N-[3-({3-[(3-氨基丙基)氨基]丙基}氨基)丙基]丁烷-1,4-二胺 | 3033-37-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: N-[3-({3-[(3-氨基丙基)氨基]丙基}氨基)丙基]丁烷-1,4-二胺
• 中文别名: 三十三烷基磷酸酯
• 英文名称: Tri(tridecyl) phosphate
• 英文别名: tritridecyl phosphate
• CAS: 3033-37-2
• 化学式: C₃₉H₈₁O₄P
• 分子量: 645.0
• InChiKey: XEQUZHYCHCGTJX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.9
• 重原子数：
  44
• 可旋转键数：
  39
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• LUBRICATING OIL COMPOSITIONS AND WATCH CONTAINING THE SAME
  申请人：Citizen Watch Co. Ltd.

  公开号：EP1201734A1

  公开（公告）日：2002-05-02

  The first lubricating oil composition of the invention comprises a polyol ester (A) as a base oil, a specific amount of a viscosity index improver (B) and a specific amount of an anti-wear agent (C), and the second lubricating oil composition of the invention comprises a paraffinic hydrocarbon oil (F) having at least 30 carbon atoms and a specific amount of a viscosity index improver (B), so that these compositions exert effects that they enable a life of watch battery to last long, they enable a watch to operate in the temperature range of -30 to 80°C with one kind of a lubricating oil, and they are free from change of properties over a long period of time. The third lubricating oil composition of the invention comprises an ether oil (G) as a base oil, a specific amount of an anti-wear agent (C) comprising a neutral phosphoric ester and/or a neutral phosphorous ester, and an antioxidant (E), so that this composition is free from change of properties over a long period of time and is favorable as a watch lubricating oil. The watch of the invention is a watch having a movable portion for which at least one composition selected from the above compositions is used.

  本发明的第一种润滑油组合物包括作为基础油的多元醇酯（A）、一定量的粘度指数改进剂（B）和一定量的抗磨剂（C），本发明的第二种润滑油组合物包括至少有 30 个碳原子的石蜡烃油（F）和一定量的粘度指数改进剂（B）、因此，这些组合物的效果是：能延长手表电池的使用寿命，能使手表在-30 至 80°C 的温度范围内使用一种润滑油工作，并且在很长一段时间内性能不会发生变化。本发明的第三种润滑油组合物包括作为基础油的醚油 (G)、一定量的抗磨剂 (C)（包括中性磷酸酯和/或中性磷酯）和抗氧化剂 (E)，因此这种组合物在很长一段时间内都不会改变性质，有利于用作手表润滑油。本发明的手表是一种具有活动部分的手表，其活动部分使用了至少一种选自上述组合物的组合物。
• PEAK TORQUE LOWERING COMPOSITION, PART WITH SLIDING PART USING THE COMPOSITION, AND PRESS-FITTING METHOD USING THE COMPOSITION
  申请人：Citizen Watch Co. Ltd.

  公开号：EP1386982A1

  公开（公告）日：2004-02-04

  The peak-torque descending composition of the present invention contains a certain amount of an extreme pressure agent comprising at least neutral phosphate esters and/or neutral phosphite esters in a solvent comprising hydrocarbons and/or ethers. Further, a certain corrosion inhibitor may be contained. The part having a sliding portion of the present invention is surface-treated with the above composition. The process for producing a component or precision machine having a sliding portion comprises immersing a part having a sliding portion in the above composition to adhere or absorb the composition onto the surface of the part, then immediately, taking out the part from the composition, followed by drying, and subsequently assembling a component or precision machine using the part. The press fit method of the present invention comprises in pressing a metal shaft into a metal plate, preliminarily immersing the metal plate or the metal shaft in the peak-torque descending composition to adhere or absorb the composition onto an inner surface of a hole for press fit of the metal plate or the surface of the shaft, then immediately, taking out the metal plate or the shaft from the composition, and drying. According to the process for the production of a component or precision machine having a sliding portion of the present invention, the peak-torque descending composition of the invention is used as the surface treating agent, so that the gearwheel body having a slip mechanism which can be made from metallic materials with a simple structure wherein a large peak torque does not produce in an initial stage when slipped and wheel teeth of the gearwheel are not chipped even when the plastic gearwheel is used, can be efficiently produced. According to the present invention, there can be provided a press fit method wherein the occurrence of a burr phenomenon is prevented when the shaft is pressed into the metal plate.

  本发明的峰值扭矩下降组合物含有一定量的极压剂，该极压剂至少由中性磷酸酯和/或中性亚磷酸酯组成，其溶剂包括碳氢化合物和/或醚。此外，还可能含有某种腐蚀抑制剂。具有本发明滑动部分的部件用上述组合物进行表面处理。生产具有滑动部分的部件或精密机器的工艺包括：将具有滑动部分的部件浸入上述组合物中，使组合物附着或吸收到部件表面，然后立即将部件从组合物中取出，接着干燥，然后使用该部件组装部件或精密机器。本发明的压配方法包括在将金属轴压入金属板时，先将金属板或金属轴浸入峰值扭矩下降组合物中，使组合物粘附或吸收到金属板压配孔的内表面或轴的表面上，然后立即从组合物中取出金属板或轴，并进行干燥。 根据本发明的具有滑动部分的部件或精密机器的生产工艺，使用本发明的峰值扭矩下降组合物作为表面处理剂，可以高效地生产出具有滑动机构的齿轮体，该齿轮体可以由金属材料制成，结构简单，在滑动初期不会产生较大的峰值扭矩，即使使用塑料齿轮，齿轮的轮齿也不会崩裂。根据本发明，可以提供一种压配方法，当轴被压入金属板时，可以防止毛刺现象的发生。
• GREASE COMPOSITION FOR PRECISION EQUIPMENT AND TIMEPIECE CONTAINING THE SAME
  申请人：Citizen Watch Co. Ltd.

  公开号：EP1533361A1

  公开（公告）日：2005-05-25

  Disclosed is a grease composition for a precision instrument comprising a lithium soap grease or a urea grease, and an anti-wear agent, wherein the lithium soap grease and the urea grease are each a grease having no hydroxyl group in a molecule, and the anti-wear agent is contained in an amount of 0.1 to 20% by weight based on the total amount of the grease composition. By the use of the grease composition for a sliding mechanism of a precision instrument such as a watch, an appropriate slip torque can be obtained, and the precision instrument such as a watch can operate stably.

  本发明公开了一种用于精密仪器的润滑脂组合物，该组合物由锂皂润滑脂或尿素润滑脂和抗磨剂组成，其中锂皂润滑脂和尿素润滑脂均为分子中不含羟基的润滑脂，抗磨剂的含量为润滑脂组合物总量的 0.1%至 20%（按重量计）。通过将该润滑脂组合物用于精密仪器（如手表）的滑动机构，可以获得适当的滑动扭矩，并且精密仪器（如手表）可以稳定运行。
• CLOCK LUBRICATING-OIL COMPOSITION AND CLOCK
  申请人：Citizen Holdings Co., Ltd.

  公开号：EP2949734A1

  公开（公告）日：2015-12-02

  [Problem] To provide a lubricating oil composition for a timepiece, said composition being excellent in durability. [Solution] The lubricating oil composition for a timepiece according to the present invention contains a lubricant component (A) containing a base oil (A1), at least one antiwear agent (B) selected from a neutral phosphate ester and a neutral phosphite ester, and an antioxidant (C), and is characterized in that the total acid number of the composition is not more than 0.8 mgKOH/g, the antiwear agent (B) is contained in an amount of 0.1 to 15 parts by mass based on 100 parts by mass of the lubricant component (A), the antioxidant (C) is contained in an amount of 0.01 to 3 parts by mass based on 100 parts by mass of the lubricant component (A), and the composition contains a diphenylamine derivative (C-1) represented by the following general formula (c-1) and a hindered amine compound (C-2) represented by the following general formula (c-2) as the antioxidants (C).

  [问题] 提供一种用于钟表的润滑油组合物，所述组合物具有优异的耐用性。[解决方案] 根据本发明的钟表润滑油组合物包含一种含有基础油（A1）的润滑剂成分（A）、至少一种选自中性磷酸酯和中性亚磷酸酯的抗磨剂（B）以及一种抗氧化剂（C），其特征在于组合物的总酸值不超过 0.8 mgKOH/g，抗磨剂（B）的含量为 0.抗磨剂（B）的含量为 0.1 至 15 份（以 100 份润滑剂组分（A）的质量为基准），抗氧化剂（C）的含量为 0.01 至 3 份（以 100 份润滑剂组分（A）的质量为基准），并且该组合物包含由以下通式（c-1）表示的二苯胺衍生物（C-1）和由以下通式（c-2）表示的受阻胺化合物（C-2）作为抗氧化剂（C）。
• POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, AND OPTICAL MATERIAL
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3118233A1

  公开（公告）日：2017-01-18

  A polymerizable composition for an optical material of the present invention includes polyisocyanate (a) including aliphatic polyisocyanate (a1) and a modified aliphatic polyisocyanate (a2), an episulfide (b), and a polythiol (c).

  用于本发明光学材料的可聚合组合物包括多异氰酸酯（a），包括脂肪族多异氰酸酯（a1）和改性脂肪族多异氰酸酯（a2）、环硫化物（b）和聚硫醇（c）。