(η(5)-C5H5)Fe(CO)2C6H4Fe(CO)2(η(5)-C5H5) | 119945-86-7

• 英文名称: (η(5)-C5H5)Fe(CO)2C6H4Fe(CO)2(η(5)-C5H5)
• 英文别名: 1,4-C6H4Fp2
• CAS: 119945-86-7
• 化学式: C₂₀H₁₄Fe₂O₄
• 分子量: 430.023
• InChiKey: CVGKWTQLGDEVMS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η(5)-C5H5)Fe(CO)2C6H4Fe(CO)2(η(5)-C5H5) 在 一氧化碳 、 氢气 作用下， 以 四氢呋喃 为溶剂， 以37%的产率得到cyclopentadienyl iron(II) dicarbonyl dimer
  参考文献：
  名称：

  The synthesis and reactivity of some μ-phthaloyl and μ-phenylene complexes

  摘要：

  The binuclear mu-phthaloyl compounds 1,4-C6H4(COM)2, where M = Re(CO)5, Mn(CO)5, eta-5-C5H5Fe(CO)2, eta-5-C5H5Mo(CO)3, Rh(PPh3)2Cl2 or Co(CO)3(PPh3), have been prepared and converted to the mu-phenylene compounds 1,4-C6H4M2, where M = Re(CO)5. Mn(CO)5 or eta-5-C5H5Fe(CO)2. The reactions of the mu-phthaloyl compounds with halogens, reducing agents and PPh3 are reported, as are the reactions of the mu-phenylene complexes with CO, synthesis gas, SO2, halogens and tertiary phosphines.

  DOI：

  10.1016/s0277-5387(00)83759-6
• 作为产物：
  描述：

  1,4-C6H4(CO(η5-C5H5)Fe(CO)2)2 以 甲苯 为溶剂， 以26%的产率得到(η(5)-C5H5)Fe(CO)2C6H4Fe(CO)2(η(5)-C5H5)
  参考文献：
  名称：

  The synthesis and reactivity of some μ-phthaloyl and μ-phenylene complexes

  摘要：

  The binuclear mu-phthaloyl compounds 1,4-C6H4(COM)2, where M = Re(CO)5, Mn(CO)5, eta-5-C5H5Fe(CO)2, eta-5-C5H5Mo(CO)3, Rh(PPh3)2Cl2 or Co(CO)3(PPh3), have been prepared and converted to the mu-phenylene compounds 1,4-C6H4M2, where M = Re(CO)5. Mn(CO)5 or eta-5-C5H5Fe(CO)2. The reactions of the mu-phthaloyl compounds with halogens, reducing agents and PPh3 are reported, as are the reactions of the mu-phenylene complexes with CO, synthesis gas, SO2, halogens and tertiary phosphines.

  DOI：

  10.1016/s0277-5387(00)83759-6

文献信息

• Electrochemically induced aromatic nucleophilic substitution in p-diiodobenzene with [(η5-C5H5)Fe(CO)2]− and [(η5-C5H5)W(CO)3]−-anions
  作者：T.V. Magdesieva、I.I. Kukhareva、G.A. Artamkina、I.P. Beletskaya、K.P. Butin

  DOI：10.1016/0022-328x(94)05077-o

  日期：1995.2

  [(η5-C5H5W(CO)3]− were studied using a complex of electrochemical techniques (cyclic voltammetry, rotating ring-disk electrode and preparative scale electrolysis). For [(η5-C5H5)Fe(CO)2]− it was shown that aromatic nucleophilic substitution of either one or two iodine atoms in p-diiodobenzene for η5-cyclopentadienylirondicarbonyl can be performed through electrochemical activation of the aryl halide. The ratio

  的反应p -diiodobenzene与[（η 5 -C 5 H ^ 5）的Fe（CO）2 ] -和[（η 5 -C 5 H ^ 5 W（CO）3 ] -使用复杂的电化学技术进行了研究（循环伏安法，旋转环盘电极和制备规模电解）在[（η 5 -C 5 H ^ 5）的Fe（CO）2 ] -它表明一个或两个碘原子的芳族亲核取代p -diiodobenzene为了η 5 -cyclopentadienylirondicarbonyl可以通过芳基卤的电化学活化来进行。之比（η 5 -C 5 H ^ 5）的Fe（CO）2 C ^ 6 ħ 4 I和（η 5 -C 5 H ^ 5）的Fe（CO）2 C ^ 6 ħ 4的Fe（CO）2（η 5 - ç 5 ħ 5）显示出在电解条件强烈地取决于：电极电位电解持续时间等的（收率η 5 -C 5ħ 5）的Fe（CO）2 C ^ 6 ħ 4的Fe（CO）2（η 5 -C
• Hunter, Allen D.; Szigety, Andrew B., Organometallics, 1989, vol. 8, # 11, p. 2670 - 2679
  作者：Hunter, Allen D.、Szigety, Andrew B.

  DOI：——

  日期：——
• Hunter, Allen D., Organometallics, 1989, vol. 8, # 4, p. 1118 - 1120
  作者：Hunter, Allen D.

  DOI：——

  日期：——