palladium diphosphide | 12066-55-6

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: palladium diphosphide
• 英文别名: Diphosphine palladium(0)；palladium;phosphane
• CAS: 12066-55-6
• 化学式: P₂Pd
• 分子量: 168.368
• InChiKey: AEGVXRFFNDYKDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.11
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三辛基膦 、 钯 以 not given 为溶剂， 生成 palladium diphosphide
  参考文献：
  名称：

  Converting Metals into Phosphides:  A General Strategy for the Synthesis of Metal Phosphide Nanocrystals

  摘要：

  Nanocrystals of metal phosphides, which can have useful catalytic, electronic, and magnetic properties, are known to be accessible by using trioctylphosphine (TOP) as a highly reactive phosphorus source. Here we report a general strategy for synthesizing transition metal phosphides, including those with 4d and 5d transition metals that have not previously been reported as unsupported nanocrystals. Unlike previously reported methods that involve direct decomposition of organometallic precursors, our method utilizes preformed metal nanoparticles as templates for generating metal phosphide nanocrystals. Metal nanoparticles are reacted with TOP in a hot solvent (290-360 degrees C) to form transition metal phosphides such as Ni2P, PtP2, Rh2P, PdP2, Pd5P2, and Au2P3. Furthermore, nanostructures such as hollow spheres can be easily made using a Kirkendall-type mechanism, which utilizes metal nanoparticles as reactive templates.

  DOI：

  10.1021/ja068502l

文献信息

• Nature of the modifying action of white phosphorus on the properties of nanosized hydrogenation catalysts based on bis(dibenzylideneacetone)palladium(0)
  作者：L. B. Belykh、N. I. Skripov、L. N. Belonogova、V. A. Umanets、T. P. Stepanova、F. K. Schmidt

  DOI：10.1134/s002315841105003x

  日期：2011.9

  the formation of nanosized palladium-based hydrogenation catalysts. The mechanism includes the formation of palladium nanoclusters via the interaction of Pd(dba)2 with the solvent (N,N-dimethylformamide) and substrate and the formation of palladium phosphide nanoparticles. The inhibiting effect exerted by elemental phosphorus on the catalytic process is due to the conversion of part of the Pd(0) into

  报道了在基于Pd（dba）2和白磷的体系中形成的纳米颗粒的催化特性和性质。提出了用于形成纳米尺寸的基于钯的氢化催化剂的示意性机理。该机理包括通过Pd（dba）2与溶剂（N，N-二甲基甲酰胺）和底物以及磷化钯纳米粒子的形成。元素磷在催化过程中发挥的抑制作用是由于部分Pd（0）转化为磷化钯（在温和条件下在氢化中不活泼）以及主要分离的钯纳米簇和磷化钯纳米颗粒的形成。通过研究苯中Pd（dba）2和白磷之间的相互作用，可以确定在温和条件下形成钯钯的过程包括以下连续步骤：Pd（0）→PdP 2 →Pd 5 P 2 →Pd 3P.解释了为什么白磷会根据钯前体的性质而对纳米级钯基加氢催化剂的催化性能产生截然相反的影响。
• Formation of palladium phosphides in the reaction of bis(dibenzylideneacetone)palladium(0) with white phosphorus
  作者：N. I. Skripov、L. B. Belykh、L. N. Belonogova、A. V. Rokhin、T. P. Stepanova、F. K. Shmidt

  DOI：10.1134/s1070363212020077

  日期：2012.2

  of bis(dibenzylideneacetone)palladium(0) with white phosphorus was studied using the methods of NMR, UV spectroscopy, and X-ray powder diffraction. The products of the reaction are shown to be palladium phosphides, their composition depending on the ratio of the reagents. The mechanism of the formation of the palladium-enriched phosphides is suggested, which includes the formation of palladium diphosphide

  使用NMR，UV光谱和X射线粉末衍射方法研究了双（二亚苄基丙酮）钯（0）​​与白磷的反应。反应产物显示为磷化钯，其组成取决于试剂的比例。提出了形成富含钯的磷化物的机理，其包括形成二磷化钯PdP 2，其随后与过量的双（二亚苄基丙酮）钯（0）​​反应，导致磷化钯Pd 5 P 2，Pd 3 P 0.8，Pd 4.8 P和游离的二亚苄基丙酮。
• Effect of the nature of the acido ligand in the precursor on the properties of nanosized palladium-based hydrogenation catalysts modified with elemental phosphorus
  作者：N. I. Skripov、L. B. Belykh、L. N. Belonogova、V. A. Umanets、E. N. Ryzhkovich、F. K. Schmidt

  DOI：10.1134/s0023158410050137

  日期：2010.10

  palladium cluster stabilizer—dimethylammonium chloride—in the reaction system via the catalytic hydrolysis of the solvent (DMF). The modifying action of elemental phosphorus on the properties of the palladium catalysts depends on the nature of the acido ligand in the precursor. In the case of oxygen-containing precursors at small P/Pd ratios, elemental phosphorus exerts a promoting effect, raising the TON

  报道了前体中的酸性配体的性质的影响和元素磷对钯催化剂加氢的改性作用。在DMF中用氢气将PdCl 2还原制得的PdCl 2上，苯乙烯加氢时观察到的苯乙烯加氢中较大的周转频率（TOF）和周转数（TON）值较大，这是由于形成了粒径为6的细颗粒催化剂–10海里。PdCl 2含量高解释了这一点通过溶剂（DMF）的催化水解，在反应体系中降低还原速率并形成钯簇稳定剂-二甲基氯化铵。元素磷对钯催化剂性能的改性作用取决于前体中酸性配体的性质。在P / Pd比小的含氧前体中，元素磷发挥促进作用，将TON和TOF值提高约9倍。在二氯化钯作为前体时，白磷发挥抑制作用。影响。同时，它提高了催化剂的稳定性，提高了P / Pd = 0.3时的TON值。考虑这些区别的原因。
• Synthesis, properties, and activity of nanosized palladium catalysts modified with elemental phosphorus for hydrogenation
  作者：L. B. Belykh、N. I. Skripov、L. N. Belonogova、V. A. Umanets、F. K. Schmidt

  DOI：10.1134/s0023158410010088

  日期：2010.2

  modifier of palladium catalysts for hydrogenation was demonstrated, and the conditions for the synthesis of nanoparticles that are highly efficient in hydrogenation catalysis were optimized. The modifying effect of elemental phosphorus depends on the P/Pd ratio; it is associated with changes in the catalyst dispersity and the nature of the formed nanoparticles containing various palladium phosphides (PdP2

  证明了元素磷作为氢化钯催化剂的改性剂的适用性，并优化了在氢化催化中高效合成纳米颗粒的条件。元素磷的改性效果取决于P / Pd比率。它与催化剂分散度的变化以及所形成的包含各种磷化钯（PdP 2，Pd5P 2和Pd 6 P）和Pd（0）簇的纳米粒子的性质有关。确定了用于氢化的钯催化剂形成的主要阶段，并提出了一种活性催化剂模型，其中Pd 6 P磷化物是纳米颗粒的核心，Pd（0）簇形成壳。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: P: MVol.B, 3.4.1.8.3, page 299 - 304
  作者：

  DOI：——

  日期：——