Tris(1,1,2,2,2-pentafluoroethyl) phosphate | 447411-37-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: Tris(1,1,2,2,2-pentafluoroethyl) phosphate
• CAS: 447411-37-2
• 化学式: C₆F₁₅O₄P
• 分子量: 452.01
• InChiKey: WBJDAYNUJLJYHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  19

文献信息

• Nonaqueous electrolyte and nonaqueous-electrolyte secondary battery
  申请人：Maruo Tatsuya

  公开号：US20060035137A1

  公开（公告）日：2006-02-16

  A nonaqueous electrolyte which contains an ionic liquid having general formula (1) below and a melting point not higher than 50° C., a compound which reductively decomposes at a more noble potential than the ionic liquid, and a lithium salt. In formula (1), R 1 to R 4 are each independently an alkyl group of 1 to 5 carbons or an alkoxyalkyl group of the formula R′—O—(CH 2 ) n — (R′ being methyl or ethyl, and the letter n being an integer from 1 to 4), and any two from among R 1 , R 2 , R 3 and R 4 may together form a ring, with the proviso that at least one of R 1 to R 4 is an alkoxyalkyl group of the above formula. X is a nitrogen atom or a phosphorus atom, and Y is a monovalent anion.

  一种非水电解质，包含具有通式（1）且熔点不高于50°C的离子液体，一个在比离子液体更高的电位下还原分解的化合物和一个锂盐。在公式（1）中，R1到R4各自独立地是1到5个碳的烷基或公式R′—O—（CH2）n—的烷氧基烷基（其中R′为甲基或乙基，字母n为1到4的整数），其中任意两个来自R1、R2、R3和R4的基团可以形成一个环，但至少有一个基团来自上述公式的烷氧基烷基。X是氮原子或磷原子，Y是一价阴离子。
• Nonaqueous electrolyte, electrical double-layer capacitors, and nonaqueous electrolyte secondary cells
  申请人：Maruo Tatsuya

  公开号：US20060034035A1

  公开（公告）日：2006-02-16

  Secondary cells and electrical double-layer capacitors of excellent charge-discharge efficiency, stability and low-temperature properties can be obtained using nonaqueous electrolytes which contain an ionic liquid that has general formula (1) below and is liquid at not higher than 50° C. and an ion-conductive polymer. In formula (1), R 1 to R 4 are each independently an alkyl group of 1 to 5 carbons or an alkoxyalkyl group of the formula R′—O—(CH 2 ) n —(R′ being methyl or ethyl, and the letter n being an integer from 1 to 4), and any two from among R 1 , R 2 , R 3 and R 4 may together form a ring, with the proviso that at least one of R 1 to R 4 is an alkoxyalkyl group of the above formula. X is a nitrogen atom or a phosphorus atom, and Y is a monovalent anion.

  非水电解质中含有一种具有通式（1）的离子液体和离子导电聚合物，可以获得具有优异的充放电效率、稳定性和低温性能的二次电池和电容器。该离子液体在不高于50°C的温度下为液体。 在式（1）中，R1至R4分别独立地表示1到5个碳原子的烷基或具有以下通式的烷氧烷基（其中R′为甲基或乙基，字母n为1到4的整数），而R1、R2、R3和R4中的任意两个可以共同形成一个环，但至少R1至R4中的一个是上述通式的烷氧烷基。X是氮原子或磷原子，Y是一价阴离子。
• PHOTOSENSITIVE COMPOSITION
  申请人：Motofuji Shihei

  公开号：US20120142806A1

  公开（公告）日：2012-06-07

  Provided is a photosensitive composition which can be cured with low energy consumption, even when a substance (such as a colorant) that attenuates or shades an illumination light is contained in a high concentration or even when the photosensitive composition is in the form of a thick film. Specifically provided is a photosensitive composition which comprises the following four components: (1) a radical initiator (A); (2) an acid generator (B) or a base generator (C); (3) a polymerizable substance (D); and (4) a colorant (E), a metal oxide powder (F), or a metal powder (G). Further, the photosensitive composition is characterized in that the radical initiator (A), the acid generator (B), and/or the base generator (C) generates an active species (H) through irradiation with an active ray of light; the active species (H) reacts the radical initiator (A), the acid generator (B), or the base generator (C) to form another species (I); and thus the polymerization of the polymerizable substance (D) by means of the active species (I) proceeds, said active species (H) or (I) being an acid or a base.

  提供的是一种光敏组合物，即使含有高浓度的能够衰减或遮蔽照明光的物质（如颜料），或者即使光敏组合物呈现为厚膜形式，也能够以低能耗进行固化。具体而言，提供的光敏组合物包括以下四个组分：（1）自由基引发剂（A）；（2）酸发生剂（B）或碱发生剂（C）；（3）可聚合物质（D）；以及（4）颜料（E）、金属氧化物粉末（F）或金属粉末（G）。此外，光敏组合物的特点在于，自由基引发剂（A）、酸发生剂（B）和/或碱发生剂（C）通过活性光线的照射生成活性物质（H）；活性物质（H）与自由基引发剂（A）、酸发生剂（B）或碱发生剂（C）反应形成另一种物质（I）；因此，通过活性物质（I）对可聚合物质（D）进行聚合，所述活性物质（H）或（I）为酸或碱。
• Pregel compositions for polymer gel electrolytes, method of dehydrating pregel compositions, secondary cell, and electrical double-layer capacitor
  申请人：NISSHINBO INDUSTRIES INC.

  公开号：EP1239531A2

  公开（公告）日：2002-09-11

  A pregel composition is added to an organic electrolyte solution of an electrolyte salt in a nonaqueous solvent for causing the solution to gel and form a polymer gel electrolyte. The pregel composition is dehydrated by azeotropic distillation and has a moisture content of not more than 1,000 ppm as determined by Karl Fischer titration. Polymer gel electrolytes prepared with such a pregel composition have a good electrochemical stability, and are thus highly suitable for use in secondary cells and electrical double-layer capacitors.

  在非水溶剂中的电解质盐的有机电解质溶液中加入预凝胶组合物，使溶液凝胶化，形成聚合物凝胶电解质。预凝胶组合物通过共沸蒸馏脱水，经卡尔费休滴定法测定，水分含量不超过 1,000 ppm。用这种预凝胶组合物制备的聚合物凝胶电解质具有良好的电化学稳定性，因此非常适合用于二次电池和双层电容器。
• COMPOSITION FOR POLYMER GEL ELECTROLYTE, POLYMER GEL ELECTROLYTE, AND SECONDARY BATTERY AND ELECTRIC DOUBLE LAYER CAPACITOR EACH EMPLOYING THE ELECTROLYTE
  申请人：Nisshinbo Industries, Inc.

  公开号：EP1391958A1

  公开（公告）日：2004-02-25

  A polymer gel electrolyte composition is composed primarily of (A) a polymeric compound having an average degree of polymerization of at least 20 which contains polyvinyl alcohol units of the following general formula (1): wherein n is a number of at least 20 and some or all of the hydroxyl groups on the polyvinyl alcohol units are substituted with cyanated monovalent hydrocarbon groups; (B) an ion-conductive salt; (C) a compound having at least two reactive double bonds on the molecule; and (D) an organic electrolyte solution.

  一种聚合物凝胶电解质组合物主要由以下物质组成：(A) 一种平均聚合度至少为 20 的聚合物化合物，该化合物含有通式(1)如下的聚乙烯醇单元： 其中 n 至少为 20，聚乙烯醇单元上的部分或全部羟基被氰化单价烃基取代； (B) 离子导电盐； (C) 分子上至少有两个活性双键的化合物；以及 (D) 有机电解质溶液。