| 234757-69-8

• CAS: 234757-69-8
• 化学式: C₁₈H₂₅FeO₄PSi
• 分子量: 420.3
• InChiKey: IXTYEJONBFFZFU-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 三甲氧基磷 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Unexpected migration of the indenyl ligand in the reaction of alkynyl(η5-indenyl)iron complexes with phosphanes and phosphites from iron to the alkynyl group

  摘要：

  Novel indenylvinylidene iron complexes are formed in the reaction of alkynyl(η5-indenyl)iron complexes with phosphites and phosphanes in large excess by an intermolecular transfer of the indenyl ligand from iron to the Cβ atom of the alkynyl ligand; mechanistic studies indicate that the reaction proceeds by a radical pathway.

  DOI：

  10.1039/a902785h
• 作为产物：
  描述：

  、 三甲氧基磷 以 二丁醚 为溶剂， 生成
  参考文献：
  名称：

  Unexpected migration of the indenyl ligand in the reaction of alkynyl(η5-indenyl)iron complexes with phosphanes and phosphites from iron to the alkynyl group

  摘要：

  Novel indenylvinylidene iron complexes are formed in the reaction of alkynyl(η5-indenyl)iron complexes with phosphites and phosphanes in large excess by an intermolecular transfer of the indenyl ligand from iron to the Cβ atom of the alkynyl ligand; mechanistic studies indicate that the reaction proceeds by a radical pathway.

  DOI：

  10.1039/a902785h