bis(4-(trifluoromethyl)phenyl)phosphate | 1404477-02-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: bis(4-(trifluoromethyl)phenyl)phosphate
• 英文别名: Bis[4-(trifluoromethyl)phenyl] hydrogen phosphate；bis[4-(trifluoromethyl)phenyl] hydrogen phosphate
• CAS: 1404477-02-6
• 化学式: C₁₄H₉F₆O₄P
• 分子量: 386.187
• InChiKey: DWJKNKVOOAQBNT-UHFFFAOYSA-N

物化性质

• 沸点：
  391.8±52.0 °C(Predicted)
• 密度：
  1.520±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  对三氟甲基苯酚 在 吡啶 、 三氯氧磷 作用下， 以 甲苯 为溶剂， 反应 1.5h， 以38%的产率得到bis(4-(trifluoromethyl)phenyl)phosphate
  参考文献：
  名称：

  Highly Chemoselective Metal-Free Reduction of Phosphine Oxides to Phosphines

  摘要：

  Unprecedented chemoselective reductions of phosphine oxides to phosphines proceed smoothly in the presence of catalytic amounts of specific Bronsted acids. By utilizing inexpensive silanes, e.g., PMHS or (EtO)(2)MeSiH, other reducible functional groups such as ketones, aldehydes, olefins, nitriles, and esters are well-tolerated under optimized conditions.

  DOI：

  10.1021/ja3069165

文献信息

• INFRARED ABSORBING COMPOSITIONS, INFRARED CUT FILTERS, CAMERA MODULES AND PROCESSES FOR MANUFACTURING CAMERA MODULES
  申请人：FUJIFILM Corporation

  公开号：US20160011336A1

  公开（公告）日：2016-01-14

  Provided are infrared absorbing compositions that allow for preparing infrared absorption patterns having good adhesiveness to substrates on which the infrared absorbing composition is applied. The infrared absorbing composition contains an infrared absorbing material, and a polymerizable compound containing a partial structure represented by formula (1) below: wherein R 1 represents a hydrogen atom or an organic group; the asterisk (*) indicates a point of attachment to another atom.
• Highly Chemoselective Metal-Free Reduction of Phosphine Oxides to Phosphines
  作者：Yuehui Li、Liang-Qiu Lu、Shoubhik Das、Sabine Pisiewicz、Kathrin Junge、Matthias Beller

  DOI：10.1021/ja3069165

  日期：2012.11.7

  Unprecedented chemoselective reductions of phosphine oxides to phosphines proceed smoothly in the presence of catalytic amounts of specific Bronsted acids. By utilizing inexpensive silanes, e.g., PMHS or (EtO)(2)MeSiH, other reducible functional groups such as ketones, aldehydes, olefins, nitriles, and esters are well-tolerated under optimized conditions.