(hydroxy)copper | 63035-26-7

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: (hydroxy)copper
• CAS: 63035-26-7
• 化学式: CuO
• 分子量: 81.546
• InChiKey: QPLDLSVMHZLSFG-NLQOEHMXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.12
• 重原子数：
  2.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  (18)O-ozone 、 铜 生成 (hydroxy)copper 、
  参考文献：
  名称：

  Matrix reactions of copper atoms and ozone molecules. Infrared spectrum of CuO

  摘要：

  The matrix reactions of copper atoms with ozone have been studied by infrared spectroscopy. Two products were found in the initial deposit: CuO3, which has a strong absorption at 802.3 cm−1, and CuO, which has its main feature, corresponding to the 63Cu16O isotopic species, at 628.0 cm−1 in solid argon. Copper atom reactions with oxygen-18-enriched ozone samples were used to obtain species identifications. The CuO3 absorption was very similar in frequency and isotopic splitting behavior to alkali and alkaline earth metal ozonide species previously studied in matrices. The CuO frequency is in good agreement with gas phase measurements which put the ground state CuO vibrational fundamental at 631.3 cm−1. Temperature cycling of the Cu–O3 matrices leads to CuO4 formation by the secondary reaction of CuO with unreacted ozone.

  DOI：

  10.1063/1.441676

文献信息

• Mechanism of the powder reaction between CuSO4(s) and PbO (α and β): A thermoanalytical and mass spectrometric study
  作者：Emilia García-Clavel、Isabel Tejedor Tejedor、Hermógenes G. Sanz

  DOI：10.1016/0022-4596(81)90384-4

  日期：1981.11

  Thermoanalytical studies and isotopic analysis of oxygen have been used to establish the actual mechanism of the exchange reaction (the reactants are fine powders). Whether SO3 is or is not involved in the reaction process depends on the crystalline form of PbO, and in the case of α-PbO on the type of heating. Oxygen isotope analysis, carried out on reaction products when PbO is enriched in 18O and

  氧气的热分析研究和同位素分析已用于确定交换反应的实际机理（反应物为细粉）。SO 3是否参与反应过程取决于PbO的晶体形式，在α-PbO的情况下取决于加热的类型。当PbO富含18 O且气态SO 3在过程中不起作用时，对反应产物进行的氧同位素分析表明，阳离子和氧的传输都参与了反应机理。