indium monodeuteride | 20655-00-9

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: indium monodeuteride
• 英文别名: indium hydride；Deuterioindium
• CAS: 20655-00-9
• 化学式: HIn
• 分子量: 116.82
• InChiKey: URLIMARWVWXBAY-IEOVAKBOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.65
• 重原子数：
  1
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  indium 、 氘 以 neat (no solvent) 为溶剂， 生成 indium monodeuteride
  参考文献：
  名称：

  The ground state infrared spectra of four diatomic deuterides (GaD, InD, TlD, AgD) and the determination of mass‐independent molecular parameters

  摘要：

  The infrared spectra of two isotopic forms of the monodeuterides of the metals gallium, indium, thallium, and silver have been measured in their ground electronic state (1Σ) in the gas phase using a diode laser spectrometer. The analysis of the experimental data was carried out in two ways: (a) a complete set of Dunham parameters was determined for each isotopic species independently and (b) all the available data over both deuterated and protonated species of a particular compound were simultaneously fitted to obtain a set of mass-independent parameters. Mass scaling coefficients, which take into account effects arising from a breakdown of the Born–Oppenheimer approximation, were determined for the hydrogen atom.

  DOI：

  10.1063/1.459877

文献信息

• Formation and Characterization of the Gallium and Indium Subhydride Molecules Ga₂H₂ and In₂H₂:  A Matrix Isolation Study
  作者：Hans-Jörg Himmel、Laurent Manceron、Anthony J. Downs、Pluton Pullumbi

  DOI：10.1021/ja0122795

  日期：2002.4.1

  spontaneously with H2 in solid Ar matrixes at 12 K to form the cyclic molecule Ga(mu-H)2Ga. In2 does not react with H2 under similar conditions, but irradiation at wavelengths near 365 nm induces the formation of the corresponding indium hydride, In(mu-H)2In. The molecules have been identified and characterized by the IR spectra displayed by matrixes containing the metal and H2, D2, HD, or H2 + D2; they

  Ga2 在 12 K 时与固体 Ar 基质中的 H2 自发反应，形成环状分子 Ga(mu-H)2Ga。In2 在类似条件下不与 H2 反应，但在波长接近 365 nm 的照射下会诱导相应的氢化铟 In(mu-H)2In 的形成。这些分子已通过包含金属和 H2、D2、HD 或 H2+D2 的基质显示的 IR 光谱进行识别和表征；它们均具有 D2h 对称性的平面二氢桥接结构，通过比较测量光谱 (i) 与量子化学计算预测的特性以及 (ii) 与已知的镓和铟氢化物的光谱进行比较。两者在可见光（λ > 450 nm）下都是光不稳定的：绿光（λ = 大约 546 nm）导致 Ga(mu-H)2Ga 异构化为 HGaGaH 和 H2GaGa 的混合物，而 In(mu-H)2In 的宽带可见光辐射 (λ > 450 nm) 会产生异构体 HInInH，以及 InH。异构化可以通过 HGaGaH、H2GaGa
• Infrared Spectra of Indium Hydrides in Solid Hydrogen and of Solid Indane
  作者：Lester Andrews、Xuefeng Wang

  DOI：10.1002/anie.200353216

  日期：2004.3.19

  One little indium: Reactions of laser‐ablated indium atoms with pure hydrogen give sharp IR absorptions corresponding to InH intermediate species. Irradiation at 193 nm maximizes further reaction to give the indane monomer InH3. Annealing provides evidence for In2H6 and ultimately the sharp absorption bands are replaced with a broad IR band centered at 1460 cm−1 assigned to solid indane (InH3)n [see Equation].$\vcenter\openup.5em\halign$#$\cr \rm InH}_3}\rightarrow 1\over 2}\rm In}_2}\rm H}_6}\rightarrow 1\over n}(\rm InH}_3})_n}\hfill\cr}}}$