lambda~2~-Stannane--ytterbium (1/1) | 59763-96-1

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: lambda~2~-Stannane--ytterbium (1/1)
• 英文别名: λ2-stannane;ytterbium
• CAS: 59763-96-1
• 化学式: SnYb
• 分子量: 291.75
• InChiKey: DTWJEJLRCDDJSD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  tin 、 氢化镱 以 neat (no solvent) 为溶剂， 生成 lambda~2~-Stannane--ytterbium (1/1)
  参考文献：
  名称：

  Yb-Sn-Te ternary system

  摘要：

  Phase equilibria in the Yb-Sn-Te ternary system were studied for the first time by physicochemical methods. Phase diagrams were constructed for the Yb-Sn binary subsystem and YbTe-SnTe, YbSn-SnTe, Yb(5)Sn(3)-YbTe, YbSn-YbSnTe(2), YbSnTe(2)-Te, Yb(5)Sn(3)-YbSnTe(2), Yb-SnTe, and YbSnTe(2)-Sn inner sections. A liquidus surface projection for the title system was constructed. The system was found to have the following features: one ternary compound of composition YbSnTe(2), which melts congruently at 1335 K, and extensive solid solutions based on SnTe and YbSnTe(2).

  DOI：

  10.1134/s0036023609110230

文献信息

• Yb3CoSn6 and Yb4Mn2Sn5: New polar intermetallics with 3D open-framework structures
  作者：Xiao-Wu Lei、Guo-Hua Zhong、Min-Jie Li、Jiang-Gao Mao

  DOI：10.1016/j.jssc.2008.05.036

  日期：2008.9

  Two new tertiary ytterbium transition metal stannides, namely, Yb3CoSn6 and Yb4Mn2Sn5, have been obtained by solid-state reactions of the corresponding pure elements in welded tantalum tubes at high temperature. Their crystal structures have been established by single-crystal X-ray diffraction studies. Yb3CoSn6 crystallizes in the orthorhombic space group Cmcm (no. 63) with cell parameters of a = 4.662(2), b = 15.964(6). c = 13.140(5) angstrom, V = 978.0(6) angstrom(3), and Z = 4. Its structure features a three-dimensional (3D) open-framework composed of unusual [CoSn3] layers interconnected by zigzag Sn chains, forming large tunnels along the c-axis which are Occupied by the ytterbium cations. Yb4Mn2Sn5 is monoclinic space group C2/m (no. 12) with cell parameters of a = 16 937(2). b = 4.5949(3), c = 7.6489(7) angstrom, 106.176(4), V = 571.70(8) angstrom(3), and Z = 2. It belongs to the Mg5Si6 structure type and its anionic Substructure is composed of parallel [Mn2Sn2] ladders interconnected by Unusual zigzag [Sn-3] chains, forming large tunnels along the c-axis. which are filled by the ytterbium cations. Band structure calculations based on density function theory methods were also made for both compounds. (C) 2008 Elsevier Inc. All rights reserved.