tetrahydroxo borate | 15390-83-7

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: tetrahydroxo borate
• 英文别名: borate；{(11)B(OH)4}(1-)；orthoborate(1-)；Tetrahydroxyboranuide
• CAS: 15390-83-7
• 化学式: BH₄O₄
• 分子量: 78.8404
• InChiKey: KCFLOKKYWBPKFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.61
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.9
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  tetrahydroxo borate 以 水 为溶剂， 生成
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.13, 1.7, page 41 - 43

  摘要：

  DOI：
• 作为产物：
  描述：

  pentaborate 以 水 为溶剂， 生成 tetrahydroxo borate
  参考文献：
  名称：

  Wu, Li; Shiyang, Gao; Shuping, Xia, Journal of the Indian Chemical Society, 1997, vol. 74, # 7, p. 525 - 527

  摘要：

  DOI：
• 作为试剂：
  描述：

  6-甲基-2-硫代-2,3-二氢-4H-1,3-苯并噁嗪-4-酮 在 tetrahydroxo borate 作用下， 生成 autoinducer-2
  参考文献：
  名称：

  Serendipitous discovery of two highly selective inhibitors of bacterial luciferase

  摘要：

  Herein, we report the serendipitous discovery of two highly selective inhibitors of bacterial luciferase, N-phenacylthiazolium bromide (PTB) and pifithrin-alpha (PFT-alpha). These compounds, which are both derivatives of N-phenacylthiazolium salts, comprise a previously unreported class of luciferase inhibitors that are effective both in vitro and in live bacteria. Interestingly, although they are structurally similar, these compounds appear to elicit inhibitory effects via two different modes of action. Support for these conclusions has been obtained using purified luciferase enzyme as well as genetic knockout strains of Vibrio harveyi. Overall, this report provides the first evidence that N-phenacylthiazolium derivatives can serve as luciferase inhibitors, and also illustrates how the systematic investigation of logical hypotheses can lead to unexpected and potentially useful outcomes. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.05.086

文献信息

• The combining ratio of boric acid and alkali borate with mannitol
  作者：R.F. Nickerson

  DOI：10.1016/0022-1902(68)80284-2

  日期：1968.7

  The composition of the complex formed by mannitol and borate was investigated by several methods. Linear relationships found between the H+ and mannitol concentrations (H3BO3 constant) and between pH and log for wide ranges of reactant concentrations indicate that H3BO3 and mannitol combine only in a 1:1 ratio and that H3BO3 is present in dilute solutions principally as a dimer. Titration data also

  用几种方法研究了甘露醇和硼酸盐形成的配合物的组成。在宽范围的反应物浓度范围内，H +和甘露醇浓度（H 3 BO 3常数）之间以及pH和log之间存在线性关系，这表明H 3 BO 3和甘露醇仅以1：1的比例结合，并且H 3 BO 3主要以二聚体形式存在于稀溶液中。滴定数据还表明具有1个甘露醇/ B的复合物。
• Boranophosphate Salts as an Excellent Mimic of Phosphate Salts: Preparation, Characterization, and Properties
  作者：Victoria Nahum、Bilha Fischer

  DOI：10.1002/ejic.200400142

  日期：2004.10

  We report on the preparation of boranophosphate salts, BPi (2), and the exploration of their properties with a view to developing a new mimic of the parent phosphate. BPi salts were easily prepared in excellent yield in a one-pot two-step reaction from tris(trimethylsilyl) phosphite, and were characterized by X-ray crystallography and IR, 1H and 31P NMR spectroscopy. We evaluated the acid/base character

  我们报告了硼磷酸盐 BPi (2) 的制备，以及对其性质的探索，以期开发一种新的母磷酸盐模拟物。BPi 盐很容易在亚磷酸三（三甲基甲硅烷基）酯的一锅两步反应中以优异的产率制备，并通过 X 射线晶体学和 IR、1H 和 31P NMR 光谱进行表征。我们通过确定其酸度常数来评估 BPi 的酸/碱特性。同样，我们评估了 BPi 在各种 pH 值下的稳定性，并计算了高酸性 pH 下的分解速率常数。我们还监测了 BPi 在有机溶剂（包括 MeOH）中的 H 键团簇。最后，我们探讨了 BPi 对各种有机和无机试剂的化学行为。BPi 在以下条件下稳定：碱性和酸性 pH 值（pH > 2) 在胺存在下和在 Mg2+ 离子存在下。然而，在 BPi 与碳二亚胺反应或催化氢化时观察到 P-B 键断裂。BH3 部分的还原性质在 BPi 中急剧下降。同样，BPi 氧原子的亲核性低于磷酸盐、Pi、盐。基于其水溶性、酸碱特性和氢键性质，BPi
• Oxidative Degradation of Polyhedral Boranes¹
  作者：Alexander Kaczmarczyk、Gerald B. Kolski、Wesley P. Townsend

  DOI：10.1021/ja01084a068

  日期：1965.3

  and B20H18(-2) by potassium permanganate: (1) proceeds readily to completion at room temperature at pH 7 and (2) results in the quantitative conversion to boric acid. A summary of results is presented for the yield of boric acid from the oxidation of B10H10(-2), B12H12(-2), B20H18(-2), B20H18(-4), and B20H17OH(-4) ions and their organic and halo derivatives by dilute permanganate. One set of data was

  摘要 : 发现高锰酸钾对 B10H10(-2) 和 B20H18(-2) 的氧化：(1) 在室温和 pH 7 下很容易完成，(2) 导致定量转化为硼酸。总结了 B10H10(-2)、B12H12(-2)、B20H18(-2)、B20H18(-4) 和 B20H17OH(-4) 离子及其有机物氧化生成硼酸的结果和卤代衍生物稀释高锰酸盐。一组数据是在没有 pH 控制的情况下收集的，另一组是在弱酸性至中性溶液中收集的。（作者）
• Kinetic Analysis of Thermal and Hydrolytic Decomposition of Spiroborate Ester of Curcumin with Salicylic Acid
  作者：Jeena John、Sudha Devi Rugmini、Balachandran Sreedharan Nair

  DOI：10.13005/ojc/330234

  日期：2017.4.28

  Spiroborate ester of curcumin with salicylic acid (CBS) has been synthesized and characterized by different spectral techniques. The non-isothermal thermogravimetric method was used to study the thermal decomposition of CBS at the heating rate of 10 °C min-1 in nitrogen atmosphere. Hydrolytic stability was studied in aqueous acetone system with different percentages of water and temperature. The activation energies associated with the hydrolysis were evaluated using Arrhenius equation and the corresponding values of thermodynamic parameters were determined using Eyring equation. The possible mechanistic route for the hydrolysis of the complex was proposed.

  我们合成了姜黄素与水杨酸的螺硼酸酯（CBS），并通过不同的光谱技术对其进行了表征。采用非等温热重法研究了 CBS 在氮气环境中以 10 °C min-1 的加热速率进行的热分解。研究了在丙酮水溶液体系中不同比例的水和温度下的水解稳定性。使用阿伦尼乌斯方程评估了与水解相关的活化能，并使用艾林方程确定了相应的热力学参数值。提出了复合物水解的可能机理路线。
• Salts of the 1-cyanocarba-closo-dodecaborate anions [1-NC-closo-1-CB11X11]− (X = H, F, Cl, Br, I)
  作者：Maik Finze、Jan A. P. Sprenger、Bernd Bastian Schaack

  DOI：10.1039/b922720b

  日期：——

  tetraethylammonium salts of the 1-cyanocarba-closo-dodecaborate anions [1-NC-closo-1-CB11X11]− (X = H, F, Cl, Br, I) were synthesized from CsLi[closo-1-CB11X11] and phenylcyanate. All anions are stable against aqueous acids and bases, except for the fluorinated anion [1-NC-closo-1-CB11F11]− that immediately reacts with water. The Cs+ and [Et4N]+ salts of the anions were characterized by IR, Raman and multinuclear

  这 铯 和 四乙铵1-cyanocarba-的盐闭合碳-dodecaborate阴离子[1- NC-闭合碳-1-CB 11 X 11 ] -（X =H， F， 氯， 溴，I）是从CSLI [合成闭合碳-1-CB 11 X 11 ]和苯氰酸。除了可立即与之反应的氟化阴离子[1- NC - closo -1-CB 11 F 11 ] -外，所有阴离子均对含水酸和碱稳定。水。这Cs + 和 [Et 4 N] +通过IR，拉曼光谱和多核NMR光谱以及MALDI和ESI质谱对阴离子的盐进行表征。Cs [1- NC - closo -1-CB 11 X 11 ]（X =H， 氯， 溴，I）和其中的一些 四乙铵通过差示扫描量热法研究了盐。的[等的晶体结构4 N] [1-NC-闭合碳-1-CB 11 ħ 11 ]和Cs [1- NC-闭合碳-1-CB 11氯11 ]测定和结构和光谱性质的讨论由密度函数和（