N'-[1,3]Dithiol-2-ylidene-phosphorohydrazidic acid diethyl ester | 799781-78-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: N'-[1,3]Dithiol-2-ylidene-phosphorohydrazidic acid diethyl ester
• 英文别名: 2-(Diethoxyphosphorylhydrazinylidene)-1,3-dithiole；2-(diethoxyphosphorylhydrazinylidene)-1,3-dithiole
• CAS: 799781-78-5
• 化学式: C₇H₁₃N₂O₃PS₂
• 分子量: 268.298
• InChiKey: WZEOMJXEEMGDOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  111
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  [1,3]ditiol-2-ylideneacetaldehyde 、 N'-[1,3]Dithiol-2-ylidene-phosphorohydrazidic acid diethyl ester 在 sodium hydride 作用下， 以 甲苯 为溶剂， 以25%的产率得到N-[1,3]Dithiol-2-ylidene-N'-[2-[1,3]dithiol-2-ylidene-eth-(E)-ylidene]-hydrazine
  参考文献：
  名称：

  Aza-analogues of extended tetrathiafulvalenes

  摘要：

  The phosphoramidate-like reaction of 1,3-dithiole derived N-(diethoxyphosphinyl)hydrazones with formyl derivatives of 1,3-dithiole affords the longest aza-analogues of extended tetrathiafulvalenes with a polyenic spacer reported to date. Their structural and electrochemical properties are discussed. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.09.027
• 作为产物：
  描述：

  phosphorohydrazidic acid diethyl ester 、 2-methylthio-1,3-dithiolium iodide 在 吡啶 作用下， 以 甲醇 为溶剂， 以79%的产率得到N'-[1,3]Dithiol-2-ylidene-phosphorohydrazidic acid diethyl ester
  参考文献：
  名称：

  Aza-analogues of extended tetrathiafulvalenes

  摘要：

  The phosphoramidate-like reaction of 1,3-dithiole derived N-(diethoxyphosphinyl)hydrazones with formyl derivatives of 1,3-dithiole affords the longest aza-analogues of extended tetrathiafulvalenes with a polyenic spacer reported to date. Their structural and electrochemical properties are discussed. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.09.027

文献信息

• Aza-analogues of extended tetrathiafulvalenes
  作者：Raquel Andreu、Javier Garı́n、Carolina López、Jesús Orduna、Eric Levillain

  DOI：10.1016/j.tetlet.2004.09.027

  日期：2004.10

  The phosphoramidate-like reaction of 1,3-dithiole derived N-(diethoxyphosphinyl)hydrazones with formyl derivatives of 1,3-dithiole affords the longest aza-analogues of extended tetrathiafulvalenes with a polyenic spacer reported to date. Their structural and electrochemical properties are discussed. (C) 2004 Elsevier Ltd. All rights reserved.