Terbium(III) nitrate hexahydrate | 13451-19-9

• 物质功能分类: 无机化工 - 无机盐 - 金属硝酸盐及亚硝酸盐
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 镧系含氧阴离子化合物
• 英文名称: Terbium(III) nitrate hexahydrate
• 英文别名: terbium(3+);trinitrate;hexahydrate
• CAS: 13451-19-9
• 化学式: H₁₂N₃O₁₅Tb
• 分子量: 453.032
• InChiKey: UTCARTSNNKGRTD-UHFFFAOYSA-N

物化性质

• 熔点：
  89.3 °C
• 溶解度：
  溶于水、乙醇、丙酮
• 稳定性/保质期：
  遵照规定使用和储存，则不会分解。

计算性质

• 辛醇/水分配系数(LogP)：
  -5.67
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  195
• 氢给体数：
  6
• 氢受体数：
  15

安全信息

• 危险等级：
  5.1
• 危险品标志：
  O,Xi
• 安全说明：
  S17,S26,S36/37/39
• 危险类别码：
  R8
• WGK Germany：
  2
• 海关编码：
  28469093
• 危险品运输编号：
  UN 1477 5.1/PG 3
• RTECS号：
  WY9625000
• 包装等级：
  III
• 危险类别：
  5.1
• 危险标志：
  GHS03,GHS07
• 危险性描述：
  H272,H315,H319,H335
• 危险性防范说明：
  P220,P261,P305 + P351 + P338

SDS

Name:	Terbium(iii)nitrate hexahydrate 99.9% Material Safety Data Sheet
Synonym:	Nitric acid, terbium (3+) salt texahydrat
CAS:	13451-19-9

Section 1 - Chemical Product MSDS Name:Terbium(iii)nitrate hexahydrate 99.9% Material Safety Data Sheet
Synonym:Nitric acid, terbium (3+) salt texahydrat

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
13451-19-9	TERBIUM(III)NITRATE HEXAHYDRATE	99.9	unlisted

Hazard Symbols: O
Risk Phrases: 8

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Contact with combustible material may cause fire.The toxicological properties of this material have not been fully investigated.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire.
Extinguishing Media:
Use water only!

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

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Section 7 - HANDLING and STORAGE
Handling:
Ground and bond containers when transferring material. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 13451-19-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 89.3 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density:
Molecular Formula: N3O9Tb.6H2O
Molecular Weight: 453.02

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, combustible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong reducing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides.
Hazardous Polymerization: Has not been reported.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13451-19-9: WY9625000 LD50/LC50:
CAS# 13451-19-9: Oral, rat: LD50 = >5 gm/kg.
Carcinogenicity:
TERBIUM(III)NITRATE HEXAHYDRATE - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: II
IMO
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: II
RID/ADR
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing group: II

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
WGK (Water Danger/Protection)
CAS# 13451-19-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13451-19-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13451-19-9 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  磷酸三苯酯 、 Terbium(III) nitrate hexahydrate 以 丙酮 为溶剂， 反应 0.25h， 以87.2%的产率得到
  参考文献：
  名称：

  有机磷改性的硝酸镧盐作为潜在的Act系元素氧化物气溶胶替代物

  摘要：

  在搜索用于从钚铀氧化还原萃取（PUREX）处理烧伤，一系列硝酸镧系元素水合物（[LN（气雾剂铀废产物合适的模拟物的κ 2 - NO 3）3 · Ñ ħ 2 O]）溶解在存在煤油中的磷酸三丁酯（O═P（O（CH 2）3 CH 3）3）称为三丁酸酯或丙酮中的磷酸三苯酯（O═P（O（C 6 H 5）称为TPhP））的晶体结构硝酸镧系和铀硝酸的TPhP衍生物就解决了为[LN（κ 2 - NO3）3（TPhP）3 ]（LN =的La，Ce的，镨，钕，钐，铕，钆，铽，镝，何，铒，的Tm，镱，路）和[U（O）2（κ 2 - NO 3）2（TPhP）2 ]（U）。镧系元素-TBP，Ln和U使用FTIR光谱，31 P NMR光谱，热重分析和X射线荧光光谱进一步表征。此外，通过PXRD分析发现使用箱式炉模拟热解条件对镧系元素TBP，Ln和U进行热处理，以生成所有系统的磷酸盐相（LnP 3 O 9或UP 2 O

  DOI：

  10.1021/acs.inorgchem.0c02428

文献信息

• Organophosphorus-Modified Lanthanide Nitrates as Potential Actinide Oxide Aerosol Surrogates
  作者：Timothy J. Boyle、Xavier J. Robinson、Fernando Guerrero、Diana Perales、Joshua A. Hubbard、Roger E. Cramer

  DOI：10.1021/acs.inorgchem.0c02428

  日期：2020.12.7

  nitrate hydrates ([Ln(κ2-NO3)3·nH2O]) were dissolved in the presence of tributylphosphate (O═P(O(CH2)3CH3)3) referred to as TBP) in kerosene or triphenylphosphate (O═P(O(C6H5) referred to as TPhP) in acetone. The crystal structure of the TPhP derivatives of the lanthanide nitrate series and uranium nitrate were solved as [Ln(κ2-NO3)3(TPhP)3] (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu)

  在搜索用于从钚铀氧化还原萃取（PUREX）处理烧伤，一系列硝酸镧系元素水合物（[LN（气雾剂铀废产物合适的模拟物的κ 2 - NO 3）3 · Ñ ħ 2 O]）溶解在存在煤油中的磷酸三丁酯（O═P（O（CH 2）3 CH 3）3）称为三丁酸酯或丙酮中的磷酸三苯酯（O═P（O（C 6 H 5）称为TPhP））的晶体结构硝酸镧系和铀硝酸的TPhP衍生物就解决了为[LN（κ 2 - NO3）3（TPhP）3 ]（LN =的La，Ce的，镨，钕，钐，铕，钆，铽，镝，何，铒，的Tm，镱，路）和[U（O）2（κ 2 - NO 3）2（TPhP）2 ]（U）。镧系元素-TBP，Ln和U使用FTIR光谱，31 P NMR光谱，热重分析和X射线荧光光谱进一步表征。此外，通过PXRD分析发现使用箱式炉模拟热解条件对镧系元素TBP，Ln和U进行热处理，以生成所有系统的磷酸盐相（LnP 3 O 9或UP 2 O

表征谱图