磷酸三[3,5-二(1,1-二甲基乙基)-4-羟基苯基]酯 | 17709-43-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 磷酸三[3,5-二(1,1-二甲基乙基)-4-羟基苯基]酯
• 英文名称: Tris(3,5-di-tert-butyl-4-hydroxyphenyl)phosphat
• 英文别名: 1,4-Benzenediol, 2,6-bis(1,1-dimethylethyl)-, 4,4',4''-phosphate；tris(3,5-ditert-butyl-4-hydroxyphenyl) phosphate
• CAS: 17709-43-2
• 化学式: C₄₂H₆₃O₇P
• 分子量: 710.932
• InChiKey: HOQYYGLJPAIXDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.9
• 重原子数：
  50
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  105
• 氢给体数：
  3
• 氢受体数：
  7

文献信息

• Improved process for making random ethylene alkyl acrylate copolymers
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0113904A2

  公开（公告）日：1984-07-25

  An improved continuous process for producing random ethylene/acrylate/cure-site copolymers with greater efficiency by copolymerizing therewith a small quantity of certain polyfunctional monomers, such as diallyl maleate.

  一种改进的连续生产工艺，通过与少量某些多官能团单体（如马来酸二烯丙酯）共聚，以更高的效率生产无规乙烯/丙烯酸酯/固位共聚物。
• Modification method of resins
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0612797A2

  公开（公告）日：1994-08-31

  Provided for resins by the present invention are flame-retarding, thermal stabilization and compatibilization methods, which make use of specific diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptane and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexane, or derivatives thereof. The novel derivatives, polymeric microspheres and the like are also provided.

  本发明为树脂提供了阻燃、热稳定和相容方法，这些方法利用了特定的二胍胺衍生物，主要是 2,5/2,6-双(4,6-二氨基-1,3,5-三嗪-2-基)-双环[2.2.1]庚烷和 1,3/1,4-双(4,6-二氨基-1,3,5-三嗪-2-基)-环己烷或其衍生物。此外，还提供了新型衍生物、聚合物微球等。
• Cycloolefin resin pellets and a process for producing a molded product thereof
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0637612A2

  公开（公告）日：1995-02-08

  Cycloolefin resin pellets of the present invention comprises a cycloolefin resin pellet comprising at least one cycloolefin resin selecting from (A) a cycloolefin random copolymer of ethylene and a specific cycloolefin, (B) a ring-opening (co)polymer of the specific cycloolefin and (C) a hydrogenation product of the ring-opening (co)polymer (B), and a powdery coating material and/or a liquid coating material, the melting point or the glass transition point of the coating material being 200 °C or lower, and the coating material being adhered onto the surface of the cycloolefin resin pellets, so that the molded product thereof is excellent in transparency.

  本发明的环烯烃树脂颗粒包括至少一种环烯烃树脂颗粒，这种环烯烃树脂选自(A)乙烯和特定环烯烃的环烯烃无规共聚物，(B)特定环烯烃的开环（共）聚合物和(C)开环（共）聚合物(B)的氢化产物、以及粉末状涂层材料和/或液体涂层材料，涂层材料的熔点或玻璃化转变点为 200 °C 或更低，涂层材料附着在环烯烃树脂颗粒表面，从而使其模塑产品具有极佳的透明度。
• Polyolefin articles with long-term elevated temperature stability
  申请人：Clariant International Ltd.

  公开号：US20020156165A1

  公开（公告）日：2002-10-24

  A heat stabilizing composition for polyolefins comprises an oxidized, non-cationized, non-silylated sulfur black pigment, a hindered phenolic antioxidant a sulfur-containing secondary stabilizer, each in stabilizing amount, and a hindered amine. The heat stabilizing composition yields polyolefin compounds and articles having improved long term heat aging stability. Preferably, the sulfur black pigment is treated by washing, to thereby reduce the concentration of soluble sodium salts.

  一种用于聚烯烃的热稳定组合物包括一种氧化的、非阳离子化的、非硅烷化的硫黑颜料、一种受阻酚类抗氧化剂、一种含硫的二级稳定剂（每种都有稳定的用量）和一种受阻胺。这种热稳定组合物可以生产出具有更好的长期热老化稳定性的聚烯烃化合物和制品。硫黑颜料最好经过水洗处理，以降低可溶性钠盐的浓度。
• Method of manufacturing cured ethylene acrylic and polyacrylate elastomers
  申请人：——

  公开号：US20030204025A1

  公开（公告）日：2003-10-30

  An improved method of making an ethylene acrylate (AEM) elastomer or a polyacrylate (ACM) elastomer wherein an aqueous solution of hexamethylene diamine (HMDA) is employed as the curative agent rather than hexamethylene diamine carbamate (HMDAC). The HMDA reacts with the curative-site monomer derived from the monoalkyl ester of a 1,4-butene-dioic acid in the presence of water, producing (i.e., after press-curing and any secondary heat-curing) a crosslinked elastomer with properties essentially indistinguishable from that produced using HMDAC as the curative agent. Advantageously, the aqueous solution of HMDA can be blended directly into the compound or it can be deposited on an additive such as silica or carbon black prior to blending. Elastomers produced by the improved method according to the present invention are particularly useful in automotive applications requiring oil resistant compositions.

  一种制造乙烯丙烯酸酯（AEM）弹性体或聚丙烯酸酯（ACM）弹性体的改进方法，其中采用六亚甲基二胺（HMDA）水溶液而不是氨基甲酸六亚甲基二胺（HMDAC）作为固化剂。HMDA 与 1,4-丁烯二酸单烷基酯衍生的固化位点单体在有水存在的情况下发生反应，产生（即在加压固化和任何二次热固化之后）交联弹性体，其特性与使用 HMDAC 作为固化剂产生的弹性体基本无异。有利的是，HMDA 水溶液可以直接混入化合物中，也可以在混合前沉积在添加剂（如二氧化硅或炭黑）上。根据本发明的改进方法生产的弹性体尤其适用于需要耐油成分的汽车应用领域。