1,4-cyclohexanedimethanol bis(diphenyl phosphate) | 476371-27-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: 1,4-cyclohexanedimethanol bis(diphenyl phosphate)
• 英文别名: [4-(Diphenoxyphosphoryloxymethyl)cyclohexyl]methyl diphenyl phosphate
• CAS: 476371-27-4
• 化学式: C₃₂H₃₄O₈P₂
• 分子量: 608.565
• InChiKey: IWVZXFYPRKLXKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  42
• 可旋转键数：
  14
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  89.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1,4-环己烷二甲醇 、 氯磷酸二苯酯 在 氯化镁 作用下， 以 甲醇 、 正己烷 为溶剂， 以82.2%的产率得到1,4-cyclohexanedimethanol bis(diphenyl phosphate)
  参考文献：
  名称：

  1,4-cyclohexanedimethanol bis (diaryl phosphate)

  摘要：

  揭示了用于聚合物的新型阻燃化合物，其中包括1,4-环己二甲醇双(二苯基磷酸酯)。这些化合物可以通过在适当溶剂（如己烷）中，在催化剂（如氯化镁）存在下，通过反应1,4-环己二甲醇和二苯基卤代磷酸酯（如二苯基氯代磷酸酯）来合成。

  公开号：

  US05616770A1

文献信息

• THERMOPLASTIC RESIN COMPOSITION, WATER-BASED COMPOSITION, HEAT-SENSITIVE PRESSURE-SENSITIVE ADHESIVE, AND HEAT-SENSITIVE SHEET
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP0989162A1

  公开（公告）日：2000-03-29

  The thermoplastic resin composition of the present invention, which is a thermoplastic resin composition containing a thermoplastic resin and a solid plasticizer, is characterized in that the solid plasticizer is at least one compound selected from the group of three kinds of compounds (i) a multiester compound of (A) (A1) an alcohol having a substituted cyclohexane ring or a substituted cyclohexene ring substituted by at least one of an alkyl group and having at least 3 carbons in the alkyl group, or (A2) an alcohol having a bridged ring containing at least one of a six-membered carbon ring with (B) a polybasic acid, (iia) a phosphorus compound having a melting point of 55 to 100°C, etc., and (iiia) a diester compound of (C) (c1) hydroquinone or lesorcinol wherein benzene ring may be substituted by an alkyl group, or (c2) catechol wherein benzene ring is substituted by an alkyl group with (D) an organic monobasic acid. Further, the thermoplastic resin composition of the present invention is high in safeness to human genital organs. The thermoplastic resin composition can be employed as a thermally- and pressure-sensitive adhesive, and there can be obtained a thermally- and pressure-sensitive adhesive sheet having an excellent blocking resistance by coating it over a base material sheet.

  本发明的热塑性树脂组合物是一种含有热塑性树脂和固体增塑剂的热塑性树脂组合物，其特征在于固体增塑剂至少是一种选自以下三类化合物的化合物 (i) (A)的多元酯化合物 (A1)具有取代环己烷环或被至少一个烷基取代的取代环己烯环且烷基中至少有 3 个碳的醇、(A1) 具有至少一个烷基且烷基中至少有 3 个碳的取代环己烷环或取代环己烯环的醇，或 (A2) 具有至少一个六元碳环的桥环的醇，且桥环中含有 (B) 多基酸、(iia) 熔点为 55 至 100°C 的磷化合物等。,和(iiia)(C)(c1)对苯二酚或间苯二酚（其中苯环可被烷基取代）或(c2)邻苯二酚（其中苯环被烷基取代）与(D)有机单碱基酸的二酯化合物。此外，本发明的热塑性树脂组合物对人体生殖器官的安全性高。本发明的热塑性树脂组合物可用作热敏和压敏粘合剂，通过在基材板材上涂覆本发明的热敏和压敏粘合剂，可获得抗阻塞性极佳的热敏和压敏粘合剂板材。
• BIS(CIS-3,3,5-TRIMETHYLCYCLOHEXYL) PHTHALATE, PROCESS FOR PRODUCING THE SAME, AND THERMOPLASTIC RESIN COMPOSITION
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1298121A1

  公开（公告）日：2003-04-02

  Bis(cis-3,3,5-trimethylcyclohexyl) phthalate includes stereoisomers represented by following Formulae (1), (2) and (3) and satisfies the following conditions:    a+b+c=100, and 50

  邻苯二甲酸二(顺式-3,3,5-三甲基环己基)酯包括以下式(1)、(2)和(3)所代表的立体异构体，并满足以下条件： a+b+c=100，且 50
• Heat-sensitive pressure-sensitive adhesive and heat-sensitive adhesive material
  申请人：Ricoh Company, Ltd.

  公开号：EP1882726A1

  公开（公告）日：2008-01-30

  A heat-sensitive pressure-sensitive adhesive which contains at least a thermoplastic resin and a thermofusible material, wherein the thermoplastic resin has a glass transition temperature of-70°C to -30°C, and the thermofusible material comprises triphenylphosphine, and at least any one of tris (2,4-di-t-butylphenyl) phosphite and tetrakis [3-(3,5-di-t-butyl-4-hydroxyphenyl) propionate] methane, or a heat-sensitive pressure-sensitive adhesive which contains at least a thermoplastic resin, a thermofusible material and a non-thermofusible material, wherein the thermofusible material contains triphenylphosphine

  一种热敏压敏粘合剂，它至少含有一种热塑性树脂和一种热熔性材料，其中热塑性树脂的玻璃化温度为-70℃至-30℃，热熔性材料包括三苯基膦、三(2. 4-二叔丁基苯基)亚磷酸酯和四[3-(3,5-二叔丁基-4-羟基苯基丙酸]甲烷中的至少任一种，或一种热敏压敏粘合剂、4-二叔丁基苯基）亚磷酸酯和四[3-（3,5-二叔丁基-4-羟基苯基）丙酸]甲烷中的至少任一种，或一种热敏压敏粘合剂，它至少含有一种热塑性树脂、一种热熔性材料和一种非热熔性材料，其中热熔性材料含有三苯基膦
• Bis(cis-3,3,5-trimethylcyclohexyl) phthalate, process for producing the same, and thermoplastic resin composition
  申请人：——

  公开号：US20020193482A1

  公开（公告）日：2002-12-19

  Bis(cis-3,3,5-trimethylcyclohexyl) phthalate includes stereoisomers represented by following Formulae (1), (2) and (3) and satisfies the following conditions: 1 a+b+c=100, and 50

  邻苯二甲酸二（顺式-3,3,5-三甲基环己基）酯包括以下式（1）、（2）和（3）所代表的立体异构体，并满足以下条件： 1 a+b+c=100, and 50
• US5616770A
  申请人：——

  公开号：US5616770A

  公开（公告）日：1997-04-01