lead hydrogen phosphate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属氧阴离子化合物
• 英文名称: lead hydrogen phosphate
• 英文别名: lead monohydrogen phosphate；2-Hydroxy-1,3,2lambda5,4lambda2-dioxaphosphaplumbetane 2-oxide；2-hydroxy-1,3,2λ5,4λ2-dioxaphosphaplumbetane 2-oxide
• 化学式: HO₄P*Pb
• 分子量: 303.179
• InChiKey: AVVSGTOJTRSKRL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.57
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  83.4
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  lead hydrogen phosphate 在 水 作用下， 以 not given 为溶剂， 生成 lead(II) pyrophosphate
  参考文献：
  名称：

  Trau, J., Acta Chimica Academiae Scientiarum Hungaricae, 1959, vol. 18, p. 387 - 391

  摘要：

  DOI：
• 作为产物：
  描述：

  lead(II) dihydrogen orthophosphate 以 neat (no solvent, solid phase) 为溶剂， 生成 lead hydrogen phosphate
  参考文献：
  名称：

  Worzala, H.; Jost, K. H., Zeitschrift für anorganische und allgemeine Chemie

  摘要：

  DOI：

文献信息

• Extending the temperature sensing range using Eu³⁺ luminescence up to 865 K in a single crystal of EuPO₄
  作者：Suchinder K. Sharma、Thomas Köhler、Jan Beyer、Margret Fuchs、Richard Gloaguen、Johannes Heitmann

  DOI：10.1039/c9cp03501j

  日期：——

  Extending the temperature sensing range up to 865 K using an appropriate choice of excitation wavelength and coupling scheme in a single crystal sample of EuPO₄.

  在EuPO₄的单晶样品中，通过选择适当的激发波长和耦合方案，将温度感应范围扩展到865 K。
• Non-quenching photoluminescence emission up to at least 865 K upon near-UV excitation in a single crystal of orange-red emitting SmPO₄
  作者：Suchinder K. Sharma、Jan Beyer、Richard Gloaguen、Johannes Heitmann

  DOI：10.1039/c9cp05663g

  日期：——

  The adjustment of photoluminescence emission spectrum and an enhancement in the thermal stability of red/orange-red emitting phosphors is an important issue for the whole lighting industry.

  光致发光发射光谱的调整和红/橙红发光荧光粉的热稳定性的提高是整个照明行业的重要问题。
• PbHPO4 derived Pb catalysts modified by polyethylene glycol toward efficient CO2 electroreduction to formate
  作者：Chunfeng Cheng、Guohui Song、Pengfei Wei、Tianfu Liu、Xiaoju Liu、Zhou Chen、Dunfeng Gao、Guoxiong Wang

  DOI：10.1016/j.jcat.2023.115125

  日期：2023.12

  solvated reactants. Herein, a polyethylene glycol-modified Pb nanosheet (Pb-PEG) catalyst is developed through in situ electrochemical reconstruction of PEG-modified PbHPO4, for efficient CO2 electroreduction. Formate is selectively produced with a Faradaic efficiency (FE) of 93.2 ± 2.9% and a remarkable partial current density of 326.0 ± 10.3 mA cm−2. The Pb-PEG catalyst also exhibits a stable formate

  催化材料的表面配体可以创造有利的反应微环境，稳定反应中间体并富集溶剂化反应物。在此，通过原位电化学重构PEG修饰的PbHPO 4 ，开发了聚乙二醇修饰的Pb纳米片（Pb-PEG）催化剂，用于有效的CO 2电还原。选择性生产甲酸盐，法拉第效率 (FE) 为 93.2 ± 2.9%，部分电流密度为 326.0 ± 10.3 mA cm -2。Pb-PEG 催化剂还表现出 100 小时内超过 80% 的稳定甲酸盐 FE，从而产生~693 mmol 甲酸盐。PEG 的形态工程保持了 Pb 纳米片的层状形态，以暴露更多的活性位点。密度泛函理论计算表明，邻位PEG配体创建的定制反应微环境充当催化库，促进CO 2吸附并稳定*OCOH中间体的形成，从而产生令人印象深刻的甲酸盐产量。
• Immobilization of Aqueous Heavy Metal Cations with Phosphates and Sulfates
  作者：Shigeru Sugiyama、Masayoshi Fujisawa、Tatsuya Koizumi、Shinya Tanimoto、Katsuhiro Kawashiro、Tahei Tomida、Hiromu Hayashi

  DOI：10.1246/bcsj.76.2419

  日期：2003.12

  The dissolution–precipitation mechanism has been suggested for the immobilization of aqueous lead cation with calcium hydroxyapatite (Ca10(PO4)6(OH)2; CaHAp). Here Na2HPO4, K2HPO4, MgHPO4 and CaHPO4 were employed for CaHAp. These hydrogenphosphates could favorably remove Pb2+, Cd2+, Co2+ and Cu2+ from aqueous solution for 0.5 h at 293 K. The removability of those hydrogenphosphates was evidently greater than that of CaHAp and seemed to be dependent on solubility of those hydrogenphosphates and the hydration enthalpy of those heavy metal cations. The structures of phosphates recovered after immobilization of Pb2+, Cd2+, and Co2+ were strongly influenced by the pH in the aqueous solution, while the structures after immobilization of Cu2+ for 0.5 and 12 h were amorphous compound and Cu2(PO4)(OH), respectively. The employment of solid state 31P MAS NMR and XRD revealed that the amorphous compound was also Cu2(PO4)(OH). The removability found with those hydrogenphosphates was also observed in the immobilization of Pb2+ with MgSO4 and CaSO4.

  羟基磷灰石钙（Ca10(PO4)6(OH)2；CaHAp）固定水溶液中铅阳离子的溶解沉淀机制已被提出。这里的 CaHAp 使用了 Na2HPO4、K2HPO4、MgHPO4 和 CaHPO4。这些氢磷酸盐在 293 K 下 0.5 小时可从水溶液中去除 Pb2+、Cd2+、Co2+ 和 Cu2+。这些氢磷酸盐的去除率明显高于 CaHAp，而且似乎取决于这些氢磷酸盐的溶解度和这些重金属阳离子的水合焓。固定 Pb2+、Cd2+ 和 Co2+ 后回收的磷酸盐结构受水溶液 pH 值的影响很大，而固定 Cu2+ 0.5 和 12 h 后的结构分别为无定形化合物和 Cu2(PO4)(OH)。固态 31P MAS NMR 和 XRD 显示，无定形化合物也是 Cu2(PO4)(OH)。在用 MgSO4 和 CaSO4 固定 Pb2+ 时，也观察到了这些磷酸盐的可去除性。
• Specific heat behaviour of the ferroelectric PbHPO4
  作者：A. López-Echarri、M.J. Tello、M.A.P. Jubindo

  DOI：10.1016/0038-1098(81)90262-3

  日期：1981.5

  Abstract Specific heat measurements of PbHPO 4 confirm the second order character for the Ferro-paraelectric phase transition at T c = 307.75 ± 0.09 K. A comparison between the experimental results and phenomenological and statistical theories is carried out. The classical critical behaviour for both α + and α - are shown to be valid up to |T − T c |

  摘要 PbHPO 4 的比热测量证实了铁顺电相变在 T c = 307.75 ± 0.09 K 时的二阶特征。对实验结果与现象学和统计理论进行了比较。α + 和 α - 的经典临界行为在|T − T c | 内均有效。