chromium distannide | 158553-27-6

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: chromium distannide
• 英文别名: lambda~2~-Stannane--chromium (2/1)；chromium;λ2-stannane
• CAS: 158553-27-6
• 化学式: CrSn₂
• 分子量: 289.416
• InChiKey: IMGCDCQQKXGUKD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  铬 、 tin 以 neat (no solvent, solid phase) 为溶剂， 生成 chromium distannide
  参考文献：
  名称：

  Crystal structures of VSn2, NbSn2 and CrSn2 with Mg2Cu-type structure and NbSnSb with CuAl2-type structure

  摘要：

  Several binary stannides of the early transition metals T have been reported with the composition T2Sn3 previously. However, the present structure refinements from single-crystal X-ray data show that they have the compositions VSn2, NbSn2, and CrSn2 (R = 0.028, R = 0.018 and R = 0.021 with 17 variable parameters and 828, 512 and 440 structure factors respectively). Their orthorhombic Mg2Cu-type structure is closely related to the structures of MoSn2 (Mg2Ni type) and CuAl2. The latter structure type was confirmed for NbSnSb by a structure refinement from single-crystal data (R = 0.010 for eight variables and 254 F values). Electrical conductivity measurements show CrSn2 and MoSn2 to be metallic conductors.

  DOI：

  10.1016/0925-8388(94)90136-8