μ-imido-1-thio-diphosphoric acid tetra-O-ethyl ester | 7109-08-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: μ-imido-1-thio-diphosphoric acid tetra-O-ethyl ester
• 英文别名: (O,O-Diethyl-phosphono)-(O,O-diethyl-thiophosphono)-amin；Diethoxyphosphoryl-diethoxythiophosphoryl-amid；Tetraethyl thioimidodiphosphate；[(diethoxyphosphinothioylamino)-ethoxyphosphoryl]oxyethane
• CAS: 7109-08-2
• 化学式: C₈H₂₁NO₅P₂S
• 分子量: 305.272
• InChiKey: UVODNENEBZDFOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  98.1
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  N-(O,O-Diethyl-thiophosphono)-imidophosphorsaeure-triethylester 在 盐酸 作用下， 以 Petroleum ether 为溶剂， 生成 μ-imido-1-thio-diphosphoric acid tetra-O-ethyl ester
  参考文献：
  名称：

  Gilyarov,V.A. et al., Journal of general chemistry of the USSR, 1966, vol. 36, p. 285 - 292

  摘要：

  DOI：

文献信息

• Process for extracting metals
  申请人：Zeneca Limited

  公开号：US05393431A1

  公开（公告）日：1995-02-28

  A process for extracting metal values especially zinc values from aqueous solutions of metal salts which comprises contacting the aqueous solution with an organic phase comprising a compound of the formula: ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4, independently, represents a substituted hydrocarbyl or hydrocarbyloxy group or R.sup.1 and R.sup.2 together with the attached phosphorus atom and/or R.sup.3 and R.sup.4 together with the attached phosphorus atom form a 5- to 8-membered heterocyclic ring.

  一种从金属盐水溶液中提取金属价值，特别是锌价值的过程，其包括将水溶液与含有下式化合物的有机相接触：##STR1## 其中R.sup.1、R.sup.2、R.sup.3和R.sup.4中的每个都独立地表示取代的烃基或烃氧基，或者R.sup.1和R.sup.2与所附磷原子一起，或者R.sup.3和R.sup.4与所附磷原子一起形成一个5-至8-成员杂环环。
• Bis(dialkylthiophosphoryl)amines as metal extractants
  申请人：Zeneca Limited

  公开号：US05502250A1

  公开（公告）日：1996-03-26

  A process for extracting metal values especially zinc values from aqueous solutions of metal salts which comprises contacting the aqueous solution with an organic phase comprising a compound of the formula: ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4, independently, represents an optionally substituted hydrocarbyl or hydrocarbyloxy group or R.sup.1 and R.sup.2 together with the attached phosphorus atom and/or R.sup.3 and R.sup.4 together with the attached phosphorus atom form a 5- to 8-membered heterocyclic ring.

  一种从金属盐的水溶液中提取金属价值，特别是锌价值的过程，其包括将水溶液与具有以下结构的化合物组成的有机相接触：##STR1## 其中R.sup.1，R.sup.2，R.sup.3和R.sup.4中的每一个，独立地代表可选择取代的烃基或烃氧基，或者R.sup.1和R.sup.2与所附的磷原子以及/或R.sup.3和R.sup.4与所附的磷原子形成5-到8-成员杂环环。
• Alkylphenoxy substituted bis (thio phosphoryl) amines
  申请人：Zeneca Limited

  公开号：US05557003A1

  公开（公告）日：1996-09-17

  A process for extracting metal values especially zinc values from aqueous solutions of metal salts which comprises contacting the aqueous solution with an organic phase comprising a compound of the formula: ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4, independently, represents an optionally substituted hydrocarbyl or hydrocarbyloxy group or R.sup.1 and R.sup.2 together with the attached phosphorus atom and/or R.sup.3 and R.sup.4 together with the attached phosphorus atom form a 5- to 8-membered heterocyclic ring.

  从金属盐的水溶液中提取金属价值，特别是锌价值的方法，包括将水溶液与含有以下化合物的有机相接触：##STR1## 其中每个R1、R2、R3和R4独立地表示可选取代的烃基或烃氧基，或者R1和R2与所连接的磷原子以及/或R3和R4与所连接的磷原子形成5-至8-成员杂环环。
• Chemical process
  申请人：Zeneca Limited

  公开号：US05728853A1

  公开（公告）日：1998-03-17

  A process for extracting metal values, especially zinc values, from aqueous solutions of metal salts, which comprises contacting the aqueous solution with an organic phase comprising a compound of the formula, ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4, independently, represents an optionally substituted hydrocarbyl or hydrocarbyloxy group or R.sup.1 and R.sup.2 together with the attached phosphorus atom and/or R.sup.3 and R.sup.4 together with the attached phosphorus atom from a 5- to 8-membered heterocyclic ring.

  一种从金属盐的水溶液中提取金属价值，特别是锌价值的方法，包括将水溶液与一个有机相接触，所述有机相包括下式化合物：##STR1## 其中，R.sup.1，R.sup.2，R.sup.3和R.sup.4分别独立地表示可选取代的烃基或烃氧基，或R.sup.1和R.sup.2与所附的磷原子以及/或R.sup.3和R.sup.4与所附的磷原子形成5-至8-成员杂环环。
• Process for extracting metal values
  申请人：ZENECA LIMITED

  公开号：EP0573182A1

  公开（公告）日：1993-12-08

  A process for extracting metal values especially zinc values from aqueous solutions of metal salts which comprises contacting the aqueous solution with an organic phase comprising a compound of the formula: wherein each of R¹, R², R³ and R⁴, independently, represents an optionally substituted hydrocarbyl or hydrocarbyloxy group or R¹ and R² together with the attached phosphorus atom and/or R³ and R⁴ together with the attached phosphorus atom form a 5- to 8-membered heterocyclic ring.

  一种从金属盐水溶液中提取金属值，特别是锌值的工艺，包括将水溶液与含有式化合物的有机相接触： 其中 R¹、R²、R³ 和 R⁴ 各自独立地代表任选取代的烃基或烃氧基，或 R¹ 和 R² 与所连接的磷原子和/或 R³ 和 R⁴ 与所连接的磷原子一起形成 5 至 8 元杂环。