Matrix-isolation studies by electronic spectroscopy of group IIIA metal–water photochemistry
作者:Monte A. Douglas、Robert H. Hauge、John L. Margrave
DOI:10.1039/f19837901533
日期:——
This paper reports an investigation of the electronic structures of the Group IIIA metal atom hydration reaction intermediates (M⋯OH2adducts) and their subsequent photolysis products (HMOH, MOH and MO) where M = Al, Ga and In. The metal–water interaction in the adduct is sufficiently strong to perturb the electronic structure of the metal atom; consequently, one observes a unique band structure for
本文报告了IIIA组金属原子水合反应中间体(M⋯OH 2加合物)及其后续光解产物(HMOH,MOH和MO)的电子结构的研究,其中M = Al,Ga和In。加合物中的金属与水的相互作用足够强,足以扰乱金属原子的电子结构。因此,人们观察到加合物具有独特的能带结构,该加合物从金属的原子共振跃迁中发生了红移。提出了分子轨道和电子状态间的相关性。