磷酸苯酯镁盐 | 62698-52-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 磷酸苯酯镁盐
• 英文名称: Phosphoric acid, monophenyl ester, magnesium salt (1:1)
• 英文别名: magnesium;phenyl phosphate
• CAS: 62698-52-6
• 化学式: C6H5MgO4P
• 分子量: 196.38
• InChiKey: JGIZKLDQCIOYLH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.49
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  72.4
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• [EN] TRIARYLMETHANE COMPOUNDS<br/>[FR] COMPOSÉS DE TRIARYLMÉTHANE
  申请人：REUTER CHEMISCHE APPBAU KG

  公开号：WO2019154727A1

  公开（公告）日：2019-08-15

  The present invention relates to triarylmethane compounds of the formula (I), which are suitable as monomers for preparing thermoplastic resins having beneficial optical properties and which can be used for producing optical devices. (I) where R1, R2 are e.g. hydrogen; Y is an alkylene group having 2, 3 or 4 carbon atoms, Ar is selected from mono-or polycyclic aryl and mono-or polycyclic hetaryl; X1, X2, X3, X4 are CH, C-Rx or N, provided that in each ring at most two of X1, X2, X3, X4 are N; Rx is e.g. halogen, CN or CH=CH2. The invention also relates to thermoplastic resins comprising a polymerized unit of the compound of formula (I).

  本发明涉及具有以下式（I）的三芳基甲烷化合物，该化合物适用作为制备具有有益光学性能的热塑性树脂的单体，并可用于生产光学器件。其中R1，R2例如是氢；Y是具有2、3或4个碳原子的烷基基团，Ar选自单环或多环芳基和单环或多环杂芳基；X1、X2、X3、X4是CH、C-Rx或N，要求在每个环中最多有两个是N；Rx例如是卤素、CN或CH=CH2。该发明还涉及包含具有上述式（I）化合物的聚合单元的热塑性树脂。
• [EN] POLYCYCLIC COMPOUNDS<br/>[FR] COMPOSÉS POLYCYCLIQUES
  申请人：REUTER CHEMISCHE APPBAU E K

  公开号：WO2020079225A1

  公开（公告）日：2020-04-23

  The present invention relates to compounds of the formula (I), which are suitable as monomers for preparing thermoplastic resins having beneficial optical properties and which can be used for producing optical devices. In Formula (I), A1, A2 are selected from mono- or bicyclic aromatic radicals and mono- or bicyclic heteroaromatic radicals; X represents e.g. a single bond, O, NH, CR6R7; Y is e.g. absent or represents a single bond, O, NH, CR8R9; R1, R2 are hydrogen, a radical Ar' or a radical Ra; R3 is Alk, O-Alk'-, O-Alk'-[O-Alk']o, O-CH2-Ar-C(O)-, O-C(O)-Ar-C(O)-or O-Alk-C(O)-,where in the last five moieties the left O is bound to A1 and A2, respectively; m, n are 0, 1 or 2; o is an integer from 1 to 10; R4, R5 are e.g. selected from CN and a radical Ra; R6, R8 are e.g. selected from hydrogen, a radical Ar' and a radical Ra; R7, R9 are e.g. selected from hydrogen, C1-C4-alkyl and a radical Ar'; Ra is selected from the group consisting of C≡C-R11 and Ar-C≡C-R11; R11 is e.g. selected from hydrogen, methyl, mono- or polycyclic aryl having from 6 to 26 carbon atoms and mono- or polycyclic hetaryl having a total of 5 to 26 atoms, which are ring members, where 1, 2, 3 or 4 of the ring atoms of hetaryl are selected from nitrogen, sulphur and oxygen, while the remainder of these atoms are carbon atoms, where mono- or polycyclic aryl are unsubstituted or substituted; and Ar is e.g. phenylene or naphthylene. The invention also relates to thermoplastic resins comprising a polymerized unit of the compound of formula (I) and to optical devices made of such resins.

  本发明涉及公式（I）的化合物，这些化合物适用作为单体制备具有有益光学性能的热塑性树脂，并可用于制造光学器件。在公式（I）中，A1、A2选自单环或双环芳香基团和单环或双环杂芳基团；X代表例如单键，O，NH，CR6R7；Y例如缺失或代表单键，O，NH，CR8R9；R1、R2为氢，基团Ar'或基团Ra；R3为Alk，O-Alk'-，O-Alk'-[O-Alk']o，O-CH2-Ar-C(O)-，O-C(O)-Ar-C(O)-或O-Alk-C(O)-，在最后五个基团中，左侧的O分别与A1和A2结合；m、n为0、1或2；o为1到10的整数；R4、R5例如选自CN和基团Ra；R6、R8例如选自氢，基团Ar'和基团Ra；R7、R9例如选自氢，C1-C4-烷基和基团Ar'；Ra选自C≡C-R11和Ar-C≡C-R11的组，R11例如选自氢，甲基，含有6到26个碳原子的单环或多环芳基和含有总共5到26个原子的单环或多环杂芳基，其中环原子中的1、2、3或4个来自氮、硫和氧，其余原子为碳原子，其中单环或多环芳基是未取代或取代的；Ar例如苯基或萘基。该发明还涉及包含公式（I）化合物聚合单元的热塑性树脂以及由这种树脂制成的光学器件。
• Aromatic-aliphatic copolycarbonate and process for producing the same
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0964016A2

  公开（公告）日：1999-12-15

  An aromatic-aliphatic copolycarbonate and a process for producing the same which comprises polycondensation of an aromatic dihydroxy compound, such as 1,1-bis(4-hydroxyphenyl)cyclohexane, tricyclo(5.2.1.02,6)decanedimethanol, and a carbonic acid diester in a molten state under heating, wherein the carbonic acid diester has a chlorine content of 20 ppm or lower. The copolycarbonate has improved refractive index, balance of dispersion, and photoelastic constant while retaining high impact resistance, high heat resistance, and excellent hue.

  一种芳香族-脂肪族共聚碳酸酯及其生产工艺，包括在加热熔融状态下对芳香族二羟基化合物（如 1,1-双（4-羟基苯基）环己烷、三环（5.2.1.02,6）癸烷二甲醇）和碳酸二酯进行缩聚，其中碳酸二酯的氯含量为 20ppm 或更低。这种共聚碳酸酯的折射率、分散平衡性和光弹性常数都得到了改善，同时还保持了高抗冲击性、高耐热性和出色的色调。
• Polycarbonate resin and process for producing the same
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1018528A2

  公开（公告）日：2000-07-12

  A polycarbonate resin obtainable by reaction of pentacyclopentadecanedimethanol with carbonic acid diester and a polycarbonate resin obtainable by reaction of pentacyclopentadecanedimethanol, an aromatic dihydroxy compound and carbonic acid diester having a low photoelastic constant and a good balance between refractive index and Abbe's number.

  一种可通过五环十五烷二甲醇与碳酸二酯反应获得的聚碳酸酯树脂，以及一种可通过五环十五烷二甲醇、芳香族二羟基化合物和碳酸二酯反应获得的聚碳酸酯树脂，其光弹性常数低，折射率和阿贝数之间平衡良好。
• Cycloaliphatic copolycarbonates, their production and use
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1065231A2

  公开（公告）日：2001-01-03

  A polycarbonate resin obtainable by reaction of pentacyclopentadecane dimethanol, at least one compound selected from the group consisting of tricyclo (5.2.1.02,6) decane dimethanol, cyclohexane-1,4-dimethanol, decalin-2,6-dimethanol and norbornane dimethanol and carbonic acid diester. This invention also describes a process for preparing this resin and the use thereof for optical products.

  一种聚碳酸酯树脂，可由五环十五烷二甲醇、至少一种选自三环（5.2.1.02,6）癸烷二甲醇、环己烷-1,4-二甲醇、癸醛-2,6-二甲醇和降冰片烷二甲醇组成的组中的化合物和碳酸二酯反应而得。本发明还介绍了制备这种树脂的工艺及其在光学产品中的应用。