phosphorofluoridic acid bis-(3-methyl-butyl) ester | 563-26-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: phosphorofluoridic acid bis-(3-methyl-butyl) ester
• 英文别名: fluorophosphoric acid diisopentyl ester；Phosphorsaeure-diisopentylester-fluorid；Fluorophosphorsaeure-diisopentylester；Di-isopentylphosphorfluoridat；Diisoamyl Fluorphosphonat；1-[fluoro(3-methylbutoxy)phosphoryl]oxy-3-methylbutane
• CAS: 563-26-8
• 化学式: C₁₀H₂₂FO₃P
• 分子量: 240.255
• InChiKey: QPJMNGDPLHFCTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  phosphonic acid bis-(3-methyl-butyl) ester 在 1,3-dichlorodimethylhydantoin-KF 作用下， 以 乙腈 为溶剂， 反应 0.5h， 以89%的产率得到phosphorofluoridic acid bis-(3-methyl-butyl) ester
  参考文献：
  名称：

  Dichlorodimethylhydantoin–KF as an efficient reagent for one pot synthesis of dialkylfluorophosphates from dialkylphosphites

  摘要：

  Organic-inorganic hybrid reagent dichlorodimethylhydantoin - KF (DCDMH - KF) mixture was explored as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkylfluorophosphates at room temperature and in shorter reaction times through a facile electrophilic - nucleophilic metathesis. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2007.11.008

文献信息

• Trichloroisocyanuric Acid–KF as an Efficient Reagent for One-Pot Synthesis of Dialkylfluorophosphates from Dialkylphosphites
  作者：J. Acharya、A. K. Gupta、Deepak Pardasani、D. K. Dubey、M. P. Kaushik

  DOI：10.1080/00397910802215880

  日期：2008.10.22

  Trichloroisocyanuric acid-KF afforded dialkylfluorophosphates from dialkylphosphites at room temperature through a facile electrophilic-nucleophilic metathesis.
• Cook; Saunders; Smith, Journal of the Chemical Society, 1949, p. 638
  作者：Cook、Saunders、Smith

  DOI：——

  日期：——