Ag(tetra-bromocatechol-1H)(PPh3)2 | 898837-86-0

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物 - 醌二甲烷类
• 英文名称: Ag(tetra-bromocatechol-1H)(PPh3)2
• CAS: 898837-86-0
• 化学式: C₄₂H₃₁AgBr₄O₂P₂
• 分子量: 1057.14
• InChiKey: XLIKJCRRJVZSCK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  silver(I) acetate bis-triphenyl phosphine 、 四溴儿茶酚 以 乙醚 、 甲苯 为溶剂， 生成 Ag(tetra-bromocatechol-1H)(PPh3)2
  参考文献：
  名称：

  The first silver catechol complexes: Crystal structures of triphenylphosphine stabilized silver tetra-bromo and tetra-chloro-catechols

  摘要：

  We report the solid-state structures of the first verifiable silver complexes containing bound catechol ligands, Ag(Br4C6(OH)O)(Ph3P)(2) and Ag(Cl4C6(OH)O)(Ph3P)(2).Only highly electron-withdrawing groups. such as tetra-substituted catechols coupled with triphenylphosphine stabilizing ligands, can be used to obtain stable silver catechol complexes. Without these features, the silver is too readily reduced to the metal. In both cases where the halide is either chloride or bromide. only one of the catechol oxygens is coordinated to the silver along with the ortho-halogen, which forms the chelate ring with the metal. The second phenolic group is not involved with the coordination of the metal. Additional hydrogen bonding between the catechol groups provides for the formation of dimeric species in the solid state. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.01.009