Pt(1,3-bis(4,4-dimethyl-2-oxazolinyl)phenyl)Cl | 668988-00-9

• 英文名称: Pt(1,3-bis(4,4-dimethyl-2-oxazolinyl)phenyl)Cl
• 英文别名: 2,6-bis(4',4'-dimethyl-2'-oxazolinyl)phenylchloroplatinum(II)；Pt(phebox)Cl
• CAS: 668988-00-9
• 化学式: C₁₆H₁₉ClN₂O₂Pt
• 分子量: 501.872
• InChiKey: PXQHVJAKJJRKEW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Pt(1,3-bis(4,4-dimethyl-2-oxazolinyl)phenyl)Cl 、 silver trifluoromethanesulfonate 以 丙酮 为溶剂， 以99%的产率得到2,6-bis(4',4'-dimethyl-2'-oxazolinyl)phenylaquoplatinum(II) triflate
  参考文献：
  名称：

  Synthesis of 2,6-Bis(2-oxazolinyl)phenylplatinum(II) NCN Pincer Complexes by Direct Cyclometalation. Catalysts for Carbon−Carbon Bond Formation

  摘要：

  1,3-Bis(4',4'-dimethyl-2'-oxazolinyl)benzene (5a) and 5-nitro-1,3-bis(4',4'-dimethyl-2'-oxazolinyl)benzene (5b) were heated in dry acetic acid with K2PtCl4 to give the corresponding 2,6-bis(4',4'-dimethyl-2'-oxazolinyl)phenylplatinum(II) chloride complexes 6a and 6b in 49 and 11% yield, respectively. The X-ray structure of 6b is reported. The main side product observed in the platination of 5a was identified as di(2-methyl-2-N-acetyl)propyl isoplithalate. In contrast, use of Pd(OAc)(2) with 5a in this protocol, followed by addition of LiBr, gave 2,6-bis(4',4'-dimethyl-2'-oxazolinyl)phenylpalladium(II) bromide in only 3% yield. Treatment of 6a with AgOTf and AgSbF6 in acetone gave quantitatively the corresponding cationic 2,6-bis(4',4'-dimethyl-2'-oxazolinyl)phenyl(aquo)platinum(II) complexes 15a and 15b. Similarly treatment of 6b with AgOTf in acetone gave 4-nitro-2,6-bis(4',4'-dimethyl-2'-oxazolinyl)phenyl(aquo)platinum(II) trifluoromethanesulfonate (15c) (72%). Complexes 15a-c, together with 2,6-bis(4',4'-dimethyl-2'-oxazolinyl)phenylaquopalladium(II) triflate (15d), were applied as catalysts for the Michael reaction between methyl vinyl ketone and ethyl cyanoacetate and the Diels-Alder reaction between acrylonitrile and cyclopentadiene. In both cases platinum complex 15a was found to be the most active, with the 4-nitro group of 15c resulting in decreased catalytic activity.

  DOI：

  10.1021/om0305162
• 作为产物：
  描述：

  间苯二甲腈 在 zinc(II) acetate dihydrate 、 溶剂黄146 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 48.0h， 生成 Pt(1,3-bis(4,4-dimethyl-2-oxazolinyl)phenyl)Cl
  参考文献：
  名称：

  具有双（恶唑啉基）苯基夹配体的铂（II）单体和二聚体配合物

  摘要：

  一系列具有式Pt（phebox）（L）+（phebox – = 1,3-双（4,4'-二甲基-2'-恶唑啉基）苯基阴离子的铂（II）配合物； L =吡啶（py） ，4-苯基吡啶，喹啉，a啶）和Pt 2（phebox）2（μ-L'）2+（L'=吡嗪，4,4'-联吡啶，1,2-双（4-吡啶基）乙烷）为准备好了。晶体学数据建立与金属中心键合到三齿phebox -和单齿配体的吡啶基。五元恶唑啉环有利于CH 2 -CMe 2扭曲构象。Pt（phebox）Cl和Pt（phebox）（py）+进行基于配体的化学可逆氧化还原反应，而其他配合物的电化学则在化学和电化学上是不可逆的。与具有1,3-双（哌啶基甲基）苯基阴离子配体（pip 2 NCN –）或相关的钳形配体的配合物相比，此处描述的每个phebox –配合物在室温的二氯甲烷溶液中均会发出强烈的发射光。源于最低的phebox ，以配体为中心的激发态。在

  DOI：

  10.1021/acs.inorgchem.5b01022