bis[bis(pentafluoroethyl)phosphinyl]imide | 916079-45-3

• 分子结构分类: 有机化合物 - 有机磷化合物 - 磷芥子化合物
• 英文名称: bis[bis(pentafluoroethyl)phosphinyl]imide
• 英文别名: HFPI；bis(pentafluoroethyl)phosphinic acid imide；1-[[Bis(1,1,2,2,2-pentafluoroethyl)phosphorylamino]-(1,1,2,2,2-pentafluoroethyl)phosphoryl]-1,1,2,2,2-pentafluoroethane；1-[[bis(1,1,2,2,2-pentafluoroethyl)phosphorylamino]-(1,1,2,2,2-pentafluoroethyl)phosphoryl]-1,1,2,2,2-pentafluoroethane
• CAS: 916079-45-3
• 化学式: C₈HF₂₀NO₂P₂
• 分子量: 585.017
• InChiKey: YAMLIVLPCMADOD-UHFFFAOYSA-N

物化性质

• 熔点：
  47 °C
• 沸点：
  192.7±50.0 °C(Predicted)
• 密度：
  1.788±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  46.2
• 氢给体数：
  1
• 氢受体数：
  23

反应信息

• 作为反应物：
  描述：

  bis[bis(pentafluoroethyl)phosphinyl]imide 、 碳酸胍 以 水 为溶剂， 反应 0.5h， 以84%的产率得到guanidinium bis[bis(pentafluoroethyl)phosphinyl]azanide
  参考文献：
  名称：

  新的离子液体与二〔二（五氟乙基）氧膦基]酰亚胺阴离子，[（C 2 ˚F 5）2 P（O）] 2 ñ - -合成和表征

  摘要：

  一系列新的低熔点和疏水性离子液体（离子液体），其含有二〔二（五氟乙基）氧膦基]酰亚胺阴离子，[（C的2 ˚F 5）2 P（O）] 2 ñ -（FPI），和铵，鏻制备并表征了咪唑鎓，吡啶鎓或吡咯烷鎓阳离子。讨论了它们的密度，粘度，熔点，玻璃化转变温度，分解温度和电导率。这些离子液体中的许多是在室温下的液体，其熔点低于15°C，粘度低于110 mm 2  s -1且热稳定性高于300°C。

  DOI：

  10.1016/j.jfluchem.2009.11.004
• 作为产物：
  描述：

  (C2H5)3N(1+)[(C2F5)2P(O)]2N(1-) 在 硫酸 作用下， 生成 bis[bis(pentafluoroethyl)phosphinyl]imide
  参考文献：
  名称：

  WO2006/128563

  摘要：

  公开号：

文献信息

• Particles for electrophoretic displays
  申请人：Merck Patent GmbH

  公开号：US10106686B2

  公开（公告）日：2018-10-23

  This invention relates to particles comprising a pigment core particle encapsulated by a polymer, a process for their preparation, electrophoretic fluids comprising such particles, and electrophoretic display devices comprising such fluids.

  这项发明涉及由聚合物封装的颜料核心颗粒组成的颗粒，其制备方法，包含这种颗粒的电泳流体，以及包含这种流体的电泳显示设备。
• PARTICLES FOR ELECTROPHORETIC DISPLAYS
  申请人：MARCK PATENT GMBH

  公开号：US20160177103A1

  公开（公告）日：2016-06-23

  This invention relates to particles comprising a pigment core particle encapsulated by a polymer, a process for their preparation, electrophoretic fluids comprising such particles, and electrophoretic display devices comprising such fluids.

  本发明涉及一种包含聚合物封装的颜料核心粒子的微粒，其制备过程，包含这种微粒的电泳流体以及包含这种流体的电泳显示器设备。
• Synthesis and Characterization of Bis[bis(pentafluoroethyl)phosphinyl]imides, M⁺N[(C₂F₅)₂P(O)]₂⁻, M = H, Na, K, Cs, Ag, Me₄N
  作者：Dana Bejan、Helge Willner、Nikolai Ignatiev、Christian W. Lehmann

  DOI：10.1021/ic801088q

  日期：2008.10.6

  A convenient synthesis and a full characterization of the strong acid bis[bis(pentafluoroethyl)phosphinyl]imide and some of its salts M (+)N[(C 2F 5) 2P(O)] 2 (-), M = Na, K, Cs, Ag, Me 4N, are presented. Their thermal (mp, T dec.) and spectroscopic (IR, Raman, NMR) properties are discussed. A single crystal structure of [Me 4N][NP(O)(C 2F 5) 2} 2] has been obtained, and the structural parameters

  方便合成强酸双[双（五氟乙基）亚膦酰基]酰亚胺及其某些盐M（+）N [（C 2F 5）2P（O）] 2（-），并对其进行全面表征，M = Na，介绍了K，Cs，Ag，Me 4N。讨论了它们的热（mp，T dec。）和光谱（IR，拉曼，NMR）性质。获得了[Me 4N] [N P（O）（C 2F 5）2} 2]的单晶结构，并将阴离子的结构参数与量子化学计算的结果进行了比较。观察到的性质与双（（三氟甲基）磺酰基）酰亚胺及其衍生物的性质相当。
• Reactive mesogen formulation with conductive additive
  申请人：Merck Patent GmbH

  公开号：US10745620B2

  公开（公告）日：2020-08-18

  The invention relates to a reactive mesogen (RM) formulation comprising a conductive additive, to a polymer film obtained thereof, and the use of the RM formulation and polymer film in optical or electrooptical components or devices, like optical retardation films for liquid crystal displays (LCDs).

  本发明涉及一种包含导电添加剂的反应性中间体（RM）配方、由此获得的聚合物薄膜，以及该反应性中间体配方和聚合物薄膜在光学或电子光学元件或设备中的应用，如液晶显示器（LCD）的光学延迟膜。
• New hydrophobic ionic liquids with perfluoroalkyl phosphate and cyanofluoroborate anions
  作者：N.V. Ignat’ev、M. Finze、J.A.P. Sprenger、C. Kerpen、E. Bernhardt、H. Willner

  DOI：10.1016/j.jfluchem.2015.03.007

  日期：2015.9

  Novel hydrophobic ionic liquids (ILs) with tris(perfluoroalkyl)trifluorophosphate anions (e.g. [(C2F5)(3)PF3](-); FAP anion), the bis[bis(pentafluoroethyl)phosphinyl]imide (FPI) anion, the tetracyanoborate (TCB) anion, the tricyanofluoroborate (MFB) anion and the dicyanodifluoroborate (DDB) anion have been developed. The properties of these ionic liquids, i.e. their thermal and electrochemical stabilities as well as their viscosities, densities and refractive indices were studied and will be discussed. FAP ionic liquids are more hydrolytically stable and less viscous compared to ionic liquids with the hexafluorophosphate ([PF6](-)) anion. The hydrophobicity of ionic liquids with the cyano- and fluoroborate anions [BFx(CN)(4-x)](-) (x = 0-4) strongly decrease in the order: EMIM[B(CN)(4)] > EMIM[BF(CN)(3)] > EMIM[BF2(CN)(2)] > EMIM[BF3(CN)] similar to EMIM[BF4]; EMIM[BF3(CN)] as well as EMIM[BF4] are miscible with water. The lowest viscosity for all ionic liquids composed of the EMIM cation and weakly coordinating anions as the ones presented herein was observed for EMIM[BF2(CN)(2)] (11.1 mPa.s at 20 degrees C). (C) 2015 Elsevier B.V. All rights reserved.