[Ni(tcnoetOH)2(4,4'-bipyridine)(H2O)2] | 1072010-83-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 亚胺内酰胺
• 英文名称: [Ni(tcnoetOH)2(4,4'-bipyridine)(H2O)2]
• 英文别名: [Ni(tcnoetOH)2(4,4'-bpy)(H2O)2]
• CAS: 1072010-83-3
• 化学式: C₂₈H₂₂N₁₀NiO₆
• 分子量: 653.236
• InChiKey: MGYHIZOHSLLOKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,4'-联吡啶 、 nickel(II) chloride hexahydrate 、 potassium 1,1,3,3-tetracyano-2-(2-hydroxyethyl)propenide 、 水 以 乙醇 、 水 为溶剂， 生成 [Ni(tcnoetOH)2(4,4'-bipyridine)(H2O)2]
  参考文献：
  名称：

  New coordination polymers based on a novel polynitrile ligand: Synthesis, structure and magnetic properties of the series [M(tcnoetOH)2(4,4′-bpy)(H2O)2] (tcnoetOH−=[(NC)2CC(OCH2CH2OH)C(CN)2]−; M=Fe, Co and Ni)

  摘要：

  A novel polynitrile anionic ligand, tcnoetOH (=[NC)(2)CCOCH(2)CH(2)OH)CCN)(2)] ), has been synthesized by a one-pot reaction from a cyclic acetal and malononitrile. This ligand has been successfully used to prepare, with 4,4'-bpy as co-ligand, a novel series of coordination polymers formulated as [MtcnoetOH) 24,4'-bpy)H(2)O)(2)] with MII) = Fe 1), Co 2) and Ni 3). These isostructural compounds present a linear chain structure consisting of octahedrally coordinated metal ions bridged by trans 4,4'-bpy ligands. The coordination sphere of the metal ions is completed with two terminal tcnoetOH ligand and two water molecules. The magnetic properties indicate that the three compounds are paramagnetic, as expected from the long 4,4'-bpy bridge connecting the metal atoms. Their magnetic properties have been fitted with a model of isolated ions including a zero field splitting for the FeII) and NiII) derivatives. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.02.046