1-methyl-2-undecyl-4,5-dihydro-1H-imidazole | 136101-84-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 亚胺内酰胺
• 英文名称: 1-methyl-2-undecyl-4,5-dihydro-1H-imidazole
• 英文别名: 1-Methyl-2-undecyl-4,5-dihydro-1H-imidazol；1-Methyl-2-undecyl-2-imidazoline；1-Methyl-2-undecyl-4,5-dihydroimidazole
• CAS: 136101-84-3
• 化学式: C₁₅H₃₀N₂
• 分子量: 238.417
• InChiKey: ALRJQFCSYAWULA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  15.6
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-methyl-2-undecyl-4,5-dihydro-1H-imidazole 在 镍 作用下， 生成 1-甲基-2-十一烷基咪唑
  参考文献：
  名称：

  取代的咪唑和2-咪唑啉。

  摘要：

  DOI：

  10.1021/jo01168a015
• 作为产物：
  描述：

  4,5-二氢-2-十一烷基-1H-咪唑 在 sodium hydroxide 、 硫酸二甲酯 作用下， 生成 1-methyl-2-undecyl-4,5-dihydro-1H-imidazole
  参考文献：
  名称：

  Dihydroimidazolium compounds

  摘要：

  公开号：

  US02493321A1

文献信息

• CROSS-LINKABLE NITRILE RUBBER COMPOSITION AND CROSS-LINKED RUBBER
  申请人：Ikeda Shinya

  公开号：US20100256294A1

  公开（公告）日：2010-10-07

  A cross-linkable nitrile rubber composition containing a highly saturated nitrile rubber (a) having an α,β-ethylenically unsaturated nitrile monomer unit and a carboxyl-group containing monomer unit and having an iodine value of 120 or less, a cross-linking agent (b), and a specific cyclic amidine and/or cyclic amidinium salt (c) is provided. Preferably, the cross-linking agent (b) is a polyamine-based cross-linking agent (d), and more preferably, the carboxyl-group containing monomer unit is an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit.

  提供了一种可交联的丁腈橡胶组合物，其中包含高度饱和的丁腈橡胶（a），其具有α，β-乙烯基不饱和丙烯腈单体单元和含羧基单体单元，并且碘值小于或等于120，交联剂（b）和特定的环状酰胺和/或环状酰胺盐（c）。优选，交联剂（b）是基于多胺的交联剂（d），更优选，含羧基单体单元是α，β-乙烯基不饱和二羧酸单酯单体单元。
• CROSSLINKABLE NITRILE RUBBER COMPOSITION AND CROSSLINKED RUBBER
  申请人：Zeon Corporation

  公开号：EP2239297A1

  公开（公告）日：2010-10-13

  A cross-linkable nitrile rubber composition containing a highly saturated nitrile rubber (a) having an α,β-ethylenically unsaturated nitrile monomer unit and a carboxyl-group containing monomer unit and having an iodine value of 120 or less, a cross-linking agent (b), and a specific cyclic amidine and/or cyclic amidinium salt (c) is provided. Preferably, the cross-linking agent(b) is a polyamine-based cross-linking agent (d), and more preferably, the carboxyl-group containing monomer unit is an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit.

  本发明提供了一种可交联丁腈橡胶组合物，该组合物含有高饱和度丁腈橡胶（a）（具有一个α，β-乙烯基不饱和丁腈单体单元和一个含羧基的单体单元，且碘值在 120 或以下）、交联剂（b）以及特定的环状脒和/或环状脒盐（c）。优选地，交联剂（b）是聚胺基交联剂（d），更优选地，含羧基的单体单元是α，β-乙烯基不饱和二羧酸单酯单体单元。
• NITRILE RUBBER COMPOSITION AND RUBBER CROSS-LINKED PRODUCT
  申请人：Zeon Corporation

  公开号：EP2781547A1

  公开（公告）日：2014-09-24

  A nitrile rubber composition containing a carboxyl group-containing nitrile rubber and an allylamine-based polymer which contains units expressed by the following general formula (1) is provided. (In the general formula (1), R1, R2, and R3 respectively independently are one selected from a group comprised of a hydrogen atom, alkyl group containing 1 to 4 carbon atoms which may have substituents, aryl group containing 6 to 12 carbon atoms which may have substituents, and halogen atom.)

  本发明提供了一种丁腈橡胶组合物，该组合物含有含羧基的丁腈橡胶和烯丙基胺基聚合物，后者含有下式（1）表示的单元。 (通式(1)中，R1、R2 和 R3 分别独立地选自由氢原子、含 1 至 4 个碳原子且可带有取代基的烷基、含 6 至 12 个碳原子且可带有取代基的芳基和卤素原子组成的基团中的一个)。
• CROSSLINKABLE RUBBER COMPOSITION AND CROSSLINKED RUBBER
  申请人：Zeon Corporation

  公开号：EP2902437A1

  公开（公告）日：2015-08-05

  A cross-linkable rubber composition containing a carboxyl group-containing nitrile rubber (A) with an iodine value of 120 or less, a polyamine cross-linking agent (B), and a specific basic cross-linking accelerator (C) is provided. The basic cross-linking accelerator (C) is preferably dicyclopentylamine or dicyclohexylamine.

  提供了一种可交联橡胶组合物，其中包含碘值在 120 或以下的含羧基丁腈橡胶（A）、多胺交联剂（B）和特定的碱性交联促进剂（C）。碱性交联促进剂（C）最好是二环戊胺或二环己胺。
• CROSSLINKABLE NITRILE RUBBER COMPOSITION AND RUBBER CROSSLINKED PRODUCT
  申请人：Zeon Corporation

  公开号：EP3088457A1

  公开（公告）日：2016-11-02

  A cross-linkable nitrile rubber composition comprising a highly saturated nitrile rubber (a) containing α,β-ethylenically unsaturated nitrile monomer units and α,β-ethylenically unsaturated dicarboxylic acid monoester monomer units and having an iodine value of 120 or less, organic staple fiber (b) with an average fiber length of 0.1 to 12 mm, and a polyamine cross-linking agent (c) is provided. According to the present invention, a cross-linkable nitrile rubber composition able to give cross-linked rubber excellent in tensile stress and low heat buildup can be provided.

  本发明提供了一种可交联丁腈橡胶组合物，该组合物包括含有α,β-乙烯基不饱和丁腈单体单元和α,β-乙烯基不饱和二羧酸单体单元且碘值小于或等于 120 的高饱和丁腈橡胶 (a)、平均纤维长度为 0.1 至 12 毫米的有机短纤维 (b) 以及聚胺交联剂 (c)。根据本发明，可提供一种可交联丁腈橡胶组合物，该组合物能够提供拉伸应力和低热积聚性能优异的交联橡胶。