gadolinium phthalocyanine chloride | 56604-50-3

• 英文名称: gadolinium phthalocyanine chloride
• CAS: 56604-50-3
• 化学式: C₃₂H₁₆ClGdN₈
• 分子量: 705.236
• InChiKey: ATINROFVTWZRHV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  gadolinium phthalocyanine chloride 在 溶剂黄146 作用下， 以 乙醇 、 溶剂黄146 为溶剂， 生成 酞青
  参考文献：
  名称：

  Mutual Influence of Ligands and Reactivity of Gd and Dy Acidophthalocyaninate Complexes

  摘要：

  The results of the kinetic study of dissociation of Gd(III) and Dy(III) complexes with phthalocyanine of the composition (X)LnPc (X is single-charged acido ligand) with isolation of macrocyclic ligand depending on the temperature, composition of mixed ethanol-acetic acid solvent, and the nature of acido ligand are presented. The total kinetic equations, the rate constants, and activation parameters of dissociation reaction are determined. The stoichiomeric mechanism is suggested for the complex dissociation involving the limiting elementary reaction between acetic acid molecule and the complex that occurs as the chelate salt (X)LnPc or the outer-sphere complex [(HOAc)LnPc]X-+(-). The state of metal phthalocyaninate at the reaction slow stage is shown to be determined by the electronic structure of the metal cation, the strength of binding of the axial ligand, and by its cis-effect on the metal bonds with macrocycle.

  DOI：

  10.1023/b:ruco.0000040727.21739.44
• 作为产物：
  描述：

  dilitium phthalocyanine 、 氯化钆 在 水 作用下， 以 水 、 二甲基亚砜 为溶剂， 生成 gadolinium phthalocyanine chloride
  参考文献：
  名称：

  Mutual Influence of Ligands and Reactivity of Gd and Dy Acidophthalocyaninate Complexes

  摘要：

  The results of the kinetic study of dissociation of Gd(III) and Dy(III) complexes with phthalocyanine of the composition (X)LnPc (X is single-charged acido ligand) with isolation of macrocyclic ligand depending on the temperature, composition of mixed ethanol-acetic acid solvent, and the nature of acido ligand are presented. The total kinetic equations, the rate constants, and activation parameters of dissociation reaction are determined. The stoichiomeric mechanism is suggested for the complex dissociation involving the limiting elementary reaction between acetic acid molecule and the complex that occurs as the chelate salt (X)LnPc or the outer-sphere complex [(HOAc)LnPc]X-+(-). The state of metal phthalocyaninate at the reaction slow stage is shown to be determined by the electronic structure of the metal cation, the strength of binding of the axial ligand, and by its cis-effect on the metal bonds with macrocycle.

  DOI：

  10.1023/b:ruco.0000040727.21739.44