

  摘要：

  A novel class of bis selena and/or thiadiazoles were prepared by the reaction of semicarbazones of 3,6-dithiaoctahydrophenanthrene- 1,8-dione, 3,6-dithiaoctahydroanthracene- 1,8-dione and 3,7-dithiaoctahydroanthracene-1,5-dione with SeO2 and SOCl2, respectively. The latter, in turn, were obtained from 1,2-, 1,3- and 1,4-xylylenedimercaptoacetic acids.

  DOI：

  10.1081/scc-100106035
• 作为产物：
  描述：

  间二溴苄 在 sodium hydroxide 、 phosphorus pentoxide 作用下， 以 甲醇 、 苯 为溶剂， 生成 3,6-dithiaoctahydroanthracene-1,8-dione
  参考文献：
  名称：

  A NEW CLASS OF FUSEDBIS[1,2,3] SELENA AND/OR THIADIAZOLES

  摘要：

  A novel class of bis selena and/or thiadiazoles were prepared by the reaction of semicarbazones of 3,6-dithiaoctahydrophenanthrene- 1,8-dione, 3,6-dithiaoctahydroanthracene- 1,8-dione and 3,7-dithiaoctahydroanthracene-1,5-dione with SeO2 and SOCl2, respectively. The latter, in turn, were obtained from 1,2-, 1,3- and 1,4-xylylenedimercaptoacetic acids.

  DOI：

  10.1081/scc-100106035

文献信息

• A NEW CLASS OF FUSED<i>BIS</i>[1,2,3] SELENA AND/OR THIADIAZOLES
  作者：D. Bhaskar Reddy、A. Balaiah、V. Padmavathi、A. Padmaja

  DOI：10.1081/scc-100106035

  日期：2001.1

  A novel class of bis selena and/or thiadiazoles were prepared by the reaction of semicarbazones of 3,6-dithiaoctahydrophenanthrene- 1,8-dione, 3,6-dithiaoctahydroanthracene- 1,8-dione and 3,7-dithiaoctahydroanthracene-1,5-dione with SeO2 and SOCl2, respectively. The latter, in turn, were obtained from 1,2-, 1,3- and 1,4-xylylenedimercaptoacetic acids.